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This document is a chemistry worksheet for Class XI students focusing on chemical bonding and molecular structure. It includes a variety of questions ranging from multiple choice to assertion-reason type, as well as problems requiring explanations and drawings of molecular structures. The worksheet is designed to assess students' understanding of concepts such as hybridization, bond lengths, and molecular geometry.

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13 views

CB

This document is a chemistry worksheet for Class XI students focusing on chemical bonding and molecular structure. It includes a variety of questions ranging from multiple choice to assertion-reason type, as well as problems requiring explanations and drawings of molecular structures. The worksheet is designed to assess students' understanding of concepts such as hybridization, bond lengths, and molecular geometry.

Uploaded by

lavanyaprasadlav
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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INDIAN SCHOOL AL WADI AL KABIR

Class: XI Department: SCIENCE Date of submission:


SUBJECT :CHEMISTRY 10.10.2020

Worksheet No: Chapter: CHEMICAL BONDING AND Note:


06 with answers MOLECULAR STRUCTURE A4 FILE FORMAT

NAME OF THE STUDENT CLASS & SEC: ROLL NO.

Questions 1 – 4 are paragraph-based questions.


The electronic configurations of three elements A, B and C are given below.
A ls22s22p6
B ls22s22p63s23p3
C ls22s22p63s23p5

1. Stable form of A may be represented by the formula


a. A
b. A2
c. A3
d. A4

2. Stable form of C may be represented by the formula


a, C
b. C2
c. C3
d. C4

3. The molecular formula of the compound formed from B and C will be


a. BC
b. B2C
c. BC2
d. BC3

4. The bond between B and C will be


a. ionic
b. covalent
c. hydrogen
d. coordinate

5. sp3d2 hybridization is present in SF6, find its geometry


a. octahedral geometry
b. square planar geometry
c. tetragonal geometry
d. tetrahedral geometry
1
6. Find the molecule with the maximum dipole moment
a. CH4
b. NH3
c. CO2
d. NF3

7. Find the pair with sp2 hybridisation of the central molecule


a. NH3 and NO2–
b. BF3 and CH4
c. BF3 and NO2–
d. NH2– and H2O

8. What is the formal charge on oxygen in the following structure?

a. +1
b. -2
c. -1
d. 0

9. The correct decreasing order of boiling points of the following compounds is


a. HF ˃ H2O ˃ NH3
b. H2O ˃ HF ˃ NH3
c. NH3 ˃ HF ˃ H2O
d. NH3 ˃ H2O ˃ HF

Assertion Reason type

10. Assertion (A): Though the central atom of both NH3 and H2O molecules are sp3 hybridised, yet H–N–H
bond angle is greater than that of H–O–H.
Reason (R): This is because nitrogen atom has one lone pair and oxygen atom has two lone pairs.
a. A and R both are correct, and R is the correct explanation of A.
b. A and R both are correct, but R is not the correct explanation of A.
c. A is true but R is false.
d. A and R both are false.

11. Assertion (A): ClF3 has a bent T shape.


Reason (R): It has two lone pairs arranged at 180°.
a. A and R both are correct, and R is the correct explanation of A.
b. A and R both are correct, but R is not the correct explanation of A.
c. A is true but R is false.
d. A and R both are false.

2
2 Marks

12. What is the total number of σ and π bonds in the following molecules?
a. C2H6 b. C2H4 c. HCOOH d. CH3COOH

13. Account for the following


a. The bond dissociation enthalpies of O-H bonds in H2O are not the same.
b. The double bond in C2 molecule consists of π bonds.

14. Amongst the following compounds, which do not obey the octet rule and why?
a. H2O b. PCl5 c. H2SO4 d. BeF2

15. Arrange the following in the increasing order of bond length.


C2 , C2- , C22-

16. Using the concept of hybridization explain the structures of PCl5 and SF6.

17. CO2 and SO2 are triatomic molecules. Do they have the same dipole moment? Justify your answer.

18. When a magnet is lowered in liquid oxygen, some O2 stick to it. No such behaviour is observed with liquid
N2. Explain.

3 Marks

19. Draw the Lewis dot structures for


a. H2SO4 b. PCl3 c. H2S

20. Which is more covalent?


a. NaCl or MgCl2 b. NaF or NaI c. HgCl2 or CaCl2

21. a Label the covalent radius and van der Waals radius (99 and 180 pm respectively) in the diagram of a
chlorine molecule.

b. Which species of each group is predicted to have the strongest bond?


i. O2, F2, N2 ii. H2, H2-, H2+ iii. N2, N2+, N2-

5 Marks

22. Complete the table

Molecule Bond pairs Lone pairs Geometry Shape Hybridisation


CH4
NH3
SF6
BrF5
H2O
PF5
BCl3

3
23. Give reasons for the following statements
a. The C-C bond length in ethane is 154 pm whereas in ethylene it is 134 pm.
b. H2O is a liquid whereas H2S is a gas.
c. PCl5 is a reactive molecule.
d. The O- O bond lengths in O3 are the same.
e. BF3 is a non-polar molecule.

Answer key
1. a
2. b
3. d
4. a
5. a
6. b
7. c
8. a
9. b
10. a
11. c

12. a. 7 σ bonds, 0 π bond


b. 5 σ bonds, 1 π bond
c. 4 σ bonds, 1 π bond
d. 7 σ bonds, 1 π bond

13. a. Due to difference in the chemical environment.


b. This is because of the presence of four electrons in two pi molecular orbitals.

14. b, c, d

15. C2
(σ1s) 2 (σ*1s) 2 (σ2s) 2 (σ * 2s) 2 (π 2px2 = π 2py2 )
B.O = ½ (8-4)
=2

C2 -
(σ1s) 2 (σ*1s) 2 (σ2s) 2 (σ * 2s) 2 (π 2px2 = π 2py2 ) (σ2pz1)
B.O = ½ (9-4)
= 2.5

C22-
(σ1s) 2 (σ*1s) 2 (σ2s) 2 (σ * 2s) 2 (π 2px2 = π 2py2 ) (σ2pz2)

B.O = ½ (10-4)
=3
Increasing bond length
C22- <C2- < C2

4
16. PCl5 SF6.

sp3d explanation sp3d2 explanation

17. CO2 (linear) SO2 (bent)

No, they don’t have the same dipole moment.


In CO2, the dipoles cancel out and hence have zero dipole moment.

18. O2 is paramagnetic (due to unpaired electrons). N2 is diamagnetic (due to paired electrons)


Electronic configurations of N2 and O2.

19..
a. H2SO4 b. PCl3 c. H2S

20. a. MgCl2 , Mg2+ - smaller cation, greater charge- greater polarizing power.
b. NaI- I- larger anion, greater polarisability
c. Hg2+, transition element -greater polarizing power.

5
21. a.

b.
i. N2
ii. H2
iii. N2

22. Complete the table


.
Molecule Bond pairs Lone pairs Shape Hybridisation
CH4 4 0 Tetrahedral sp3

NH3 3 1 Trigonal sp3


pyramid
SF6 6 0 Octahedral sp3d2

BrF5 5 1 Square pyramid sp3d2

H2O 2 2 Bent sp3

PF5 5 0 Trigonal sp3d


bipyramid
BCl3 3 0 Trigonal planar sp2

23.

a. Ethane is single covalent bonded, sp3 hybridised.


Ethene is double bonded, sp2 hybridisation, Thus shorter bond length.

b. H2O molecules are associated to each other using strong H bonds. Since associated they are in liquid
state. In H2S there is no H bond.

c. Axial bonds are longer and weaker than equatorial bonds.


d. Resonance, partial double bond character
e. The resultant of 1st and 2nd dipoles cancel out the third dipole.

Prepared by Ms. Jasmin Joseph Checked by : HOD - SCIENCE

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