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CHEMICAL BONDING AND MOLECULAR STRUCTURE

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14 views

CHEMICAL BONDING AND MOLECULAR STRUCTURE

Uploaded by

sareenniyati85
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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CHEMICAL BONDING AND MOLECULAR STRUCTURE

1) Draw atomic overlap diagram of Methane, Ethane, Ethene , Acetylene .


2) Calculate the formal charge on each atom in Nitrite ion , carbonate ion , ozone ,
ammonium ion , Hydronium ion .
3) Calculate Formal charge on S in HSO4- .
4) Out of MgO and NaCl , which has higher lattice energy and why ?
5) Why is NaCl bad conductor of electricity in the solid state?
6) Write Lewis dot symbol to show electron transfer between the following atoms to form
cations and anions :
a) Na and Cl b) Ca and O c ) K and S
7) Why does NaCl give a white precipitate with AgNO3 solution but CCl4 does not ?
8) Give one example each of molecules which have the following geometries?
a) Linear b) Trigonal bipyramidal c) Tetrahedral
9) Although F is more electronegative than Cl yet the diploe moment of NH3 is higher than
that of NF3 . Why ?
10) Arrange the following molecules in decreasing order of Bond angles :
a) SF6 , CCl4 , H2O , NH3 b) AlCl3 , H2S , BeH2 , H2O
11) Out of sigma and π bond , which one is stronger and why ?
12) Give one basic difference between σ and π bond .
13) Why CO2 and BF3 have zero dipole moments ?
14) Calculate the total number of sigma and π bonds in the following molecules –
a) CH3CH2OH b) CH3COOH c) CH2=CH-CH2CHO d) C2H2
15) Arrange the following carbon atoms numbered C-1 , C-2 and C- 3 in the decreasing order
of s- character

16) CO2 is non polar while H2O is polar . What conclusions do you draw about their structures
from these ?
17) Which type of hybridization explain the trigonal pyramidal shape of SF4 .
18) Write the full form of LCAO .
19) Explain why N2 has greater bond dissociation energy than N2+ whereas O2 has lesser bond
dissociation energy than O2+ .
20) Why is the energy of π2px and π2py Mos lower than σ2pz MO in N2 molecule ?
21) List two main conditions for forming Hydrogen Bonds .
22) Why ice floats over water ?
23) Water has maximum density and minimum volume at 40C . Why ?
24) H2O is a liquid whereas H2S is a gas at room temperature . Why ?
25) Use the MOT to explain why the Ne2 molecule does not exist ?
26) In going from O2 to O2+ , the bond dissociation energy increases and bond length
decreases. Do we expect the same behaviour for the change of N2 to N2+ . Explain using MOT .
27) Write the hybridization state of each C atom in –

a) b) CH3COOH
28) Give an example of a compound showing Intramolecular Hydrogen Bonding .
29) Differentiate between Bonding and Antibonding Molecular Orbital .
30) The axial bonds in PCl5 are slightly elongated. Why ?
31) Show the formation of Molecular orbitals formed by the combination of
a) 2s and 2s b) 2pz and 2pz c) 2py and 2py
32) What shapes are associated with sp3d and sp3d2 hybrid orbitals ?
33) What is Hybridisation ? Discuss the bonding in acetylene molecule on the basis of
hybridization ?
34) Presence of lone pairs distorts the geometry of a molecule . Explain with example.
35) Define electronegativity .
36) Write the important conditions required for the linear combination of atomic orbitals to
form molecular orbitals.
37) Using VSEPR theory , draw the molecular structure of XeF4 indicating the location of lone
pair of electrons .Also mention the shape of molecule.
38) Both BH4- and NH4+ are isolobal . Why ?
39) Why HF has higher boiling point than HCl ?
MCQ-
1) The hybridization of C involved in acetylene is –
a) sp2 b) sp3 c) dsp2 d) sp
2) Ratio of π to σ bonds in Benzene is
a) 1:2 b) 1:6 c) 1:4 d) 1:1
3) Which of the following molecule /ion does not contain unpaired electrons ?
a) N2+ b) O22- c) O2 d) B2
4) . In which of the following molecules octet rule is not followed?
(a) NH3 (b) CH4 (c) CO2 (d) NO
5) The hybrid state of sulphur in SO2 molecule is
(a) sp2 (b) sp³ (c) sp (d) sp³d
6) Using VSEPR theory, predict the species which has square pyramidal shape
(a) SnCl2 (b) CCl4 (c) SO3 (d) BrF5
7) The maximum number of hydrogen bonds that a molecule of water can have is
(a) 1 (b) 2 (c) 3 (d) 4
8) The percentage of s- character of the hybrid orbitals in methane , ethene and ethyne are
a) 25 , 50 , 75 b) 25, 33 , 75 c) 25, 33 , 50 d) 100, 50 , 25
9) In which of the following molecules are all the bonds not equal ?
a) BF3 b) AlF3 c) NF3 d) ClF3
10) According to molecular orbital theory , which of the lists ranks the nitrogen species in
terms of increasing bond order ?
a) N22- < N2- < N2 b) N2< N22- < N2- c) N2- < N22- < N2 d) N2- < N2 < N22-
ASSERTION – REASON
a) If both assertion and reason are correct and reason is the correct explanation for assertion
b) If both assertion and reason are correct , but reason is not the correct explanation for
assertion
c) If assertion is correct but reason is incorrect
d) If assertion is incorrect but reason is correct
1) Assertion- BF3 molecule is planar while NF3 is pyramidal
Reason – N atom is smaller than B atom .
2) Assertion : The bond order of helium is always zero.
Reason : The number of electrons in bonding molecular orbital and antibonding molecular
orbital is equal.
3) Assertion : BF3 molecule has zero dipole moment.
Reason : F is electronegative and B–F bonds are polar in nature.
4) Assertion – C2H2 molecule is linear.
Reason – In C2H2 molecule carbon atoms remain unhybridized .
5) Assertion – The dipole moment helps to predict whether a molecule is polar or non- polar.
Reason – The dipole moment helps to predict the geometry of molecules.

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