CB XI Sept-2024
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mary jamesCB XI Sept-2024
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mary jamesChapter -Chemical Bonding
Q1 (i) Write the Lewis electron dot formula for CN-, SO42- , OF2 and SO3.
(ii) Arrange the following in order of increasing dipole moment and bond angle.
BF3 , HF , H2O ,
Q2 (i) On the basis of VSEPR theory predict the shape of : NH 4+, C2H2, CF4, BeF2 and PH3.
(ii) Explain why NF3 is pyramidal and while BF3 is triangular planar.
(iii) Explain why bond angle in H2O is larger than bond angle in H2S .
Q3 (i) What is the effect of π bond on the bond length and bond energy of a molecule?
(ii) How many σ and π bonds are present in benzene?
Q4 Explain why BF3 molecule has zero dipole moment although the B-H bonds are polar.
Q5 On the basis of hybridization of ‘C’ arrange the following in the increasing order of electro
negativity: CH Ξ CH , CH3-CH3 and CH2=CH2
Q6 Write the state of hybridization of C in CO32- and N in NO31- .
Q7 Explain : (i) H2O is a liquid while H2S is a gas.
(ii) NH3 has high boiling point than PH3, AsH3 and SbH3
(iii) HCl is a gas while HF is a volatile liquid at room temperature.
(iv) Ice floats on water .
(v) Water contracts when heated between 0°C and 4°C.
Q8 Why is it that in the SF4 molecule, the lone pair of electron occupies an equatorial positioning of
overall trigonal bipyramidal arrangement in preference to an axial position?
Q9 What is meant by hybridization of atomic orbitals? Describe the change in hybridization of the ‘Al’
atom in the following reaction [AlCl3 + Cl - AlCl4 -]
Q10 The dipole moment of hydrogen halides decreases from HF to HI. Explain this trend.
Q11 BH4– and NH4+ have similar shape. Explain
Q12 What is the total number of sigma and pi bonds in the following molecule-
CH3 CH= CH-CH2- C≡ CH ?
Q13 Explain why axial bonds longer as compared to equatorial bonds in PCl 5.
Q14 Which hybrid orbitals are used by the carbon atoms in the following molecules?
1 2 3 4 5 6
CH2=CH-CH2-C ≡ CH-CHO
Q15 Calculate the formal charge on each atom in NO21-.
Q16 What is dipole moment? What is its unit? What is its significance?
Q17 Write the differences between sigma and pi bonds.
Q18 What is hydrogen bonding? Name the two types of hydrogen bonding? Give example of each type
Q19 Describe the state of hybridization in PCl5. Why are the axial bonds longer as compared to
equatorial bond?
Q20 Arrange the bonds in order of increasing covalent character in the molecules:
LiF, K2O, N2 and SO2
Q21 Predict the hybrid state of central atom in the following compounds and draw its structure
showing the bond pairs and lone pairs, also predict its shape : H 2S , SF4 .
Q22 Which out of NH3 and NF3 has higher dipole moment and why?
Q23 Calculate the formal charge on all oxygen atoms in ozone molecule and justify that it is a neutral
molecule.
Q24 Use the molecular orbital theory to explain why Be 2 molecule does not exist.
Q25 How does multiplicity of bonds affect the bond strength and bond length.
Q26 Draw orbital diagram showing the formation of σ and π bond between carbon atoms in C 2H4.
Q27 Predict the hybrid state of central atom in the following compounds and draw its structure
showing the bond pairs and lone pairs, also predict its shape - ClF 3 , XeF4.
Q28 Out of ortho nitro phenol and para nitro phenol which will have greater boiling point? Why
Q29 Arrange in the increasing order of bond angle- CH 4, H2O, SF6, BF3, NH3, CO2.
Q30 Do NH3 and H2O have same or different hybridization of the central atom? Explain.
Questions on MOT
Q1 What would be the increasing order of bond length in Cl 2, O2 and N2 molecules?
Q2 What is meant by bond order? Calculate the bond order of He 2+, O2- , O2+ and O22-
molecular ions.
Q3 (i) How would the bond lengths vary in the dicarbon species C 2 , C2 - , C2 2- ?
(ii) What is the effect of the following ionisation processes on stability in C 2 and O2 ?
a) C2 C 2+ + e - b) O2 O 2+ + e -
Q4 Write the molecular orbital configuration of F2+
Q5 (i) Which of the following species is not likely to exist? He 2+, HeH, He2.
(ii) With the help of MO diagram show that Ne2 does not exist as a stable molecule.
Q6 How is bonding MO in a molecule of hydrogen different from its antibonding MO?
Q7 Find bond order of O2, O21-, O22- & O21+ and arrange these species in decreasing order of
bond lengths.
Q8 Draw Molecular orbital diagram, write molecular orbital electronic configuration and
calculate bond order of N2, N2+, N22-, N21- and discuss their magnetic property.
