THE TEACHER’S ACADEMY

TEST (CHEMICAL BONDING)

Time: Max Marks: 37

*Question 1 to 37 carry one marks (select correct option).

1. Which of the following molecules is not an exception to octet

rule?
(a) BF3 (b) PF5
(c) CO₂ (d) IF7
2. Ratio of π to σ bonds in benzene is
(a) 1:2 (b) 1:6
(c) 1:4 (d) 1:1.
3. Which of the following molecule/ion does not contain unpaired
electrons?
(a) N₂+ (b) O2−¿ 2
(C) O2 (d) B₂
4. The percentage ionic character of a bond having 1.275 Å its
length and 1.03 D its dipole moment is :
(a) 10% (b) 15%
(c) 16.83% (d) 18.8%.
5. The angle between covalent bonds is maximum in
(a) CH3 (b) BF3
(c) PF3 (d) NH3
6. CO₂ is isostructural with
(a) SnCl₂ (b) ZnCl₂
(c) HgCl₂ (d) C₂H4
7. In an octahedral structure, the pair of d-orbitals involved in d 2sp3
hybridisation is?
(a) dx2-y2,dxz (b) dz2,dzx
(c) dxy ,dyz (d) dx2-y2, dz2
8. The correct order of dipole moment is
(a) CH4 <NF3 <NH3< H2O
(b) NF3 <CH4<NH3< H2 O
(c) CH4 <NH3 <NF3<H2 O
(d) H2 O <NH3 <NF3<CH4
9. The calculated bond order in O₂- ions is
(a) 1 (b) 1½
(c) 2 (d) 2½
10. Which of the following is the electron deficient molecule?
(a) C₂H6 (b) B₂H6
(c) SiH4 (d) PH3
11. Which of the following would have a permanent dipole
moment?
a) SiF4 (c) XeF4
(b) SF4 (d) BF3
12. PCl5, molecule has the following geometry
(a) Trigonal bipyramidal (b) Octahedral
(c) Square plannar (d) Plannar triangular.
13. Which of the following is paramagnetic?
(a) O2- (b) CN-
(c) CO (d) NO+.
14. In which of the following pairs, the two species
isostructural:
(a) BrO-3 and XeO3
(b) SF4 and XeF4 (c) SO2-3 and NO-3
(d) BF3 and NF3
15. Which one of the following species does not exist under
normal conditions?
(a) B2 (b) Li2
(c) Be2+ (d) Be2
16. Intramolecular hydrogen bond exists in
(a) ortho nitrophenol (b) ethyl alcohol
(c) water (d) diethyl ether
(e) para chlorophenol
17. Which of the following species contains three bond pairs
and one lone pair around the central atom?
(a) H₂O (b) BF3
(c) NH2- (d) PCL5
18. Which of the following is a polar molecule?
(a) SiF4 (b) XeF4
(c) BF3 (d) SF4
19. Which one of the following molecules contains no π bond?
(a) SO₂ (b) NO₂
(c) CO₂ (d) H₂O
20. Maximum bond angle at nitrogen is present in which of the
following?
(a) NO2+ (c) NO2
(b) NO3- (d) NO2-
21. Which of the following molecules has the maximum dipole
moment?
(a) CO2 (b) CH4
(C) NH3 (d) NF3
22. Find the pair that has the same bond order with properties
dimagnetic and paramagnetic properties respectively
(a) F2 and 02 (b) N, and 02²-
(c) Li2 and B₂ (d) B2 and 0₂
(e) He and Ne
23. In which one of the following compounds does the central
atom obey the octet rule?
(a) XeF4 (b) XeOF₂
(c) SCI2 (d) AICI3
(e) BF3
24. Decreasing order of stability of 02 , 02-, 02+, and 022-
(a) 0₂>0₂+ > 0₂2->0₂-
(b) 02-> 0₂2- > 0₂+ > 0₂
(c) 0₂+>0₂> 02- > 022-
(d) 022->0₂->02> 02+
25. Which of the following pairs of ions are isoelectronic and
isostructural?
(a) SO32-, NO3- (b) CIO3- , SO32-
(c) CO32-, SO32- (d) ) CIO3- , CO32-
26. Which one of the following compound shows the presence
of intramolecular hydrogen bond?
(a) H₂O (b) HCN
(c) Cellulose (d)
Concentrated acetic acid
27. The hybridizations of atomic orbitals of nitrogen in NO2+ ,
NO3- , and NH4+, respectively are
(a) sp , sp3 and sp² (b) sp2, sp3 and
sp3
(c) sp, sp² and sp³ (d) sp2 ,sp and
sp3
28. The species, having bond angles of 120 is
(a)CIF3 (b) NCl3,
(c) BCI3 (d) PH3
29. The types of hybridisation on the five carbon atomsfrom
left to right in the molecule
CH3-CH=C=CH-CH3 are
(a) sp³, sp², sp², sp², sp³
(b) sp³, sp, sp², sp2, sp³
(c) sp³, sp², sp, sp², sp³
(d) sp³, sp², sp², sp, sp³
(e) sp³, sp, sp, sp², sp³
30. Which one of the following conversions involve change in
both hybridization and shape?
(a) CH4 → C₂H6 (b) NH3 → NH4+
(c) BF3 → BF4- (d) H₂O → H3O+
31. Which one of the following contains ionic, covalent and co-
ordinate bonds?
(a) NaOH (b) NaCl
(c) NaCN (d) NaNC
32. Stability of the species Li2, Li2- and Li2+, increases in the
order of
(a) Li₂- <Li₂ <Li₂+ (b) Li₂ <Li₂+ <Li₂-
(c) Li₂- < Li₂+ <Li2 (d) Li₂<Li₂- <Li₂+
33. Identify the T-shaped molecule in the following:
(a) BF3 (b) NH3
(c) NF3 (d) CIF3
(e) PCI3
34. Which one of the following molecule has the least dipole
moment?
(a) H₂O (b) BeF2
(c) NH3 (d) NF3
(e) PF3
35. Which of the following structures of a molecule is expected
to have three bond pairs and one lone pair of electrons?
(a) Trigonal Planar (b) Tetrahedral
(c) Octahedral (d) Pyramidal
36. Total number of lone pair of electrons in XeOF4 is?
(a) 0 (b) 1
(c) 2 (d) 3

37. The bond orders for O₂+ and C2 respectively are

((a) 2.5, 2 (b) 3,2

(c) 2, 2.5 (d) 2, 3

(e) 3,3