CHEMISTRY

BOOKS - VK JAISWAL CHEMISTRY (HINGLISH)

CHEMICAL BONDING (BASIC)

Level 1

1. The correct order of boiling point is :

A. I > II > III

B. III > II > I

C. II > I > III

D. III > I > II

Answer: B

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2. Which of the following is not true about H 2

O molecule ?

A. The molecule has μ = 0

B. The molecule can act as a base

C. Shows abnormally high boiling point in comparison to the hydrides

of other elements of oxygen group

D. The molecule has a bent shape

Answer: A

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3. The boiling points at atmospheric pressure of H F , H2 S, N H3 can be

arranged in the following order :

A. H F > N H3 > H2 S

B. H F > H2 S > N H3

C. H F < H2 S < N H3

D. H F < N H3 < H2 S

Answer: A

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4. The correct order of strength of H − bond in the following compound

A. H 2
O > H2 O 2 > H F > H2 S

B. H F > H2 O 2 > H2 O 2 > H2 S

C. H F > H2 O > H2 S > H2 O 2

D. H F > H2 O > H2 O 2 > H2 S

Answer: D

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5. Which compound has electrovalent, covalent, co-ordinate as well as

hydrogen bond ?

A. [Cu(H 2
O) ]SO4 . H2 O
4

B. [Zn(H 2
O) ]SO4 . H2 O
6

C. [F e(H 2
O) ]SO4 . H2 O
6

D. [F e(H 2
O) ]Cl3
6

Answer: A

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6. Which statement is correct ?

A. m.p. of H2 O, N H3 are maximum in their respective group due to

intermolecular H-Bonding

B. b.p. of CH4 out of CH4 , SiH4 , GeH4 and SnH4 is least due to

weak intermolecular force of attraction

C. formic acid forms dimer by H-bonding

D. all are correct

Answer: D

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7. Which of the following molecules are expected to exhibit

intermolecular H-bonding ?

(I) Acetic acid ((II) o-nitrophenol (III) m-nitrophenol (IV)o-boric acid

Select correct alternate :

A. I, II, III

B. I,II,IV

C. I,III,IV

D. II,III,IV

Answer: C

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8. Which of the following compounds can form H-bonding with each

other ?

A. CH 3
COOH and H2 O

B. Phenol and CH 4

C. CH F and acetone
3

D. P H and HF
3

Answer: A
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9. BF3 and N F3 both are covalent compounds but N F3 is polar

whereas BF is non-polar. This is because :

3

A. Nitrogen atom is smaller than boron atom

B. N-F bond is more polar than B-F bond

C. N F is pyramidal whereas BF is planar triangular

3 3

D. BF is electron deficient whereas N F is not

3 3

Answer: C

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10. Dipole moment of N F is smaller than :

3

A. N H 3

B. CO 2
C. BF 3

D. CCl 4

Answer: A

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11. Which of the following molecules will have polar bonds but zero dipole

moment?

A. O 2

B. CH Cl 3

C. CF 4

D. none of these

Answer: C

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12. Which has maximum dipole moment?

A.

B.

C.

D.
Answer: B

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13. Which of the following compound is planar and non-polar ?

A. XeO 4

B. SF 4

C. XeF 4

D. CF 4

Answer: C

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14. H 2
O has a net dipole moment while BeF2 has zero dipole moment

because :
A. F is more electronegativity than oxygen

B. Be is more electronegativity than oxygen

C. H 2
O molecule is linear and BeF is bent
2

D. BeF molecule is linear and H

2 2
O is bent

Answer: D

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15. Correct set of species with zero dipole moment is :

(i) CO 2
(ii)COCl2 (iii)CH2 Cl2 (iv)BCl3

A. I and iv

B. ii and iv

C. iii and iv

D. I, iii and iv

Answer: A
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16. Which pair of molecules are polar species ?

A. CO 2
and H2 O

B. BF 3
and P Cl3

C. SO 2
and SCl2

D. CS 2
and SO3

Answer: C

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17. In which molecule does the chlorine have the most positive partial

charge?

A. HCl

B. BrCl
C. Ocl 2

D. SCl 2

Answer: C

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18. Which of the following attraction is strongest ?

A.

B.

C.

D.

Answer: D

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19. Which is distilled first ?

A. Liquid H 2

B. Liquid CO 2

C. Liquid O 2

D. Liquid N 2

Answer: A

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20. Molecular size of ICI and Br 2 is nearly same but b. pt. of ICI is

about 40 higher than BR . This is due to :

∘
2

A. Icl bond is stronger than Br-Br bond

B. IE of iodine < IE of bromine

C. Icl is polar while Br is nonpolar

2

D. I has larger size than Br

Answer: C

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21. Which of the following order of molecular force of attraction among

given species is incorect ?

A. H I > H Br > Cl2

B. CH 3
Cl > CCl4 > CH4

C. n-pentane > iso-pentane > neo-pentane

D. OH 2
> O(CH3 )
2
> OBr 2

Answer: D

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22. Which gas should not be collected over water because of its high

solubility in water ?
A. H 2

B. N 2

C. CH 4

D. H Cl

Answer: D

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23. Low melting point is expected for a solid :

A. Ionic solid

B. Metallic solid

C. Molecular solid

D. Covalent solid

Answer: C

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24. Which substance has the strongest London dispersion forces ?

A. SiH 4

B. CH 4

C. SnH 4

D. GeH 4

Answer: C

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25. Which of the following compounds has the lowest boiling point ?

A. HF

B. HCl

C. HBr
D. HI

Answer: B

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26. When the substances Si, KCl, CH3 OH and C2 H6 are arranged in

order of increasing melting point, what is the correct order ?

A. Si, KCl, CH 3
OH , C2 H6

B. CH 3
OH , C2 H6 , Si, KCl

C. KCl, Si, C 2
H6 , CH3 OH

D. C2
H6 , CH3 OH , KCl, Si

Answer: D

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27. Which substance has the highest melting point ?

A. CO

B. CO 2

C. SiO 2

D. P 2
O5

Answer: C

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28. How many 2

sp and sp-hybridised carbon atoms are present

respectively in the following compound ?

A. 4,2

B. 6,0

C. 3,3

D. 5,1

Answer: B

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29. Which of the following is a correct set with respect to molecule,

hybridization, and shape?

A. BeCl 2
, sp
2
, linear

B. BeCl 2
, sp
2
, triangular planar

C. BCl 3
, sp
2
, triangular planar

D. BCl 3
, sp
3
, tetrahedral

Answer: C

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30. Hybridisation of central atom in ICl +

2
is

A. dsp 2

B. sp

C. sp2

D. sp3
Answer: D

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31. The state of hybridization of the central atom is not the same as in the

others :

A. B in BF 3

B. O in H 3
O
+

C. N in N H 3

D. P in P Cl 3

Answer: A

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32. The number of sp 2

− s sigma bonds in benzene are
A. 3

B. 6

C. 12

D. none of these

Answer: B

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33. The hybridization of the central atom will change when :

A. N H combines with H
3
+

B. H 3
BO3 combines withOH −

C. N H forms N H
3
−

D. H 2
O combines with H +

Answer: B

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34. CH 3
− CH2 − CH = CH2 has hybridisation :

A. sp, sp, sp 2
, sp
2

B. sp 3 3
, sp , sp , sp
2

C. sp 3 3
, sp , sp , sp
2 2

D. sp 3 2
, sp , sp , sp
2

Answer: C

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35. The state of hybridization of xenon of XeF is 6

A. sp 3
d
3

B. sp 3
d
2

C. sp 3
d
D. sp
3

Answer: A

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36. During the complete combustion of methane CH4 , what change in

hybridisation does the carbon atom undergo ?

A. sp to sp
3

B. sp
3
to
2
sp

C. sp to sp
2

D. sp
2
to
3
sp

Answer: A

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37. The hybridisation of central iodine atom in IF5 , I
3
−
and I
3
+
are

respectively :

A. sp 3 2
d , sp d, sp
3 3

B. sp 3 3
d, sp d, sp
3

C. sp 3 2 3
d , sp d , sp
2 3

D. sp 3 3
d, sp d , sp
2 3

Answer: A

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38. In which of the following combination hybridisation of central atom

( ∗ ) does not change ?

A. H 2
O + CO2

B. H 3
BO3 + OH
−

C. BF 3
+ N H3
D. none of these

Answer: C

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39. Which of the following species has used both axial set of d-orbitals in

hybridisation of central atom ?

A. P Br +

B. P Cl
−

C. ICl4
−

D. none of these

Answer: C

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40. Which bonds are formed by a carbon atom with sp -hybridisation ?
2

A. 4π-bonds

B. 2π-bonds and 2σ-bonds

C. 1π-bonds and 3σ-bonds

D. 4σ-bonds

Answer: C

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41. What are the hybridisation of the carbon atoms labeled C1 and C2 ,

respectively in glycine ?
C1 C2
A. 2 2
sp sp

C1 C2
B. 2 3
sp sp

C1 C2
C. 3 2
sp sp

C1 C2
D. 3 3
sp sp

Answer: C

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42. The H-O-H bond angles in H 3

O
+
are approximately 107 . The orbitals
∘

used by oxygen in these bonds are best described as :

A. p-orbitals

B. sp-hybrid orbitals

C. sp -hybrid orbital
2

D. sp -hybrid orbital
3

Answer: D
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43. Which pair of elements can form multiple bond with itself and oxygen

A. F,N

B. N, Cl

C. N,P

D. N,C

Answer: D

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44. Which of the following is a covalent compound ?

A. Al2
O3

B. AlF 3
C. AlCl 3

D. Al2
(SO4 )
3

Answer: C

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45. Which of the following is an example of super octet molecule ?

A. ClF 3

B. P Cl 5

C. IF 7

D. All the three

Answer: D

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46. Which of the following molecule is theoretically not possible ?

A. SF 4

B. OF 2

C. OF 4

D. O 2
F2

Answer: C

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47. The phosphate of a metal has the formula M H P O4 . The formula of

its chloride would be

A. MCl

B. M Cl 2

C. M Cl 3

D. M 2
Cl3
Answer: B

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48. The compound that has the higest ionic character associated with the

X-Cl bond is :

A. P Cl 5

B. BCl 3

C. CCl 4

D. SiCl 4

Answer: D

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49. The bond having the highest bond energy is :

A. C = C

B. C = S

C. C = O

D. P = N

Answer: C

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50. Which of the following species in neither hypervalent nor hypovalent

A. ClO
−

B. BF 3

C. SO 2−

D. CO 2−

Answer: D
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51. In which of the following species central atom is NOT surrounded by

exactly 8 valence electrons ?

A. BF 4
−

B. N Cl 3

C. P Cl
+

D. SF 4

Answer: D

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52. Which atom can have more than eight valence electrons when it is

forming covalent bonds ?

A. H
B. N

C. F

D. Cl

Answer: D

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53. Which bond is expected to be the least polar?

A. O-F

B. P-F

C. Si-N

D. B-F

Answer: A

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54. Which set contains only covalently bonded molecules ?

A. BCl 3
, SiCl4 , P Cl3

B. N H 4
Br, N2 H4 , H Br

C. I
2
, H2 S, N aI

D. Al, O 3
, As4

Answer: A

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55. Which molecule does not exist ?

A. OF 2

B. OF 4

C. SF 2

D. SF 4
Answer: B

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56. Solid NaCl is a bad conductor of electricity because

A. in solid NaCl there are no ions

B. solid NaCl is covalent

C. in solid NaCl there is no mobility of ions

D. in solid NaCl there are no electrons

Answer: C

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57. An ionic compound A +

B
−
is most likely to be formed when :

A. the ionization energy of A is high and electron affinity of B is low

B. the ionization energy of A is low and electron affinity of B is high

C. both, the ionization energy of A and electron affinity of B are high

D. both, the ionization energy of A and electron affinity of B are low

Answer: B

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58. A compound contains three elements A, B and C , if the oxidation

number of A = + 2 B = + 5 and C = − 2 then possible formula of

the compound is

A. A 3
(B 4 C)
2

B. A 3
(BC4 )
2

C. A 2
(BC3 )
2

D. ABC 2

Answer: B
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59. Which pair of atoms form strongest ionic bond ?

A. Al and As

B. Al and N

C. Al and Se

D. Al and O

Answer: D

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60. The correct order of increasig C − O bond length of

CO, CO
2−

3
, CO2 is

A. CO 2−

3
< CO2 < CO

B. CO 2
< CO
2−

3
< CO
C. CO < CO
2−

3
< CO2

D. CO < CO2 < CO

2−

Answer: A

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61. Resonance structures can be written for.

A. O 3

B. N H 3

C. CH 4

D. H 2
O

Answer: A

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62. The correct order of Cl-O bond order is :

A. ClO − − − −
< ClO < ClO < ClO
3 4 2

B. ClO − − − −
< ClO < ClO < ClO
4 3 2

C. ClO − − − −
< ClO < ClO < ClO
2 3 4

D. ClO −

4
< ClO
−

3
< ClO
−

3
< ClO
−

Answer: C

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63. How many resonance structures can be drawn for the nitrate ion,

NO
−

3
?

A. 1

B. 2

C. 3

D. 4
Answer: C

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64. Among given species identify the isostructural pairs :

A. [N F 3
and BF3 ]

B. [BF
− +
and N H ]
4 4

C. [BCl 3
and BrCl3 ]

D. [N H 3
and N O
−

3
]

Answer: B

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65. 0.01 mole H3 P O x is completely neutralised by 0.56 gram of KOH

hence :
A. x=3 and given acid is dibasic

B. x=2 and given acid is monobasic

C. x=3 and given acid is monobasic

D. x=4 and given acid forms three series of salt

Answer: B

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66. The solid P Cl exists as

5

A. P Cl 5

B. P Cl
+ −
Cl
4

C. P Cl 4
+
P Cl
−

D. P Cl 5
. Cl2

Answer: C

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67. The ratio of σ − bond and π − bond in tetracryano ethylene is :

A. 2 : 1

B. 1 : 1

C. 1 : 2

D. none of these

Answer: B

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68. The bonds present in N 2

O5 are .

A. only ionic

B. only covalent

C. covalent and co-ordinate

D. covalent and ionic

Answer: C

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69. The pair of species with similar shape is

A. P Cl 3
, N H3

B. CF 4
, SF4

C. P bCl 2
, CO2

D. P F 5
, IF5

Answer: A

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70. Which of the following statements is correct in the context of the

allene molecule, C 3
H4 ?

A. The central carbon is sp hybridized

B. The terminal carbon atoms are sp hybridized

2

C. The planes containing the CH2 groups are mutually perpendicular

to permit the formations two separate π-bonds

D. all are correct

Answer: D

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71. Number of S-S bond is H 2

Sn O6 :

A. n

B. (n-1)

C. (n-2)
D. (n+1)

Answer: B

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72. How many S-S bonds, S-O-S bonds, σ-bonds, π-bonds are present in

trimer of sulphur trioxide ?

A. 0,3,16,2

B. 0,3,12,6

C. 0,6,12,16

D. 0,4,12,6

Answer: B

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73. Number of identical Cr-O bonds in dichromate ion Cr is :
2−
2
O
7

A. 4

B. 6

C. 7

D. 8

Answer: B

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74. The nodal plane in the π-bond of ethene is located in:

A. the molecular plane

B. a plane parallel to the molecular plane

C. a plane perpendicular to the molecular plane which bisects the

carbon-carbon σ bond at right angle

D. a plane perpendicular to the molecular plane which contains the

carbon-carbon bond

Answer: A

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75. Which of the following are isoelectronic and isostructural ?

− 2− −
NO , CO , ClO , SO3
3 3 3

A. N O −

3
, CO
2−

B. SO 3
, NO
−

C. ClO −

3
, CO
2−

D. CO 2−

3
, ClO
−

Answer: A

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76. In the electronic structure of H2 SO4 , the total number of unshared

electrons is

A. 20

B. 16

C. 12

D. 8

Answer: B

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77. Which of the following xenon compound has the same number of lone

pairs as in I ? (near central atom)

−

A. XeO 4

B. XeF 4

C. XeF 2
D. XeO 3

Answer: C

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78. The geometry of XeF +

3
is

A. Trigonal planar

B. Pyramidal

C. Bent T-shpae

D. See-saw

Answer: C

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79. Which of the following shape are not possible for possible value of n

in XeF molecule ?
n

A. Linear

B. Square planar

C. Trigonal planar

D. Capped octahedral

Answer: C

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80. BeCl is not isostructural with

2

A. ICl 2
−

B. C2
H2

C. XeF 2

D. GeCl 2
Answer: D

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81. Which statement is true about the most stable Lewis structure for

CS2 ?

A. There are no lone pairs in molecule

B. All bonds are double bonds

C. The central atom does not have an octet of electrons

D. A sulfur atom must be the central atom for the structure to be

stable

Answer: B

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82. Shape of the compounds XeF +

3
and XeF +

5
are respectively
A. Square pyramidal, T-shpaed

B. Bent-T-shape, square pyramidal

C. See-saw, square pyramidal

D. Square pyramidal, see -saw

Answer: B

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83. In which of the following species maximum atom can lie in same plane

A. XeF 2
O2

B. P Cl 5

C. AsH 4
+

D. XeF 4

Answer: D
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84. Correct statement regarding molecules SF 4

, CF4 and XeF4 are :

A. 2,0 and 1 lone pairs of central atom respectively

B. 1,0 and 1 lone pairs of central atom respectively

C. 0,0 and 2 lone pairs of central atom respectively

D. 1,0 and 2 lone pairs of central atom respectively

Answer: D

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85. The geometrical arrangement and shape of I 3

−
are respectively

A. trigonal bipyramidal geometry, linear shape

B. hexagonal geometry, T-shape

C. triangular planar geometry, triangular shape

D. tetrahedral geometry, pyramidal shape

Answer: A

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86. Which of the following statements is incorrect for P Cl ?

5

A. Its three P-Cl bond lengths are equal

B. It involves sp d hybridization
3

C. It has an regular geometry

D. Its shape is trigonal bipyramidal

Answer: C

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87. Molecular shape of SF 4

, CF4 and XeF are
4
A. the same with 2,0 and 1 lone pair of electrons respectively

B. the same with 1,1 and 1 lone pair of electrons respectively

C. the same with 0m1 and 2 lone pair of electrons respectively

D. the same with 1,0 and 2 lone pair of electrons respectively

Answer: D

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88. The structure of the noble gas compound XeF is :4

A. square planar

B. distorted tetrahedral

C. tetrahedral

D. octahedral

Answer: A

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89. The molecule exhibiting maximum number of non-bonding electron

pairs (l.p.) around the central atom is :

A. XeOF 4

B. XeO 2
F2

C. XeF −

D. XeO 3

Answer: C

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90. Which is the following pairs of species have identical shapes ?

A. N O +

2
and N O
−

B. P Cl 5
and BrF5

C. XeF
−
4
and ICl
4
D. T eCl 4
and XeO4

Answer: C

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91. The shapes of XeF 4

, XeF
−

5
and SnCl2 are :

A. octahedral, trigonal bipyramidal and bent

B. square pyramidal, pentagonal planar and linear

C. square planar, pentagonal planar and angular

D. see-saw, T-shaped and linear

Answer: C

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92. Which is not correctly matched ?

A. XeO -Trigonal bipyramidal
3

B. ClF - bent T-shape

3

C. XeOF - Square pyramidal

4

D. XeF - Linear shape

2

Answer: A

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93. Amongst NO
−

3
, AsO
3−

3
, CO
2−

3
, ClO
−

3
, SO
2−

3
and BO
2−

3
, the non-

planar species are :

A. CO 2−

3
, SO
2−

3
, BO
3−

B. AsO 3−

3
, ClO
−

3
, SO
2−

C. N O −

3
, CO
2−

3
, BO
3−

D. SO 2−

3
, NO
−

3
, BO
3−

Answer: B
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94. The geometry of ammonia molecule can be best described as :

A. Nitrogen at one vetex of a regular tetrahedron, the other three

vertices being occupied by three hydrogens

B. Nitrogen at the centre of the tetrahedron, three of the vertices

being occupied by three hydrogens

C. Nitrogen at the centre of an equilateral triangle, three corners

being occupied by three hydrogens

D. Nitrogen at the junction of a T, three open ends being occupied by

three hydrogens

Answer: B

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95. Which molecular geometry is least likely to result from a trigonal

bipyramidal electron geometry ?

A. Trigonal planar

B. See-saw

C. Linear

D. T-shpaed

Answer: A

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96. Give the correct order of initials T or F for following statements. Use T

if statement is true and F if it is falese :

(I) The order of repulsion between different pair of electron is

Ip − Ip > Ip − bp > bp − bp

(II) In general, as the number o flone pair of electron on central atom

increases, value of bond angle from normal bond angle also increases
(III) The number of lone pair on O in H 2
O is 2 while on N in N H is 1
3

(IV ) The structures of xenon fluorides and xenon oxyfluorides could not

be explained on the basis of VSEPR theory

A. T T TF

B. TFTF

C. TFT T

D. TF F F

Answer: B

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97. Which species is planar ?

A. CO 2−

B. SO 2−

C. ClO −

3
D. BF
−

Answer: A

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98. What is the geometry of the IBr −

2
ion ?

A. Linear

B. Bent shape with bond angle of about 90 ∘

C. Bent shape with bond angle of about 109 ∘

D. Bent shape with bond angle of about 120 ∘

Answer: A

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99. What is the shape ClF molecule ?

3
A. Trigonal planar

B. Trigonal pyramidal

C. T-shaped

D. Tetrahedral

Answer: C

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100. Which species below has the same general shape as N H ?

3

A. SO 2−

B. CO 2−

C. N O −

D. SO 3

Answer: A

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101. According to VSEPR theory, in which species do all the atoms lie in the

same plane ?

+ −
1. CH 2. CH
3 3

A. 1 only

B. 2 only

C. both 1 and 2

D. neither 1 nor 2

Answer: A

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102. Which of the following species / molecules does not have same

number of bond pairs and lone pairs ?

A. OCN −
B. H 2
O

C. C2
H2 Cl2

D. O 3

Answer: D

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103. Least stable hydride is

A. stannane

B. silane

C. plumbane

D. germane

Answer: C

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104. The lowest O-O bond length in the following molecule is :

A. O 2
F2

B. O 2

C. H 2
O2

D. O 3

Answer: B

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105. The fluorine molecules is formed by :

A. p-p orbitals (sideways overlap)

B. p-p orbitals (end -to -end overlap)

C. sp-sp orbitals

D. s-s orbitals
Answer: B

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106. Which of the following leads to bonding?

A.

B.

C.

D.

Answer: B

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107. Which of the following overlaps is incorrect (assuming Z-axis is

internucler axis ) ?

(A)2Py + 2py → π - Bond formation (B)2px + 2px → σ - Bond

formation

(C ) 33d xy + 3dpxy → π - Bond formation (D)2s + 2py → π - Bond

formation

(E ) 3d xy + 3d xy → δ - Bond formation (F )2px + 2px → σ -Bond

formation

A. A,B,C

B. C,F

C. B,E

D. B,C,D

Answer: D

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108. Which of the following overlapping is not present in XeO3 molecule

A. sp 3
+ px

B. sp 3
+ py

C. d xz
+ px

D. sp 3
+ s

Answer: D

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109. How many sigma bonds are in a molecule of diethyl ether,

C2 H5 OC2 H5 ?

A. 14

B. 12

C. 8
D. 16

Answer: A

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110. The lattice energies of KF, KCl, KBr and KI follow the order :

A. KF > KCl > KBr > KI

B. KI > KBr > KCl > KF

C. KF > KCl > KI > KBr

D. KI > KBr > KF > KCl

Answer: A

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111. Which set of compounds in the following pair of ionic compounds has

the higher lattice energy ?

(i) KCl or M gO (ii)LiF or LiBr (iii)M g3 N2 or N aCl

A. KCl, LiBr, M g 3
N2

B. M gO, LiBr, M g 3
N2

C. M gO, LiF , N aCl

D. M gO, LiF , M g 3
N2

Answer: D

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112. The incorrect order of lattice energy is :

A. AlF 3
> M gF2

B. Li 3
N > Li2 O

C. N aCl > LiF

D. T iC > ScN

Answer: C

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113. Which ionic compound has the largest amount of lattice energy ?

A. NaF

B. AlF 3

C. AlN

D. M gF 2

Answer: C

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114. Which of the following compounds has the smallest bond angle in its

molecule ?

A. OH 2

B. SH 2

C. N H 3

D. SO 2

Answer: B

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115. Maximum bond angle is present in case of

A. BBr 3

B. BCl 3

C. BF 3

D. none of these
Answer: D

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116. The correct order of H-M-H bonds angle is :

A. N H 3
< P H3 < SbH3 < BiH3

B. AsH 3
< SbH3 < P H3 < N H3

C. N H 3
< P H3 < BiH3 < SbH3

D. BiH 3
< SbH3 < AsH3 < P H3

Answer: D

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117. The correct increasing bomnd angle among BF3 , P F3 and CIF3

follow the order

A. BF 3
< P F3 < ClF3

B. P F 3
< BF3 < ClF3

C. ClF 3
< P F3 < BF3

D. BF 3
= P F3 = ClF3

Answer: C

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118. Among the following species, the least angle around the central atom

is in :

A. O 3

B. I 3
−

C. N O −

D. P H 3

Answer: D
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119. The bond angles of N H and N H are in the order .

⊕
3, NH 2
4

A. N H − +
> N H3 > N H
2 4

B. N H
+ −
> N H3 > N H
4 2

C. N H − +
3 > NH > NH
2 4

D. N H
+ −
3 > NH > NH
4 2

Answer: B

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120. The H-C-H bond angle in CH4 is109.5

∘
, due to lone pair repulsion,

the H-O-H angle in H 2O will :

A. remain the same

B. increase
C. decrease

D. become 180 ∘

Answer: C

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121. The molecule having the largest bond angle is :

A. H 2
O

B. H 2
S

C. H 2
Se

D. H 2
Te

Answer: A

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122. The compound M X4 is tetrahedral. The number of ∠XM X angles

formed in the compound is

A. three

B. four

C. five

D. six

Answer: D

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123. Which of the following is the correct order for increasing bond angle

A. N h 3
< P H3 < AsH3 < SbH3

B. H 2
O < OF2 < Cl2 O

C. H 2
Te
+
< H3 Se
+
< H3 S
+
< H3 O
+
D. BF 3
< BCl3 < BBr 3 < BI3

Answer: C

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124. The correct order of boiling point is :

A. I > II > III

B. III > II > I

C. II > I > III

D. III > I > II

Answer: B

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125. Which of the following is not true about H 2
O molecule ?

A. The molecule has μ = 0

B. The molecule can act as a base

C. Shows abnormally high boiling point in comparison to the hydrides

of other elements of oxygen group

D. The molecule has a bent shape

Answer: A

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126. The boiling points at atmospheric pressure of H F , H2 S, N H3 can

be arranged in the following order :

A. H F > N H3 > H2 S

B. H F > H2 S > N H3

C. H F < H2 S < N H3
D. H F < N H3 < H2 S

Answer: A

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127. The correct order of strength of H − bond in the following

compound :

A. H 2
O > H2 O 2 > H F > H2 S

B. H F > H2 O 2 > H2 O 2 > H2 S

C. H F > H2 O > H2 S > H2 O 2

D. H F > H2 O > H2 O 2 > H2 S

Answer: D

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128. Which compound has electrovalent, covalent, co-ordinate as well as

hydrogen bond ?

A. [Cu(H 2
O) ]SO4 . H2 O
4

B. [Zn(H 2
O) ]SO4 . H2 O
6

C. [F e(H 2
O) ]SO4 . H2 O
6

D. [F e(H 2
O) ]Cl3
6

Answer: A

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129. Which statement is correct ?

A. m.p. of H2 O, N H3 are maximum in their respective group due to

intermolecular H-Bonding

B. b.p. of CH4 out of CH4 , SiH4 , GeH4 and SnH4 is least due to

weak intermolecular force of attraction

C. formic acid forms dimer by H-bonding

D. all are correct

Answer: D

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130. Which of the following molecules are expected to exhibit

intermolecular H-bonding ?

(I) Acetic acid ((II) o-nitrophenol (III) m-nitrophenol (IV)o-boric acid

Select correct alternate :

A. I, II, III

B. I,II,IV

C. I,III,IV

D. II,III,IV

Answer: C
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131. Which of the following compounds can form H-bonding with each

other ?

A. CH 3
COOH and H2 O

B. Phenol and CH 4

C. CH F and acetone
3

D. P H and HF
3

Answer: A

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132. BF3 and N F3 both are covalent compounds but N F3 is polar

whereas BF is non-polar. This is because :

3

A. Nitrogen atom is smaller than boron atom

B. N-F bond is more polar than B-F bond

C. N F is pyramidal whereas BF is planar triangular

3 3

D. BF is electron deficient whereas N F is not

3 3

Answer: C

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133. Dipole moment of N F is smaller than :

3

A. N H 3

B. CO 2

C. BF 3

D. CCl 4

Answer: A

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134. Which of the following molecules will have polar bonds but zero

dipole moment ?

A. O 2

B. CH Cl 3

C. CF 4

D. none of these

Answer: C

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135. Which has maximum dipole moment ?

A.
B.

C.

D.

Answer: B

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136. Which of the following compound is planar and non-polar ?

A. XeO 4

B. SF 4

C. XeF 4

D. CF 4

Answer: C

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137. H 2
O has a net dipole moment while BeF2 has zero dipole moment

because :

A. F is more electronegativity than oxygen

B. Be is more electronegativity than oxygen

C. H 2
O molecule is linear and BeF is bent
2

D. BeF molecule is linear and H

2 2
O is bent

Answer: D
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138. Correct set of species with zero dipole moment is :

(i) CO 2
(ii)COCl2 (iii)CH2 Cl2 (iv)BCl3

A. i and iv

B. ii and iv

C. iii and iv

D. I, iii and iv

Answer: A

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139. Which pair of molecules are polar species ?

A. CO 2
and H2 O

B. BF 3
and P Cl3
C. SO 2
and SCl2

D. CS 2
and SO3

Answer: C

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140. In which molecule does the chlorine have the most positive partial

charge?

A. H Cl

B. BrCl

C. OCl 2

D. SCl 2

Answer: C

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141. Which of the following attraction is strongest ?

A.

B.

C.

D.

Answer: D

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142. Which is distilled first ?

A. Liquid H 2

B. Liquid CO 2

C. Liquid O 2

D. Liquid N 2
Answer: A

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143. The molecular size of Icl and Br is approximately same, but b.p. if Icl
2

is about 40 ∘
C higher than that of Br . It is because :
2

A. Icl bond is stronger than Br-Br bond

B. IE of iodine < IE of bromine

C. Icl is polar while Br is nonpolar

2

D. I has larger size than Br

Answer: C

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144. Which of the following order of molecular force of attraction among

given species is incorect ?

A. H I > H Br > Cl2

B. CH 3
Cl > CCl4 > CH4

C. n-pentane > iso-pentane > neo-pentane

D. OH 2
> O(CH3 )
2
> OBr 2

Answer: D

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145. Which gas should not be collected over water because of its high

solubility in water ?

A. H 2

B. N 2

C. CH 4

D. H Cl

Answer: D
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146. Low melting point is expected for a solid :

A. Ionic solid

B. Metallic solid

C. Molecular solid

D. Covalent solid

Answer: C

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147. Which substance has the strongest London dispersion forces ?

A. SiH 4

B. CH 4

C. SnH 4
D. GeH 4

Answer: C

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148. Which of the following compounds has the lowest boiling point ?

A. H F

B. H Cl

C. H Br

D. H I

Answer: B

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149. When the substances Si, KCl, CH3 OH and C2 H6 are arranged in

order of increasing melting point, what is the correct order ?

A. Si, KCl, CH 3
OH , C2 H6

B. CH 3
OH , C2 H6 , Si, KCl

C. KCl, Si, C 2
H6 , CH3 OH

D. C 2
H6 , CH3 OH , KCl, Si

Answer: D

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150. Which substance has the highest melting point ?

A. CO

B. CO 2

C. SiO 2

D. P 2
O5
Answer: C

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151. How many sp

2
and sp-hybridised carbon atoms are present

respectively in the following compound ?

A. 4,2

B. 6,0

C. 3,3

D. 5,1
Answer: B

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152. Which one of the following is the correct set with respect to

molecule, hybridization and shape ?

A. BeCl 2
, sp
2
, linear

B. BeCl 2
, sp
2
, triangular planar

C. BCl 3
, sp
2
, triangular planar

D. BCl 3
, sp
3
, tetrahedral

Answer: C

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153. Hybridisation of central atom in ICl +

2
is
A. dsp 2

B. sp

C. sp2

D. sp3

Answer: D

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154. The state of hybridization of the central atom is not the same as in

the others :

A. B in BF 3

B. O in H 3
O
+

C. N in N H 3

D. P in P Cl 3

Answer: A
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155. The number of sp 2

− s sigma bonds in benzene are

A. 3

B. 6

C. 12

D. none of these

Answer: B

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156. The hybridization of the central atom will change when :

A. N H combines with H
3
+

B. H 3
BO3 combines withOH −

C. N H forms N H
3
−

2
D. H 2
O combines with H +

Answer: B

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157. CH 3
− CH2 − CH = CH2 has hybridisation :

A. sp, sp, sp 2
, sp
2

B. sp 3 3
, sp , sp , sp
2

C. sp 3 3
, sp , sp , sp
2 2

D. sp 3 2
, sp , sp , sp
2

Answer: C

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158. What is the state of hybridisation of Xe in cationic part of solid XeF 6

A. sp
3
d
3

B. sp
3
d
2

C. sp
3
d

D. sp
3

Answer: B

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159. During the complete combustion of methane CH4 , what change in

hybridisation does the carbon atom undergo ?

A. sp to sp
3

B. sp
3
to
2
sp

C. sp to sp
2

D. sp
2
to
3
sp

Answer: A
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160. The hybridisation of central iodine atom in IF5 , I

3
−
and I
3
+
are

respectively :

A. sp 3 2 3
d , sp d, sp
3

B. sp 3 3
d, sp d, sp
3

C. sp 3 2 3
d , sp d , sp
2 3

D. sp 3 3
d, sp d , sp
2 3

Answer: A

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161. In which of the following combination hybridisation of central atom

( ∗ ) does not change ?

A. H 2
O + CO2
∗

B. H 3
BO3 + OH
−

C. BF 3
+ N H3

D. none of these

Answer: C

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162. Which of the following species used both axial set of d-orbitals in

hybridisation of central atom ?

A. P Br
+

B. P Cl
−

C. ICl
−

D. none of these

Answer: C

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163. Which bonds are formed by a carbon atom with sp -hybridisation ?
2

A. 4π-bonds

B. 2π-bonds and 2σ-bonds

C. 1π-bonds and 3σ-bonds

D. 4σ-bonds

Answer: C

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164. What are the hybridisation of the carbon atoms labeled C1 and C2 ,

respectively in glycine ?
C1 C2
A. 2 2
sp sp

C1 C2
B. 2 3
sp sp

C1 C2
C. 3 2
sp sp

C1 C2
D. 3 3
sp sp

Answer: C

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165. The H-O-H bond angles in are approximately . The

+ ∘
H3 O 107

orbitals used by oxygen in these bonds are best described as :

A. p-orbitals
B. sp-hybrid orbitals

C. sp -hybrid orbital
2

D. sp -hybrid orbital
3

Answer: D

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166. Which pair of elements can form multiple bond with itself and

oxygen ?

A. F , N

B. N , Cl

C. N , P

D. N , C

Answer: D

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167. Which of the following is a covalent compound ?

A. Al2
O3

B. AlF 3

C. AlCl 3

D. Al2
(SO4 )
3

Answer: C

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168. Which of the following is an example of super octet molecule ?

A. ClF 3

B. P Cl 5

C. IF 7

D. All the three

Answer: D

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169. Which of the following molecule is theoretically not possible ?

A. SF 4

B. OF 2

C. OF 4

D. O 2
F2

Answer: C

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170. The phosphate of a metal has the formula M H P O4 . The formula of

its chloride would be

A. M Cl

B. M Cl 2

C. M Cl 3

D. M 2
Cl3

Answer: B

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171. The compound that has the higest ionic character associated with

the X-Cl bond is :

A. P Cl 5

B. BCl 3

C. CCl 4

D. SiCl 4

Answer: D
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172. The bond having the highest bond energy is :

A. C = C

B. C = S

C. C = O

D. P = N

Answer: C

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173. Which of the following species is neither hypervalent nor hypovalent

A. ClO −

B. BF 3
C. SO 2−

D. CO 2−

Answer: D

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174. In which of the following species central atom is NOT surrounded by

exactly 8 valence electrons ?

A. BF
−

B. N Cl 3

C. P Cl
+

D. SF 4

Answer: D

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175. Which atom can have more than eight valence electrons when it is

forming covalent bonds ?

A. H

B. N

C. F

D. Cl

Answer: D

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176. Which bond is expected to be the least polar?

A. O − F

B. P − F

C. Si − N

D. B − F
Answer: A

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177. Which set contains only covalently bonded molecules ?

A. BCl 3
, SiCl4 , P Cl3

B. N H 4
Br, N2 H4 , H Br

C. I
2
, H2 S, N aI

D. Al, O 3
, As4

Answer: A

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178. Which molecule does not exist ?

A. OF 2
B. OF 4

C. SF 2

D. SF 4

Answer: B

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179. Solid NaCl is a bad conductor of electricity because

A. in solid N aCl there are no ions

B. solid N aCl is covalent

C. in solid N aCl there is no mobility of ions

D. in solid N aCl there are no electrons

Answer: C

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180. An ionic compound A +
B
−
is most likely to be formed when :

A. the ionization energy of A high and electron affinity of B is low

B. the ionization energy of A is low and electron affinity of B is high

C. both, the ionization energy of A and electron affinity of B are high

D. both, the ionization energy of A and electron affinity of B are low

Answer: B

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181. A compound contains three elements A, B and C , if the oxidation

number of A = + 2B = + 5 and C = − 2 then possible formula of

the compound is

A. A 3
(B 4 C)
2

B. A 3
(BC4 )
2

C. A 2
(BC3 )
2
D. ABC 2

Answer: B

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182. Which pair of atoms form strongest ionic bond ?

A. Al and As

B. Al and N

C. Al and Se

D. Al and O

Answer: D

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183. The correct order of increasing C-O bond strength of

CO, CO
2−

3
, CO2 is :

A. CO 2−

3
< CO2 < CO

B. CO 2
< CO
2−

3
< CO

C. CO < CO
2−

3
< CO2

D. CO < CO2 < CO

2−

Answer: A

View Text Solution

184. Resonance structures can be written for .

A. O 3

B. N H 3

C. CH 4

D. H 2
O
Answer: A

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185. The correct order of Cl-O bond order is :

A. ClO −

3
< ClO
−

4
< ClO
−

2
< ClO
−

B. ClO − − − −
< ClO < ClO < ClO
4 3 2

C. ClO −
< ClO
−

2
< ClO
−

3
< ClO
−

D. ClO
− − − −
< ClO < ClO < ClO
4 3 3

Answer: C

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186. How many resonance structures can be drawn for the nitrate ion,

NO
−

3
?
A. 1

B. 2

C. 3

D. 4

Answer: C

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187. Among given species identify the isostructural pairs :

A. [N F 3
and BF3 ]

B. [BF −

4
and N H
+

4
]

C. [BCl 3
and BrCl3 ]

D. [N H 3
and N O
−

3
]

Answer: B

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188. 0.01 mole H3 P O x is completely neutralised by 0.56 gram of KOH

hence :

A. x=3 and given acid is dibasic

B. x=2 and given acid is monobasic

C. x=3 and given acid is monobasic

D. x=4 and given acid forms three series of salt

Answer: B

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189. Phosphorus pentachloride in the solid exists as :

A. P Cl 5

B. P Cl 4
+
Cl
−

C. P Cl
+ −
P Cl
4 6
D. P Cl 5
. Cl2

Answer: C

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190. The ratio of σ − bond and π − bond in tetracryano ethylene is :

A. 2 : 1

B. 1 : 1

C. 1 : 2

D. none of these

Answer: B

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191. The bonds present in N 2

O5 are .
A. only ionic

B. only covalent

C. covalent and co-ordinate

D. covalent and ionic

Answer: C

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192. The pair of species with similar shape is

A. P Cl 3
, N H3

B. CF 4
, SF4

C. P bCl 2
, CO2

D. P F 5
, IF5

Answer: A

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193. Which of the following statements is correct in the context of the

allene molecule, C 3
H4 ?

A. The central carbon is sp hybridized

B. The terminal carbon atoms are sp hybridized

2

C. The planes containing the CH2 groups are mutually perpendicular

to permit the formations two separate π-bonds

D. all are correct

Answer: D

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194. Number of S-S bond is H 2

Sn O6 :

A. n

B. (n-1)
C. (n-2)

D. (n+1)

Answer: B

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195. How many S-S bonds, S-O-S bonds, σ-bonds, π-bonds are present in

trimer of sulphur trioxide ?

A. 0,3,16,2

B. 0,3,12,6

C. 0,6,12,16

D. 0,4,12,6

Answer: B

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196. Number of identical Cr-O bonds in dichromate ion Cr 2
O
2−

7
is :

A. 4

B. 6

C. 7

D. 8

Answer: B

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197. The nodal plane in the π-bond of ethene is located in:

A. the molecular plane

B. a plane parallel to the molecular plane

C. a plane perpendicular to the molecular plane which bisects the

carbon-carbon σ bond at right angle

D. a plane perpendicular to the molecular plane which contains the

carbon-carbon bond

Answer: A

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198. Which of the following are isoelectronics and isostructural ?

A. N O −

3
, CO
2−

B. SO 3
, NO
−

C. ClO −

3
, CO
2−

D. CO 2−

3
, ClO
−

Answer: A

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199. In the electronic structure of H2 SO4 , the total number of unshared

electrons is

A. 20

B. 16

C. 12

D. 8

Answer: B

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200. Which of the following xenon compound has the same number of

lone pairs as in I ? (near central atom)

−

A. XeO 4

B. XeF 4

C. XeF 2
D. XeO 3

Answer: C

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201. The shape of XeF +

3
is :

A. Trigonal planar

B. Pyramidal

C. Bent T-shpae

D. See-saw

Answer: C

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202. Which of the following shape are not possible for possible value of n

in XeF molecule ?
n

A. Linear

B. Square planar

C. Trigonal planar

D. Capped octahedral

Answer: C

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203. BeCl is not isostructural with

2

A. ICl 2
−

B. C2
H2

C. XeF 2

D. GeCl 2
Answer: D

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204. Which statement is true about the most stable Lewis structure for

CS2 ?

A. There are no lone pairs in molecule

B. All bonds are double bonds

C. The central atom does not have an octet of electrons

D. A sulfur atom must be the central atom for the structure to be

stable

Answer: B

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205. SbF5 reacts with XeF4 and XeF6 to form ionic compounds

+ − + −
[XeF ][SbF ] and [XeF ][SbF `thenmo ≤ carshapeof
3 6 5 6
–

[XeF_(3)^(+)]ion and [XeF_(5)^(+)]` ion respectively :

A. Square pyramidal, T-shpaed

B. Bent-T-shape, square pyramidal

C. See-saw, square pyramidal

D. Square pyramidal, see -saw

Answer: B

View Text Solution

206. In which of the following species maximum atom can lie in same

plane ?

A. XeF 2
O2

B. P Cl 5
C. AsH +

D. XeF 4

Answer: D

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207. Correct statement regarding molecules SF 4

, CF4 and XeF4 are :

A. 2, 0 and 1 lone pairs of central atom respectively

B. 1, 0 and 1 lone pairs of central atom respectively

C. 0, 0 and 2 lone pairs of central atom respectively

D. 1, 0 and 2 lone pairs of central atom respectively

Answer: D

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208. The geometrical arrangement and shape of I −

3
are respectively

A. trigonal bipyramidal geometry, linear shape

B. hexagonal geometry, T-shape

C. triangular planar geometry, triangular shape

D. tetrahedral geometry, pyramidal shape

Answer: A

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209. Which of the following statements is incorrect for P Cl ? 5

A. Its three P − Cl bond lengths are equal

B. It involves sp 3
d hybridization

C. It has an regular geometry

D. Its shape is trigonal bipyramidal

Answer: C

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210. Molecular shapes of SF 4

, CF4 and XeF4 are :

A. the same with 2,0 and 1 lone pair of electrons respectively

B. the same with 1,1 and 1 lone pair of electrons respectively

C. the same with 0m1 and 2 lone pair of electrons respectively

D. the same with 1,0 and 2 lone pair of electrons respectively

Answer: D

View Text Solution

211. The structure of the noble gas compound XeF is : 4

A. square planar
B. distorted tetrahedral

C. tetrahedral

D. octahedral

Answer: A

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212. The molecule exhibiting maximum number of non-bonding electron

pairs (l.p.) around the central atom is :

A. XeOF 4

B. XeO 2
F2

C. XeF +

D. XeO 3

Answer: C

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213. Which is the following pairs of species have identical shapes ?

A. N O +

2
and N O
−

B. P Cl 5
and BrF5

C. XeF 4
and ICl
4
−

D. T eCl 4
and XeO4

Answer: C

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214. The shapes of XeF 4

, XeF
−

5
and SnCl2 are :

A. octahedral, trigonal bipyramidal and bent

B. square pyramidal, pentagonal planar and linear

C. square planar, pentagonal planar and angular

D. see-saw, T-shaped and linear

Answer: C

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215. Which is not correctly matched ?

A. XeO -Trigonal bipyramidal

3

B. ClF - bent T-shape

3

C. XeOF - Square pyramidal

4

D. XeF - Linear shape

2

Answer: A

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216. Amongst N O −

3
, AsO
3−

3
, CO
2−

3
, ClO
−

3
, SO
2−

3
and BO
2−

3
, the non-

planar species are :

A. CO 2−

3
, SO
2−

3
, BO
3−

B. AsO 3−

3
, ClO
−

3
, SO
2−

C. N O −

3
, CO
2−

3
, BO
3−

D. SO 2−

3
, NO
−

3
, BO
3−

Answer: B

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217. The geometry of ammonia molecule can be best described as :

A. Nitrogen at one vetex of a regular tetrahedron, the other three

vertices being occupied by three hydrogens

B. Nitrogen at the centre of the tetrahedron, three of the vertices

being occupied by three hydrogens

C. Nitrogen at the centre of an equilateral triangle, three corners

being occupied by three hydrogens

D. Nitrogen at the junction of a T, three open ends being occupied by

three hydrogens

Answer: B

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218. Which molecular geometry is least likely to result from a trigonal

bipyramidal electron geometry ?

A. Trigonal planar

B. See-saw

C. Linear

D. T-shpaed

Answer: A

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219. Give the correct order of initials T or F for following statements. Use

T if statement is true and F if it is falese :

(I) The order of repulsion between different pair of electron is

Ip − Ip > Ip − bp > bp − bp

(II) In general, as the number o flone pair of electron on central atom

increases, value of bond angle from normal bond angle also increases

(III) The number of lone pair on O in H 2

O is 2 while on N in N H is 1
3

(IV ) The structures of xenon fluorides and xenon oxyfluorides could not

be explained on the basis of VSEPR theory

A. T T TF

B. TFTF

C. TFT T

D. TF F F

Answer: B

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220. Which species is planar ?

A. CO 2−

B. SO 2−

C. ClO −

D. BF 4
−

Answer: A

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221. What is the geometry of the IBr −

2
ion ?

A. Linear

B. Bent shape with bond angle of about 90 ∘

C. Bent shape with bond angle of about 109 ∘

D. Bent shape with bond angle of about 120 ∘

Answer: A

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222. What is the shape of the ClF molecule?

3

A. Trigonal planar

B. Trigonal pyramidal

C. T-shaped

D. Tetrahedral

Answer: C

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223. Which species below has the same general shape as N H ?

3

A. SO 2−

3
B. CO 2−

C. N O −

D. SO 3

Answer: A

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224. According to VSEPR theory, in which species do all the atoms lie in

the same plane ?

+ −
1. CH 2. CH
3 3

A. 1 only

B. 2 only

C. both 1 and 2

D. neither 1 nor 2

Answer: A
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225. Which of the following species / molecules does not have same

number of bond pairs and lone pairs ?

A. OCN −

B. H 2
O

C. C2
H2 Cl2

D. O 3

Answer: D

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226. Least stable hydride is

A. stannane

B. silane
C. plumbane

D. germane

Answer: C

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227. The lowest O-O bond length in the following molecule is :

A. O 2
F2

B. O 2

C. H 2
O2

D. O 3

Answer: B

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228. The fluorine molecules is formed by :

A. p-p orbitals (sideways overlap)

B. p-p orbitals (end -to -end overlap)

C. sp-sp orbitals

D. s-s orbitals

Answer: B

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229. Which of the following leads to bonding?

A.

B.
C.

D.

Answer: B

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230. Which of the following overlaps is incorrect (assuming Z-axis is

internucler axis ) ?

(A)2Py + 2py → π - Bond formation (B)2px + 2px → σ - Bond

formation

(C ) 3d xy + 3d xy → π - Bond formation (D)2s + 2py → π - Bond

formation

(E ) 3d xy
- Bond formation
+ 3d xy → δ

A. A,B,C

B. C,F
C. B,E

D. B,C,D

Answer: D

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231. Which of the following overlapping is not present in XeO3 molecule

A. sp 3
+ px

B. sp 3
+ py

C. d xz
+ px

D. sp 3
+ s

Answer: D

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232. How many sigma bonds are in a molecule of diethyl ether,

C2 H5 OC2 H5 ?

A. 14

B. 12

C. 8

D. 16

Answer: A

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233. The lattice energies of KF, KCl, KBr and KI follow the order :

A. KF > KCl > KBr > KI

B. KI > KBr > KCl > KF

C. KF > KCl > KI > KBr

D. KI > KBr > KF > KCl

Answer: A

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234. Which set of compounds in the following pair of ionic compounds

has the higher lattice energy ?

(i) KCl or M gO (ii)LiF or LiBr (iii)M g3 N2 or N aCl

A. KCl, LiBr, M g 2
N2

B. M gO, LiBr, M g 3
N2

C. M gO, LiF , N aCl

D. M gO, LiF , M g 3
N2

Answer: D

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235. The incorrect order of lattice energy is :

A. AlF 3
> M gF2

B. Li 3
N > Li2 O

C. N aCl > LiF

D. T iC > ScN

Answer: C

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236. Which ionic compound has the largest amount of lattice energy ?

A. NaF

B. AlF 3

C. AlN

D. M gF 2

Answer: C

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237. Which of the following compounds has the smallest bond angle?

A. OH 2

B. SH 2

C. N H 3

D. SO 2

Answer: B

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238. Maximum bond angle is present in case of

A. BBr 3

B. BCl 3

C. BF 3
D. none of these

Answer: D

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239. The correct order of H-M-H bonds angle is :

A. N H 3
< P H3 < SbH3 < BiH3

B. AsH 3
< SbH3 < P H3 < N H3

C. N H 3
< P H3 < BiH3 < SbH3

D. BiH 3
< SbH3 < AsH3 < P H3

Answer: D

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240. The correct increasing bomnd angle among BF3 , P F3 and CIF3

follow the order

A. BF 3
< P F3 < ClF3

B. P F 3
< BF3 < ClF3

C. ClF 3
< P F3 < BF3

D. BF 3
= P F3 = ClF3

Answer: C

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241. Among the following species, the least angle around the central

atom is in :

A. O 3

B. I3
−

C. N O −

2
D. P H 3

Answer: D

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242. The bond angles of N H 3

, NH
+

4
and N H
−

2
are in the order

A. N H −

2
> N H3 > N H
+

B. N H
+ −
> N H3 > N H
4 2

C. N H 3
> NH
−

2
> NH
+

D. N H
+ −
3
> NH > NH
4 2

Answer: B

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243. The H-C-H bond angle in CH4 is109.5
∘
, due to lone pair repulsion,

the H-O-H angle in H 2

O will :

A. remain the same

B. increase

C. decrease

D. become 180 ∘

Answer: C

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244. The molecule having the largest bond angle is :

A. H 2
O

B. H 2
S

C. H 2
Se

D. H 2
Te
Answer: A

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245. The compound M X4 is tetrahedral. The number of ∠XM X angles

formed in the compound is

A. three

B. four

C. five

D. six

Answer: D

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246. The O − N − O bond angle in the nitrite ion, N O , is closest to :

−

2
A. N2
O

B. N O +

C. N O −

D. N O −

Answer: B

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247. Which of the following is the correct order for increasing bond angle

A. N h 3
< P H3 < AsH3 < SbH3

B. H 2
O < OF2 < Cl2 O

C. H 2
Te
+
< H3 Se
+
< H3 S
+
< H3 O
+

D. BF 3
< BCl3 < BBr 3 < BI3

Answer: C
View Text Solution

1. N − O − N bond angle is maximum in :

A. N 2
O

B. N O +

C. N O −

D. N O −

Answer: B

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Level 2

1. The incorrect order of boiling point is :

A. H 2
O > CH3 OH

B. N (CH 3
)
3
> N H (CH3 )
2

C. H 3
P O4 > M e3 P O4

D. CH 3
N3 > H N3

Answer: B,D

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2. Iodine molecules are held in the solid lattice by ______

A. London forces

B. dipole-dipole interactions

C. covalent bonds

D. coulombic force

Answer: A

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3. At room temperature, CO is a gas while SiO is a solid because
2 2

A. CO is a linear molecule, while SiO is angular

2 2

B. van der Waals's forces are very strong in SiO 2

C. CO is covalent, while SiO is ionic

2 2

D. Si cannot form stable bonds with O, hence Si has to form a 3D

lattice

Answer: D

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4. Choose the correct code of characteristics for the given order of hybrid

orbitals of same atom,

2 3
sp < sp < sp

(i) Electrongativity (ii) Bond angle between same hybrid orbitals

(iii) Size (iv) Energy level

A. ii, iii and iv

B. iii, iv

C. ii and iv

D. I, ii, iii and iv

Answer: B

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5. Which is correct statement ?

As the s-character of a hybrid orbital decreases

(I) The bond angle decreases (II) The bond strength increases

(III) The bond length increases (IV) Size of orbitals increases

A. I, III and IV

B. II, III and IV

C. I and II

D. all are correct

Answer: A

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6. Which of the following is incorrectly match ?

Hybridisation Geometry Orbitals use

A. 3
sp d Trigonal bipyramidal s + px + py + ps + d s 2

B.

Hybridisation Geometry Orbitals use

3 3
sp d Pentagonal bipyramidal s + px + py + ps + d x2 − y

C.

Hybridisation Geometry Orbitals use

3 2
sp d Capped octahedral s + px + py + ps + d x2 − y 2 + d

Hybridisation Geometry Orbitals use

D. 3
sp Tetrahedral s + px + py + ps

Answer: C

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7. The ionic bond X +
Y
−
are formed when :

(I) electron affinity of Y is high (II) ionization energy of X is low

(III) lattice energy of XY is high (IV) lattice energy of XY is low

Choose the correct code :

A. I and II

B. I and III

C. I, II and III

D. All

Answer: C

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8. In the Born-Haber cycle for the formation of solid common salt (NaCl),

the largest contribution comes from :

A. the low ionization potential of Na

B. the high electron affinity of Cl

C. the low ΔH vap

of Na(s)

D. the lattice energy

Answer: D

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9. Species having maximum 'Cl-O' bond order is :

A. ClO −

B. ClO 3

C. ClO 2

D. ClO −

Answer: B

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10. Which of the following species contains minimum number of atoms in

XY plane ?

A. XeF −

B. SF 6

C. IF 7

D. All

Answer: B

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11. The molecule M L is planar with 7 pairs of electrons around M in the

x

valence shell. The value of x is :

A. 6

B. 5

C. 4
D. 3

Answer: B

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12. Choose the correct option for the collowing molecule in view of

chemical bonding :

A. non-planar

B. μ ≠ 0

C. both a and b

D. μ = 0

Answer: D

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13. Which of the following statement is correct about I
3
+
and I
3
−

molecular ions ?

A. Number of lone pairs at central atoms are same in both molecular

ions

B. Hybridization of central atoms in both ions are same

C. Both are polar species

D. Both are planar species

Answer: D

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14. In which of the following molecular shape dz 2 orbital must not be

involved in bonding ?

A. Pentagonal planar
B. Trigonal planar

C. Linear

D. Square planar

Answer: B

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15. The correct statement regarding SO molecule is :

2

A. two pπ − dπ bonds

B. molecule has 2 lone pair, 2σ bonds and 2π bonds

C. two pπ − pπ bonds

D. one pπ − pπ and one pπ − dπ bond

Answer: D

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16. A molecule XY2 contains two σ bonds two π bond and one lone pair

of electrons in the valence shell of X . The arrangement of lone pair as

well as bond pairs is

A. square pyramidal

B. linear

C. Trigonal planar

D. unpredictable

Answer: C

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17. In which of the following pairs, both the species have the same

hybridisation ?

(I)

− − − 3−
SF4 , XeF4 (II)I , XeF2 (III)ICI , SiCl4 (IV )ClO , PO
3 4 3 4
A. I,II

B. II, III

C. II, IV

D. I,II,III

Answer: C

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18. Which of the following possess two lone pair of electrons on the

central atom and square planar in shape ?

(I) SF 4
(II)XeO4 (III)XeF4 (IV )ICl
4
−

A. I,III

B. II,IV

C. III, IV

D. All
Answer: C

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19. Select pair of compounds in which both have different hybridization

but have same molecular geometry :

A. BF 3
, BrF3

B. ICl Θ
2
, BeCl2

C. BCl 3
, P Cl3

D. P Cl 3
, N Cl3

Answer: B

Watch Video Solution

20. The species having no pπ − pπ bond but its bond order equal to that

of O −

2
A. ClO −

B. P O 3−

C. SO
2−

D. XeO 3

Answer: C

Watch Video Solution

21. Which of the following fact is directly explained by the statement

oxygen is a smaller atom than sulphur ?

A. H 2
O boils at a much higher temperature than H 2
S

B. H 2
O undergoes intermolecular hydrogen bonding

C. H 2
O is liquid and H 2
S is gas at room temperature

D. S-H bond is longer than O-H bond

Answer: D
Watch Video Solution

22. Which of the following compound has maximum "C-C" single bond

length ?

A. CH 2
CH CCH

B. HC C C CH

C. CH 3
CH CH2

D. CH 2
CH CH CH2

Answer: C

Watch Video Solution

23. If two different non-axial d-orbitals having 'xz' nodal plane form π -

bond by overlapping each other, then internuclear axis will be :

A. x
B. y

C. z

D. They don't form π-bond

Answer: D

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24. Assuming pure 2s and 2p orbitals of carbon are used in forming CH4

molecule, which of the following statement is false ?

A. Three C-H bonds will be at right angle

B. One C-H bond will be weaker than other three C-H bonds

C. The shape of molecule will be tetrahedral

D. The angle of C-H bond formed by s-s overlapping will be uncertain

with respect to other three bonds.

Answer: C
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25. The strength of bonds by 2s -2s, 2p2p and 2p-2s overlap has the order

A. s − s > p − p > p − s

B. s − s > p − s > p − p

C. p − p > p − s > s − s

D. p − p > s − s > p − s

Answer: C

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26. Which of the following statement is not correct for sigma and pi-

bonds formed between two carbon atoms ?

A. Sigma-bond is stronger than a π-bond

B. Bond energies of sigma and π -bonds are of the order of 264 kJ /

mol and 347 kJ / mol

C. Free rotation of surrounding atoms about a sigma -bond is allowed

but not in case of a π-bond

D. Sigma-bond determines the direction between carbon atoms but a

π -bond has no primary effect in this regard

Answer: B

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27. Assuming the bond direction to the z-axis, which of the overlapping of

atomic orbitals of two atom (A) and (B) will result in bonding ?

(I) s-orbital of A and p orbital of B (II) s-orbital of A and p orbital of B

x z

(III) p -orbital of A and p orbital of B (IV) s-orbital of both (A) and (B)
y z

A. I and IV

B. I and II
C. III and IV

D. II and IV

Answer: D

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28. Which of the following orbital can not form π as well as δ-Bond ?

A. d xy

B. d z
2

C. d x
2
−y
2

D. d yz

Answer: B

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29. Incorrect statement is :

A. AlF 3
> M gO > M gF2 : Lattice energy

B. Li > N a > Al > M g : Electron afinity

C. SF 6
> P F5 > SiF4 : Lewis acidic character

D. SiCl 4
> SiBr 4 > SiI4 : Decreasing order of electronegativity of Si

Answer: C

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30. Which of the following set contains species having same angle around

the central atom?

A. SF 4
, CH4 , N H3

B. N F 3
, BCl3 , N H3

C. BF 3
, N F3 , AlCl3

D. BF 3
, BCl3 , BBr 3
Answer: D

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31. Which of the following compound has the smallest (X − A − X)

bond angle in each series repectively.

(A) OsF2 , OsCl2 , OsBr 2

(B) SbCl3 , SbBr 3 , SbI3

(C) P l3 , AsI3 , SbI3

A. OSF 2
, SbCl3 and P I3

B. OSBr 2
, SbI3 and P I3

C. OSF 2
, SbI3 and P I3

D. OSF 2
, SbCl3 and SbI3

Answer: D

Watch Video Solution

32. The incorrect order of boiling point is :

A. H 2
O > CH3 OH

B. N (CH 3
)
3
> N H (CH3 )
2

C. H 3
P O4 > M e3 P O4

D. CH 3
N3 > H N3

Answer: D

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33. Iodine molecules are held in the solid lattice by ______

A. London forces

B. dipole-dipole interactions

C. covalent bonds

D. coulombic force
Answer: A

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34. Carbon dioxide is a gas but silica is a solid because:

A. CO is a linear molecule, while SiO is angular

2 2

B. van der Waals's forces are very strong in SiO 2

C. CO is covalent, while SiO is ionic

2 2

D. Si cannot form stable bonds with O, hence Si has to form a 3D

lattice

Answer: D

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35. Choose the correct code of characteristics for the given order of

hybrid orbitals of same atom,

2 3
sp < sp < sp

(i) Electrongativity (ii) Bond angle between same hybrid orbitals

(iii) Size (iv) Energy level

A. ii, iii and iv

B. iii, iv

C. ii and iv

D. I, ii, iii and iv

Answer: B

Watch Video Solution

36. Which is correct statement ?

As the s-character of a hybrid orbital decreases

(I) The bond angle decreases (II) The bond strength increases

(III) The bond length increases (IV) Size of orbitals increases

A. I, III and IV
B. II, III and IV

C. I and II

D. all are correct

Answer: A

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37. Which of the following is incorrectly matched ?

Hybridisation Geometry Orbitals use

A. 3
sp d Trigonal bipyramidal s + px + py + ps + d s 2

B.

Hybridisation Geometry Orbitals use

3 3
sp d Pentagonal bipyramidal s + px + py + ps + d x2 − y

C.

Hybridisation Geometry Orbitals use

3 2
sp d Capped octahedral s + px + py + ps + d x2 − y 2 + d

Hybridisation Geometry Orbitals use

D. 3
sp Tetrahedral s + px + py + ps

Answer: C
Watch Video Solution

38. The ionic bond X +

Y
−
are formed when :

(I) electron affinity of Y is high (II) ionization energy of X is low

(III) lattice energy of XY is high (IV) lattice energy of XY is low

Choose the correct code :

A. I and II

B. I and III

C. I, II and III

D. All

Answer: C

Watch Video Solution

39. In the Born-Haber cycle for the formation of solid common salt (NaCl),

the largest contribution comes from :

A. the low ionization potential of Na

B. the high electron affinity of Cl

C. the low ΔH vap

of Na(s)

D. the lattice energy

Answer: D

Watch Video Solution

40. Species having maximum 'Cl-O' bond order is :

A. ClO −

B. ClO 3

C. ClO 2

D. ClO −

Answer: B

Watch Video Solution

41. Which of the following species contains minimum number of atoms in

XY plane ?

A. XeF −

B. SF 6

C. IF 7

D. All

Answer: B

Watch Video Solution

42. The molecule M L is planar with 7 pairs of electrons around M in the

x

valence shell. The value of x is :

A. 6

B. 5
C. 4

D. 3

Answer: B

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43. Choose the correct option for the collowing molecule in view of

chemical bonding :

A. non-planar

B. μ ≠ 0

C. both a and b

D. μ = 0

Answer: D
Watch Video Solution

44. Which of the following statement is correct about I

3
+
and I
3
−

molecular ions ?

A. Number of lone pairs at central atoms are same in both molecular

ions

B. Hybridization of central atoms in both ions are same

C. Both are polar species

D. Both are planar species

Answer: D

Watch Video Solution

45. In which of the following molecular shape dz 2 orbital must not be

involved in bonding ?
A. Pentagonal planar

B. Trigonal planar

C. Linear

D. Square planar

Answer: B

Watch Video Solution

46. The correct statement regarding SO molecule is :

2

A. two pπ − dπ bonds

B. molecule has 2 lone pair, 2σ bonds and 2π bonds

C. two pπ − pπ bonds

D. one pπ − pπ and one pπ − π bond

Answer: D

Watch Video Solution

47. A molecule XY contains two
2
σ bonds two π bond and one lone pair

of electrons in the valence shell of X . The arrangement of lone pair as

well as bond pairs is

A. square pyramidal

B. linear

C. Trigonal planar

D. unpredictable

Answer: C

Watch Video Solution

48. In which of the following pairs, both the species have the same

hybridisation ?

(I)

− − − 3−
SF4 , XeF4 (II)I , XeF2 (III)ICI , SiCl4 (IV )ClO , PO
3 4 3 4
A. I,II

B. II, III

C. II, IV

D. I,II,III

Answer: C

Watch Video Solution

49. Which of the following possess two lone pair of electrons on the

central atom and square planar in shape ?

(I) SF 4
(II)XeO4 (III)XeF4 (IV )ICl
4
−

A. I,III

B. II,IV

C. III, IV

D. All
Answer: C

Watch Video Solution

50. Select pair of compounds in which both have different hybridization

but have same molecular geometry :

A. BF 3
, BrF3

B. ICl Θ
2
, BeCl2

C. BCl 3
, P Cl3

D. P Cl 3
, N Cl3

Answer: B

Watch Video Solution

51. The species having no pπ − pπ bond but its bond order equal to that

of O −

2
A. ClO −

B. P O 3−

C. SO
2−

D. XeO 3

Answer: D

Watch Video Solution

52. Which of the following fact is directly explained by the statement

oxygen is a smaller atom than sulphur ?

A. H 2
O boils at a much higher temperature than H 2
S

B. H 2
O undergoes intermolecular hydrogen bonding

C. H 2
O is liquid and H 2
S is gas at room temperature

D. S-H bond is longer than O-H bond

Answer: D
Watch Video Solution

53. Which of the following compound has maximum "C-C" single bond

length ?

A. CH 2
CH CCH

B. HC C C CH

C. CH 3
CH CH2

D. CH 2
CH CH CH2

Answer: C

Watch Video Solution

54. If two different non-axial d-orbitals having 'xz' nodal plane form π -

bond by overlapping each other, then internuclear axis will be :

A. x
B. y

C. z

D. They don't form π-bond

Answer: D

Watch Video Solution

55. Assuming pure 2s and 2p orbitals of carbon are used in forming CH4

molecule, which of the following statement is false ?

A. Three C-H bonds will be at right angle

B. One C-H bond will be weaker than other three C-H bonds

C. The shape of molecule will be tetrahedral

D. The angle of C-H bond formed by s-s overlapping will be uncertain

with respect to other three bonds.

Answer: C
Watch Video Solution

56. Which of the following is correct order of σ - bond strength ?

I. 2s-2s

II. 2s-2p

III. 2p-2p

IV. 3s-3s

A. s − s > p − p > p − s

B. s − s > p − s > p − p

C. p − p > p − s > s − s

D. p − p > s − s > p − s

Answer: C

Watch Video Solution

57. Which of the following statements in incorrect for sigma and π -bonds

formed between two carbon atoms ?

A. Sigma-bond is stronger than a π-bond

B. Bond energies of sigma and π -bonds are of the order of 264 kJ /

mol and 347 kJ / mol

C. Free rotation of surrounding atoms about a sigma -bond is allowed

but not in case of a π-bond

D. Sigma-bond determines the direction between carbon atoms but a

π -bond has no primary effect in this regard

Answer: B

View Text Solution

58. Assuming the bond direction to the z-axis, which of the overlapping of

atomic orbitals of two atom (A) and (B) will result in bonding ?
(I) s-orbital of A and p orbital of B (II) s-orbital of A and p orbital of B
x z

(III) p -orbital of A and p orbital of B (IV) s-orbital of both (A) and (B)
y z

A. I and IV

B. I and II

C. III and IV

D. II and IV

Answer: D

Watch Video Solution

59. Which of the following orbital can not form π as well as δ-Bond ?

A. d xy

B. d z
2

C. d x
2
−y
2

D. d yz
Answer: B

Watch Video Solution

60. Incorrect statement is :

A. AlF 3
> M gO > M gF2 : Lattice energy

B. Li > N a > Al > M g : Electron afinity

C. SF 6
> P F5 > SiF4 : Lewis acidic character

D. SiCl 4
> SiBr 4 > SiI4 : Decreasing order of electronegativity of Si

Answer: C

View Text Solution

61. Which of the following set contains species having same angle around

the central atom?

A. SF 4
, CH4 , N H3

B. N F 3
, BCl3 , N H3

C. BF 3
, N F3 , AlCl3

D. BF 3
, BCl3 , BBr 3

Answer: D

Watch Video Solution

62. Which of the following compound has the smallest (X − A − X)

bond angle in each series repectively.

(A) OsF2 , OsCl2 , OsBr 2

(B) SbCl3 , SbBr 3 , SbI3

(C) P l3 , AsI3 , SbI3

A. OSF 2
, SbCl3 and P I3

B. OSBr 2
, SbI3 and P I3

C. OSF 2
, SbI3 and P I3
D. OSF 2
, SbCl3 and SbI3

Answer: D

Watch Video Solution

Level 3 (Passive 1)

1. According to VSEPR model, molecules adopt geometries in which their

valence electron pairs position themselves as far from each other as

possible. The VSEPR model considers double and triple bonds to have

slightly greater repulsive effects than single bonds because of the

repulsive effect of π -electrons. However the lone pair creates the

maximum repulsive effect.

Which of the following statement is false ?

A. SbF −

4
and SF4 are isostructural

B. In IOF the hybridization of central atom is sp

5
3
d
2
C. Double bond(s) in SOF4 and XeO3 F2 , is / are occupying

equatorial position(s) of their respective geometry

D. none of these

Answer: D

Watch Video Solution

2. According to VSEPR model, molecules adopt geometries in which their

valence electron pairs position themselves as far from each other as

possible. The VSEPR model considers double and triple bonds to have

slightly greater repulsive effects than single bonds because of the

repulsive effect of π -electrons. However the lone pair creates the

maximum repulsive effect.

Which of the following does not represent the isostructural pair ?

A. SF −

5
and IF5

B. ClO 2
F3 and SOF4
C. SeF +

3
and XeO3

D. None

Answer: D

Watch Video Solution

3. According to VSEPR model, molecules adopt geometries in which their

valence electron pairs position themselves as far from each other as

possible. The VSEPR model considers double and triple bonds to have

slightly greater repulsive effects than single bonds because of the

repulsive effect of π -electrons. However the lone pair creates the

maximum repulsive effect.

Select the incorrect statement with respect to SO 2

Cl2 molecule :

A. It gives H 2
SO4 and HCl on hydrolysis at room temperature

B. It has two dπ − pπ bonds between S and O bonded atoms

C. It is a polar molecule
D. None

Answer: D

Watch Video Solution

4. According to VSEPR model, molecules adopt geometries in which their

valence electron pairs position themselves as far from each other as

possible. The VSEPR model considers double and triple bonds to have

slightly greater repulsive effects than single bonds because of the

repulsive effect of π -electrons. However the lone pair creates the

maximum repulsive effect.

Which of the following statement is false ?

A. SbF −

4
and SF4 are isostructural

B. In IOF the hybridization of central atom is sp

5
3
d
2

C. Double bond(s) in SOF4 and XeO3 F2 , is / are occupying

equatorial position(s) of their respective geometry

D. none of these

Answer: D

Watch Video Solution

5. According to VSEPR model, molecules adopt geometries in which their

valence electron pairs position themselves as far from each other as

possible. The VSEPR model considers double and triple bonds to have

slightly greater repulsive effects than single bonds because of the

repulsive effect of π -electrons. However the lone pair creates the

maximum repulsive effect.

Which of the following does not represent the isostructural pair ?

A. SF −

5
and IF5

B. ClO 2
F3 and SOF4

C. SeF +

3
and XeO3

D. None
Answer: D

Watch Video Solution

6. According to VSEPR model, molecules adopt geometries in which their

valence electron pairs position themselves as far from each other as

possible. The VSEPR model considers double and triple bonds to have

slightly greater repulsive effects than single bonds because of the

repulsive effect of π -electrons. However the lone pair creates the

maximum repulsive effect.

Select the incorrect statement with respect to SO 2

Cl2 molecule :

A. It gives H 2
SO4 and HCl on hydrolysis at room temperature

B. It has two dπ − pπ bonds between S and O bonded atoms

C. It is a polar molecule

D. None

Answer: D
Watch Video Solution

Level 3 (Passive 2)

1. According to VBT any covalent bond will be formed by overlapping of

atomic orbitals of bonded atoms provided atomic orbitals must be half-

filled and electrons be in opposite spin. According to type of overlapping

covalent bonds can be classified as (a)σ-bond (b) π-bond (c ) δ-bond :

Which of the following set of orbitals does not produce nobal plane in xz-

plane ?

A. d yz
+ d yz

B. d xy
+ d xy

C. p
y
+ d xy

D. none of these

Answer: D

Watch Video Solution

2. According to VBT any covalent bond will be formed by overlapping of

atomic orbitals of bonded atoms provided atomic orbitals must be half-

filled and electrons be in opposite spin. According to type of overlapping

covalent bonds can be classified as (a)σ-bond (b) π-bond (c ) δ-bond :

The combination of orbital that can not produce non-bonding molecular

orbital is (internuclear axis is z-axis ) :

A. py
+ dx2 − y 2

B. pz
+ d yz

C. s + d xz

D. d xy
+ d xy

Answer: D

Watch Video Solution

3. According to VBT any covalent bond will be formed by overlapping of

atomic orbitals of bonded atoms provided atomic orbitals must be half-

filled and electrons be in opposite spin. According to type of overlapping

covalent bonds can be classified as (a)σ-bond (b) π-bond (c ) δ-bond :

If F2 C1 = C2 part of F2 C1 = C2 = C3 = C4 F2 lies in yz-plane, then

incorrect statment is :

A. Nodal plane of π-bond between C1 and C2 lies in yz-plane, formed

by sideways overlapping of p -orbitals

x

B. Nodal plane of π-bond between C2 and C3 lies in xz-plane, formed

by sideways overlapping of p -orbitals

y

C. Nodal plane of π- bond between C 3

and C4 lies in yz-plane, formed

by sideways overlapping of p -orbitals

y

D. Nodal plane of π-bond between C2 and C3 lies in xy-plane, formed

by sideways overlapping of p - orbitals

x

Answer: C
View Text Solution

4. According to VBT any covalent bond will be formed by overlapping of

atomic orbitals of bonded atoms provided atomic orbitals must be half-

filled and electrons be in opposite spin. According to type of overlapping

covalent bonds can be classified as (a)σ-bond (b) π-bond (c ) δ-bond :

Which of the following set of orbitals does not produce nobal plane in xz-

plane ?

A. d yz
+ d yz

B. d xy
+ d xy

C. py
+ d xy

D. none of these

Answer: D

Watch Video Solution

5. According to VBT any covalent bond will be formed by overlapping of

atomic orbitals of bonded atoms provided atomic orbitals must be half-

filled and electrons be in opposite spin. According to type of overlapping

covalent bonds can be classified as (a)σ-bond (b) π-bond (c ) δ-bond :

The combination of orbital that can not produce non-bonding molecular

orbital is (internuclear axis is z-axis ) :

A. py
+ dx2 − y 2

B. pz
+ d yz

C. s + d xz

D. d xy
+ d xy

Answer: D

Watch Video Solution

6. According to VBT any covalent bond will be formed by overlapping of

atomic orbitals of bonded atoms provided atomic orbitals must be half-

filled and electrons be in opposite spin. According to type of overlapping

covalent bonds can be classified as (a)σ-bond (b) π-bond (c ) δ-bond :

If F2 C1 = C2 part of F2 C1 = C2 = C3 = C4 F2 lies in yz-plane, then

incorrect statment is :

A. Nodal plane of π-bond between C1 and C2 lies in yz-plane, formed

by sideways overlapping of p -orbitals

x

B. Nodal plane of π-bond between C2 and C3 lies in xz-plane, formed

by sideways overlapping of p -orbitals

y

C. Nodal plane of π- bond between C 3

and C4 lies in yz-plane, formed

by sideways overlapping of p -orbitals

y

D. Nodal plane of π-bond between C2 and C3 lies in xy-plane, formed

by sideways overlapping of p - orbitals

x

Answer: C

View Text Solution

Level 3 (Passive 3)

1. If the central atom is of third row or below this in the periodic table,

then lone pair will occupy a stereochemically inactive s-orbital and

bonding will be through almost pure p-orbitals and bond angles are

nearly 90 , if the substituent's electronegativity value is

∘
.
≤ 2.5

In which of the following option, covalent bond is having maximum s%

character ?

A. S-H bond in H 2
S

B. P-H bond in P H 3

C. N-H bond in N H 3

D. All have equal s% character

Answer: C

Watch Video Solution

2. If the central atom is of third row or below this in the periodic table,

then lone pair will occupy a stereochemically inactive s-orbital and

bonding will be through almost pure p-orbitals and bond angles are

nearly 90 , if the substituent's electronegativity value is

∘
.
≤ 2.5

Select incorrect statement regarding P molecule.

4

A. Each P atom is ioined with three P-atoms

B. P molecule contains total 12 bond angles

4

C. Lone pair of each P atom is present in almost pure s-orbital

D. Lone pair of each P atom present in hybrid orbital

Answer: D

Watch Video Solution

3. If the central atom is of third row or below this in the periodic table,

then lone pair will occupy a stereochemically inactive s-orbital and

bonding will be through almost pure p-orbitals and bond angles are
nearly 90 , if the substituent's electronegativity value is
∘
≤ 2.5.

The hybridisation of atomic orbitals of central atom "Xe" in

XeO4 , XeO2 F2 and XeOF4 respectively.

A. sp3 3 2
, sp d , sp d
3 2

B. sp3 3
d, sp d, sp d
3 2

C. sp3 3 2
, sp d , sp d
3

D. sp3 3
, sp d, sp d
3 2

Answer: D

Watch Video Solution

4. If the central atom is of third row or below this in the periodic table,

then lone pair will occupy a stereochemically inactive s-orbital and

bonding will be through almost pure p-orbitals and bond angles are

nearly 90 , if the substituent's electronegativity value is

∘
≤ 2.5.

In which of the following option, covalent bond is having maximum s%

character ?
A. S-H bond in H 2
S

B. P-H bond in P H 3

C. N-H bond in N H 3

D. All have equal s% character

Answer: C

View Text Solution

5. If the central atom is of third row or below this in the periodic table,

then lone pair will occupy a stereochemically inactive s-orbital and

bonding will be through almost pure p-orbitals and bond angles are

nearly 90 , if the substituent's electronegativity value is

∘
.
≤ 2.5

Select incorrect statement regarding P molecule.

4

A. Each P atom is ioined with three P-atoms

B. P molecule contains total 12 bond angles

4

C. Lone pair of each P atom is present in almost pure s-orbital

D. Lone pair of each P atom present in hybrid orbital

Answer: D

View Text Solution

6. If the central atom is of third row or below this in the periodic table,

then lone pair will occupy a stereochemically inactive s-orbital and

bonding will be through almost pure p-orbitals and bond angles are

nearly 90 , if the substituent's electronegativity value is

∘
≤ 2.5.

The hybridisation of atomic orbitals of central atom "Xe" in

XeO4 , XeO2 F2 and XeOF4 respectively.

A. sp3 3 2
, sp d , sp d
3 2

B. sp3 3
d, sp d, sp d
3 2

C. sp3 3 2
, sp d , sp d
3

D. sp3 3
, sp d, sp d
3 2

Answer: D
Watch Video Solution

Level 3 (Passive 4)

1. According to V.B.T., atoms of element form bond only to pair up their

unpaired electrons present in ground state or excited state. This pairing

of unpaired electron will take place by overlapping of orbitals each one

having one unpaired electron with opposite spin.

Which of the following orbital combination does not form π-bond ?

A. px
+ px sideways overlapping

B. d x
2
−y
2 + py sideways overlapping

C. d xy
+ d xy sideways overlapping

D. d yz
+ py sideways overlapping

Answer: B

Watch Video Solution

2. According to V.B.T., atoms of element form bond only to pair up their

unpaired electrons present in ground state or excited state. This pairing

of unpaired electron will take place by overlapping of orbitals each one

having one unpaired electron with opposite spin.

Which of the following orbital cannot form δ-bond ?

A. d x
2
−y
2 orbital

B. d xy
orbital

C. d z
2 orbital

D. d zx
orbital

Answer: C

Watch Video Solution

3. According to V.B.T., atoms of element form bond only to pair up their

unpaired electrons present in ground state or excited state. This pairing

of unpaired electron will take place by overlapping of orbitals each one

having one unpaired electron with opposite spin.

Which of the following combination of orbitals does not from any type of

covalent bond (if z-axis is molecular axis)?

A. ps
+ pz

B. py
+ py

C. s + p y

D. s + s

Answer: C

Watch Video Solution

4. According to V.B.T., atoms of element form bond only to pair up their

unpaired electrons present in ground state or excited state. This pairing

of unpaired electron will take place by overlapping of orbitals each one

having one unpaired electron with opposite spin.

Which of the following orbital combination does not form π-bond ?

A. p
x
+ px sideways overlapping

B. d x
2
−y
2 + py sideways overlapping

C. d xy
+ d xy sideways overlapping

D. d yz
+ py sideways overlapping

Answer: B

Watch Video Solution

5. According to V.B.T., atoms of element form bond only to pair up their

unpaired electrons present in ground state or excited state. This pairing

of unpaired electron will take place by overlapping of orbitals each one

having one unpaired electron with opposite spin.

Which of the following orbital cannot form δ-bond ?

A. d x
2
−y
2 orbital

B. d xy
orbital

C. d x
2 orbital
D. d zx
orbital

Answer: C

View Text Solution

6. According to V.B.T., atoms of element form bond only to pair up their

unpaired electrons present in ground state or excited state. This pairing

of unpaired electron will take place by overlapping of orbitals each one

having one unpaired electron with opposite spin.

Which of the following combination of orbitals does not from any type of

covalent bond (if z-axis is molecular axis)?

A. ps
+ pz

B. py
+ py

C. s + p y

D. s + s

Answer: C
Watch Video Solution

Level 3 (Passive 5)

1. The space model which is obtained by joining the points representing

various bonded atoms gives the shape of the molecule. The geometry of

the molecule is definite relative arrangement of the bonded atoms in a

molecule. The shape and geometry of a molecule is explained by valence

shell electron pair repulsion theory given by Gillespie and Nyholm.

Select the correct code for the following repulsion orders, according to

VSEPR theory :

(I) lone pair -lone pair > lone pair-bond pair

(II) lone pair-bond pair > bond pair -bond pair

(III) lone pair -lone pair > bond pair-bond pair

(IV) lone pair - bond pair > lone pair-lone pair

A. I,II and III

B. II and IV
C. I,II and IV

D. All

Answer: A

Watch Video Solution

2. The space model which is obtained by joining the points representing

various bonded atoms gives the shape of the molecule. The geometry of

the molecule is definite relative arrangement of the bonded atoms in a

molecule. The shape and geometry of a molecule is explained by valence

shell electron pair repulsion theory given by Gillespie and Nyholm.

Which molecule has both shape and geometry identical ?

(I)SnCl2 (II)N H3 (III)P Cl5 (IV )SF6

A. I, III and IV

B. II,III and IV

C. III and IV
D. All

Answer: C

Watch Video Solution

3. The space model which is obtained by joining the points representing

various bonded atoms gives the shape of the molecule. The geometry of

the molecule is definite relative arrangement of the bonded atoms in a

molecule. The shape and geometry of a molecule is explained by valence

shell electron pair repulsion theory given by Gillespie and Nyholm.

Which is not the electron geometry of covalent molecules ?

A. Pentagonal bipyramidal

B. Octahedral

C. Hexagonal

D. Tetrahedral

Answer: C
Watch Video Solution

4. The space model which is obtained by joining the points representing

various bonded atoms gives the shape of the molecule. The geometry of

the molecule is definite relative arrangement of the bonded atoms in a

molecule. The shape and geometry of a molecule is explained by valence

shell electron pair repulsion theory given by Gillespie and Nyholm.

Select the correct code for the following repulsion orders, according to

VSEPR theory :

(I) lone pair -lone pair > lone pair-bond pair

(II) lone pair-bond pair > bond pair -bond pair

(III) lone pair -lone pair > bond pair-bond pair

(IV) lone pair - bond pair > lone pair-lone pair

A. I,II and III

B. II and IV

C. I,II and IV

D. All
Answer: A

Watch Video Solution

5. The space model which is obtained by joining the points representing

various bonded atoms gives the shape of the molecule. The geometry of

the molecule is definite relative arrangement of the bonded atoms in a

molecule. The shape and geometry of a molecule is explained by valence

shell electron pair repulsion theory given by Gillespie and Nyholm.

Which molecule has both shape and geometry identical ?

(I)SnCl2 (II)N H3 (III)P Cl5 (IV )SF6

A. I, III and IV

B. II,III and IV

C. III and IV

D. All

Answer: C
Watch Video Solution

6. The space model which is obtained by joining the points representing

various bonded atoms gives the shape of the molecule. The geometry of

the molecule is definite relative arrangement of the bonded atoms in a

molecule. The shape and geometry of a molecule is explained by valence

shell electron pair repulsion theory given by Gillespie and Nyholm.

Which is not the electron geometry of covalent molecules ?

A. Pentagonal bipyramidal

B. Octahedral

C. Hexagonal

D. Tetrahedral

Answer: C

View Text Solution

Level 3 (Passive 6)
1. When hybridisation involving d-orbitals are considered then all the five

d-orbitals are not degenerate, rather dx2 − y 2 , ds 2 and d xy , d zx form two

different sets of orbitals and orbitals of appropriate set is involved in the

hybridisation.

In sp3
d
2
hybridisation, which sets of d-orbitals is involved ?

A. d x
2
−y
2 , dz 2

B. d z
2 , d xy

C. d xy
, d yz

D. d x
2
−y
2 , d xy

Answer: A

Watch Video Solution

2. The d orbitals involved in sp 3

d
3
hybridization are ?

A. d x
2
−y
2 , d z 2 , d xy
B. d xy
, d yz , d zx

C. d x
2
−y
2 , d xy , d xz

D. d x
2 , d yz , d zx

Answer: A

Watch Video Solution

3. When hybridisation involving d-orbitals are considered then all the five

d-orbitals are not degenerate, rather dx2 − y 2 , ds 2 and d xy , d zx form two

different sets of orbitals and orbitals of appropriate set is involved in the

hybridisation.

Molecule having trigonal bipyramidal geometry and sp d hybridisation, d-

3

orbitals involved is :

A. d xy

B. d yz

C. d x
2
−y
2
D. d z
2

Answer: D

Watch Video Solution

4. When hybridisation involving d-orbitals are considered then all the five

d-orbitals are not degenerate, rather dx2 − y 2 , ds 2 and d xy , d zx form two

different sets of orbitals and orbitals of appropriate set is involved in the

hybridisation.

Which of the following orbitals can not undergo hybridisation amongst

themselves.

(I) 3d, 4s (II)3d, 4d

(III) 3d, 4s&4p (IV )3s, 3p&4s

A. only II

B. II and III

C. I, II and IV

D. II and IV
Answer: D

Watch Video Solution

5. When hybridisation involving d-orbitals are considered then all the five

d-orbitals are not degenerate, rather dx2 − y 2 , ds 2 and d xy , d zx form two

different sets of orbitals and orbitals of appropriate set is involved in the

hybridisation.

In sp3
d
2
hybridisation, which sets of d-orbitals is involved ?

A. d x
2
−y
2 , ds 2

B. d z
2 , d xy

C. d xy
, d yz

D. d x
2
−y
2 , d xy

Answer: A

View Text Solution

6. When hybridisation involving d-orbitals are considered then all the five

d-orbitals are not degenerate, rather dx2 − y 2 , ds 2 and d xy , d zx form two

different sets of orbitals and orbitals of appropriate set is involved in the

hybridisation.

In sp3
d
3
hybridisation, which orbitals are involved ?

A. d x
2
−y
2 , d z 2 , d xy

B. d xy
, d yz , d zx

C. d x
2
−y
2 , d xy , d xz

D. d x
2 , d yz , d zx

Answer: A

View Text Solution

7. When hybridisation involving d-orbitals are considered then all the five

d-orbitals are not degenerate, rather dx2 − y 2 , ds 2 and d xy , d zx form two

different sets of orbitals and orbitals of appropriate set is involved in the

hybridisation.

Molecule having trigonal bipyramidal geometry and sp d hybridisation, d-

3

orbitals involved is :

A. d xy

B. d yz

C. d x
2
−y
2

D. d z
2

Answer: D

View Text Solution

8. When hybridisation involving d-orbitals are considered then all the five

d-orbitals are not degenerate, rather dx2 − y 2 , ds 2 and d xy , d zx form two

different sets of orbitals and orbitals of appropriate set is involved in the

hybridisation.

Which of the following orbitals can not undergo hybridisation amongst

themselves.
(I) 3d, 4s (II)3d, 4d

(III) 3d, 4s&4p (IV )3s, 3p&4s

A. only II

B. II and III

C. I, II and IV

D. II and IV

Answer: D

Watch Video Solution

Level 3 (Passive 7)

1. Ionic bond is defined as the electrostatic force of attraction holding the

oppositely charged ions. Ionic compounds are mostly crystalline solid

having high melting and boiling points, electrical conductivity in moleten

state, solubility in water etc. Covalent bond is defined as the force which

binds atoms of same or different elements by mutual sharing of electrons

in a covalent bond. Covalent compounds are solids, liquids or gases. They

have low melting and boiling points compounds. They are more soluble in

non-polar solvents.

The valence electrons are involved in formation of covalent bonds is /are

called :

A. non-bonding electrons

B. lone pairs

C. unshared pairs

D. none of these

Answer: D

Watch Video Solution

2. Ionic bond is defined as the electrostatic force of attraction holding the

oppositely charged ions. Ionic compounds are mostly crystalline solid

having high melting and boiling points, electrical conductivity in moleten

state, solubility in water etc. Covalent bond is defined as the force which
binds atoms of same or different elements by mutual sharing of electrons

in a covalent bond. Covalent compounds are solids, liquids or gases. They

have low melting and boiling points compounds. They are more soluble in

non-polar solvents.

The amount of energy released when one mole of ionic solid is formed by

packing of gaseous ion is called :

A. Ionisation energy

B. Solvation energy

C. Lattice energy

D. Hydration energy

Answer: C

Watch Video Solution

3. Ionic bond is defined as the electrostatic force of attraction holding the

oppositely charged ions. Ionic compounds are mostly crystalline solid

having high melting and boiling points, electrical conductivity in moleten

state, solubility in water etc. Covalent bond is defined as the force which

binds atoms of same or different elements by mutual sharing of electrons

in a covalent bond. Covalent compounds are solids, liquids or gases. They

have low melting and boiling points compounds. They are more soluble in

non-polar solvents.

Which of the following is arranged order of increasing boiling point ?

A. H 2
O < CCl4 < CS2 < CO2

B. CO 2
< CS2 < CCl4 < H2 O

C. CS 2
< H2 O < CO2 < CCl4

D. CCl 4
< H2 O < CO2 < CS2

Answer: B

Watch Video Solution

4. Ionic bond is defined as the electrostatic force of attraction holding

the oppositely charged ions. Ionic compounds are mostly crystalline solid

having high melting and boiling points, electrical conductivity in moleten

state, solubility in water etc. Covalent bond is defined as the force which

binds atoms of same or different elements by mutual sharing of electrons

in a covalent bond. Covalent compounds are solids, liquids or gases. They

have low melting and boiling points compounds. They are more soluble in

non-polar solvents.

The valence electrons are involved in formation of covalent bonds is /are

called :

A. non-bonding electrons

B. lone pairs

C. unshared pairs

D. none of these

Answer: D

Watch Video Solution

5. Ionic bond is defined as the electrostatic force of attraction holding the

oppositely charged ions. Ionic compounds are mostly crystalline solid

having high melting and boiling points, electrical conductivity in moleten

state, solubility in water etc. Covalent bond is defined as the force which

binds atoms of same or different elements by mutual sharing of electrons

in a covalent bond. Covalent compounds are solids, liquids or gases. They

have low melting and boiling points compounds. They are more soluble in

non-polar solvents.

The amount of energy released when one mole of ionic solid is formed by

packing of gaseous ion is called :

A. Ionisation energy

B. Solvation energy

C. Lattice energy

D. Hydration energy

Answer: C

Watch Video Solution

6. Ionic bond is defined as the electrostatic force of attraction holding the

oppositely charged ions. Ionic compounds are mostly crystalline solid

having high melting and boiling points, electrical conductivity in moleten

state, solubility in water etc. Covalent bond is defined as the force which

binds atoms of same or different elements by mutual sharing of electrons

in a covalent bond. Covalent compounds are solids, liquids or gases. They

have low melting and boiling points compounds. They are more soluble in

non-polar solvents.

Which of the following is arranged order of increasing boiling point ?

A. H 2
O < CCl4 < CS2 < CO2

B. CO 2
< CS2 < CCl4 < H2 O

C. CS 2
H2 O < CO2 < CCl4

D. CCl 4
< H2 O < CO2 < CS2

Answer: B

Watch Video Solution

Level 3 (Passive 8)

1. When an ionic compound is dissolved in water (polar solvent), it breaks

up into its constituent ions. The given ionic compound will be dissolved

in water if its hydration energy is more than lattice energy . IF hydration

energy is less than lattice energy then ionic compound is usually either

sparingly soluble or insoluble in water.

Which of the following ionic compound is having maximum lattice energy

A. NaF

B. M gF 2

C. AlF 3

D. KF

Answer: C

Watch Video Solution

2. When an ionic compound is dissolved in water (polar solvent), it breaks

up into its constituent ions. The given ionic compound will be dissolved

in water if its hydration energy is more than lattice energy . IF hydration

energy is less than lattice energy then ionic compound is usually either

sparingly soluble or insoluble in water.

Most hydrated cation is :

A. Ce 4+

( aq . )

B. La 3+

( aq . )

C. Ba 2+

( aq . )

D. Cs +

( aq )

Answer: A

Watch Video Solution

3. When an ionic compound is dissolved in water (polar solvent), it breaks

up into its constituent ions. The given ionic compound will be dissolved
in water if its hydration energy is more than lattice energy . IF hydration

energy is less than lattice energy then ionic compound is usually either

sparingly soluble or insoluble in water.

Which of the following ionic compound is having maximum lattice energy

A. NaF

B. M gF 2

C. AlF 3

D. KF

Answer: C

Watch Video Solution

4. When an ionic compound is dissolved in water (polar solvent), it breaks

up into its constituent ions. The given ionic compound will be dissolved

in water if its hydration energy is more than lattice energy . IF hydration

energy is less than lattice energy then ionic compound is usually either
sparingly soluble or insoluble in water.

Most hydrated cation is :

A. Ce 4+

( aq . )

B. La 3+

( aq . )

C. Ba 2+

( aq . )

D. CS +

( aq )

Answer: A

Watch Video Solution

Level 3 (Passive 9)

1. A covalent bond will be formed by the overlapping of atomic orbitals

having single electron of opposite spin, according to the overlapping of

atomic orbitals the covalent bond may be of two types :

(i) Sigma bond (σ) (ii) Pi bond (π)

Sigma bond is stronger bond than the Pi-bond. If atomic orbitals overlap
about the nuclear axis then sigma bond is formed but when atomic

orbitals overlap sideway then Pi-bond is formed.

The correct order of increasing C-O bond length of CO, CO 2−

3
, CO2 is :

A. CO 2−

3
< CO2 < CO

B. CO 2
< CO
2−

3
< CO

C. CO < CO
2−

3
< CO2

D. CO < CO2 < CO

2−

Answer: D

Watch Video Solution

2. A covalent bond will be formed by the overlapping of atomic orbitals

having single electron of opposite spin, according to the overlapping of

atomic orbitals the covalent bond may be of two types :

(i) Sigma bond (σ) (ii) Pi bond (π)

Sigma bond is stronger bond than the Pi-bond. If atomic orbitals overlap

about the nuclear axis then sigma bond is formed but when atomic
orbitals overlap sideway then Pi-bond is formed.

Compound having maximum bond angle is :

A. BBr 3

B. BCl 3

C. BF 3

D. none of these

Answer: D

Watch Video Solution

3. A covalent bond will be formed by the overlapping of atomic orbitals

having single electron of opposite spin, according to the overlapping of

atomic orbitals the covalent bond may be of two types :

(i) Sigma bond (σ) (ii) Pi bond (π)

Sigma bond is stronger bond than the Pi-bond. If atomic orbitals overlap

about the nuclear axis then sigma bond is formed but when atomic

orbitals overlap sideway then Pi-bond is formed.

The strength of bonds formed by 2s-2s,2p-2p and 2p-2s overlap has the

order :

A. s − s > p − p > p − s

B. s − s > p − s > p − p

C. p − p > p − s > s − s

D. p − p > s − s > p − s

Answer: C

Watch Video Solution

4. A covalent bond will be formed by the overlapping of atomic orbitals

having single electron of opposite spin, according to the overlapping of

atomic orbitals the covalent bond may be of two types :

(i) Sigma bond (σ) (ii) Pi bond (π)

Sigma bond is stronger bond than the Pi-bond. If atomic orbitals overlap

about the nuclear axis then sigma bond is formed but when atomic
orbitals overlap sideway then Pi-bond is formed.

The correct order of increasing C-O bond length of CO, CO 2−

3
, CO2 is :

A. CO 2−

3
< CO2 < CO

B. CO 2
< CO
2−

3
< CO

C. CO < CO
2−

3
< CO2

D. CO < CO2 < CO

2−

Answer: D

Watch Video Solution

5. A covalent bond will be formed by the overlapping of atomic orbitals

having single electron of opposite spin, according to the overlapping of

atomic orbitals the covalent bond may be of two types :

(i) Sigma bond (σ) (ii) Pi bond (π)

Sigma bond is stronger bond than the Pi-bond. If atomic orbitals overlap

about the nuclear axis then sigma bond is formed but when atomic
orbitals overlap sideway then Pi-bond is formed.

Compound having maximum bond angle is :

A. BBr 3

B. BCl 3

C. BF 3

D. none of these

Answer: D

Watch Video Solution

6. A covalent bond will be formed by the overlapping of atomic orbitals

having single electron of opposite spin, according to the overlapping of

atomic orbitals the covalent bond may be of two types :

(i) Sigma bond (σ) (ii) Pi bond (π)

Sigma bond is stronger bond than the Pi-bond. If atomic orbitals overlap

about the nuclear axis then sigma bond is formed but when atomic

orbitals overlap sideway then Pi-bond is formed.

The strength of bonds formed by 2s-2s,2p-2p and 2p-2s overlap has the

order :

A. s − s > p − p > p − s

B. s − s > p − s > p − p

C. p − p > p − s > s − s

D. p − p > s − s > p − s

Answer: C

Watch Video Solution

Level 3 (Passive 10)

1. According to VBT the extent of overlapping depends upon types of

orbitals involved in overlapping and nature of overlapping. More will be

the overlapping and the bond energy will also be high.

The incorrect order of bond dissociation energy will be :

A. H − H > Cl − Cl > Br − Br

B. Si − Si > P − P > Cl − Cl

C. C − C > N − N > O − O

D. H − Cl > H − Br > H − I

Answer: B

Watch Video Solution

2. According to VBT the extent of overlapping depends upon types of

orbitals involved in overlapping and nature of overlapping. More will be

the overlapping and the bond energy will also be high.

Which of the following combination of orbitals does not form covalent

bond (x-axis is inter nuclear axis) :

A. s + p y

B. py
+ py

C. d yz
+ d yz
D. d xy
+ d xy

Answer: A

Watch Video Solution

3. According to VBT the extent of overlapping depends upon types of

orbitals involved in overlapping and nature of overlapping. More will be

the overlapping and the bond energy will also be high.

Which of the following compound does not form pπ − pπ bond ?

A. SO 3

B. N O −

C. SO 2−

D. CO 2−

Answer: C

Watch Video Solution

4. According to VBT the extent of overlapping depends upon types of

orbitals involved in overlapping and nature of overlapping. More will be

the overlapping and the bond energy will also be high.

The incorrect order of bond dissociation energy will be :

A. H − H > Cl − Cl > Br − Br

B. Si − Si > P − P > Cl − Cl

C. C − C > N − N > O − O

D. H − Cl > H − Br > H − I

Answer: B

Watch Video Solution

5. According to VBT the extent of overlapping depends upon types of

orbitals involved in overlapping and nature of overlapping. More will be

the overlapping and the bond energy will also be high.

Which of the following combination of orbitals does not form covalent

bond (x-axis is inter nuclear axis) :

A. s + p y

B. py
+ py

C. d yz
+ d yz

D. d xy
+ d xy

Answer: A

Watch Video Solution

6. According to VBT the extent of overlapping depends upon types of

orbitals involved in overlapping and nature of overlapping. More will be

the overlapping and the bond energy will also be high.

Which of the following compound does not form pπ − pπ bond ?

A. SO 3

B. N O −

3
C. SO 2−

D. CO 2−

Answer: C

Watch Video Solution

Level 3 (Passive 11)

1. Consider the following elements with their period number and valence

electrons.
−
Elements Period number Total valencee

P 2 4

Q 2 6

R 3 7

S 3 3

T 3 6

U 3 4

According to the given informations, answer the following questions :

Choose incorrect statement :

A. R exhibits maximum covalency among all elements given

B. Q does not exhibit variable covalency

C. R exhibits minimum covalency among all elements given

D. R and S combine each other and form SR type of compound

5

Answer: D

Watch Video Solution

2. Consider the following elements with their period number and valence

electrons.
−
Elements Period number Total valencee

P 2 4

Q 2 6

R 3 7

S 3 3

T 3 6

U 3 4

According to the given informations, answer the following questions :

Choose the correct statement :

A. Q has maximum value of electron affinity

B. R has maximum value of electronegativity

C. S has maximum atomic size

D. T and U are same group elements

Answer: C

Watch Video Solution

3. Consider the following elements with their period number and valence

electrons.
−
Elements Period number Total valencee

P 2 4

Q 2 6

R 3 7

S 3 3

T 3 6

U 3 4

According to the given informations, answer the following questions :

Choose incorrect statement :

A. SR is a hypovalent compound
3
B. U R can act as a Lewis acid
4

C. P Q can not acts as Lewis acid

2

D. U R 4
> SR 3 : Lewis acidic character

Answer: C

Watch Video Solution

4. Consider the following elements with their period number and valence

electrons.
−
Elements Period number Total valencee

P 2 4

Q 2 6

R 3 7

S 3 3

T 3 6

U 3 4

According to the given informations, answer the following questions :

Choose incorrect statement :

A. R exhibits maximum covalency among all elements given

B. Q does not exhibit variable covalency

C. R exhibits minimum covalency among all elements given

D. R and S combine each other and form SR type of compound

5

Answer: D

Watch Video Solution

5. Consider the following elements with their period number and valence

electrons.
−
Elements Period number Total valencee

P 2 4

Q 2 6

R 3 7

S 3 3

T 3 6

U 3 4

According to the given informations, answer the following questions :

Choose the correct statement :

A. Q has maximum value of electron affinity

B. R has maximum value of electronegativity

C. S has maximum atomic size

D. T and U are same group elements

Answer: C

View Text Solution

6. Consider the following elements with their period number and valence

electrons.
−
Elements Period number Total valencee

P 2 4

Q 2 6

R 3 7

S 3 3

T 3 6

U 3 4

According to the given informations, answer the following questions :

Choose the incorrect statement :

A. SR is a hypovalent compound
3
B. U R can act as a Lewis acid
4

C. P Q can not acts as Lewis acid

2

D. U R 4
> SR 3 : Lewis acidic character

Answer: C

View Text Solution

Level 3 (Passive 12)

1. Hybridisation involves the mixing of orbitals having comparable

energhies of same atom. Hybridised orbitals perform efficient overlapping

than overlapping by pure s, p or orbitals.

Which of the following is not correctly match between given species and

type of overlapping ?

A. XeO : Three (dπ

3
− pπ) bonds

B. H 2
SO4 : Two (dπ − pπ) bonds
C. SO : Three (dπ
3
− pπ) bonds

D. H ClO : Three (dπ

4
− pπ) bonds

Answer: C

Watch Video Solution

2. Hybridisation involves the mixing of orbitals having comparable

energhies of same atom. Hybridised orbitals perform efficient overlapping

than overlapping by pure s, p or orbitals.

Consider the following compounds and select the incorrect statement

from the following :

N H3 , P H3 , H2 S, SO2 , BF3 , P Cl3 , IF7 , P4 , H2

A. Six molecules out of given compounds involves hybridisation

B. Three molecules are hypervalent compounds

C. Six molecules out of above compounds are non-planar in structure

D. Two molecules out of given compounds involves (dπ − pπ)

bonding as well as also involves (pπ − pπ) bonding

Answer: C

Watch Video Solution

3. Hybridisation involves the mixing of orbitals having comparable

energhies of same atom. Hybridised orbitals perform efficient overlapping

than overlapping by pure s, p or orbitals.

Which of the following is not correctly match between given species and

type of overlapping ?

A. XeO : Three (dπ

3
− pπ) bonds

B. H 2
SO4 : Two (dπ − pπ) bonds

C. SO : Three (dπ
3
− pπ) bonds

D. H ClO : Three (dπ

4
− pπ) bonds

Answer: C
Watch Video Solution

4. Hybridisation involves the mixing of orbitals having comparable

energhies of same atom. Hybridised orbitals perform efficient overlapping

than overlapping by pure s, p or orbitals.

Consider the following compounds and select the incorrect statement

from the following :

N H3 , P H3 , H2 S, SO2 , BF3 , P Cl3 , IF7 , P4 , H2

A. Six molecules out of given compounds involves hybridisation

B. Three molecules are hypervalent compounds

C. Six molecules out of above compounds are non-planar in structure

D. Two molecules out of given compounds involves (dπ − pπ)

bonding as well as also involves (pπ − pπ) bonding

Answer: C

Watch Video Solution

ONE OR MORE ANSWERS IS / ARE CORRECT

1. In which of the following there is intermolecular hydrogen bonding ?

A. Water

B. Ethanol

C. Acetic acid

D. H-F

Answer: A::B::C::D

Watch Video Solution

2. Correct order of decreasing boiling points is :

A. H F > H I > H Br > H Cl

B. H 2
O > H2 T e > H2 Se > H2 S

C. Br 2
> Cl2 > F2
D. CH 4
> GeH4 > SiH4

Answer: A::B::C

Watch Video Solution

3. In which species the hybrid state of central atom is / are sp d ?

3

A. I3
−

B. SF 4

C. P F 5

D. IF 5

Answer: A::B::C

View Text Solution

4. Select correct statement(s) is /are :

A. In AsH3 molecule lone pair at central atom is present in almost

pure s-orbital

B. Number of pπ − dπ bond in SO 3
and SO2 are same

C. N F is better Lewis base than N Cl

3 3

D. Stable oxidation state of Lead is + 2

Answer: A::D

Watch Video Solution

5. Which of the following species does / do not exist ?

A. OF 4

B. N H 2
−

C. N Cl 5

D. ICl 2−

Answer: A::C::D
Watch Video Solution

6. Which of the following species is /are superoctet molecule ?

A. AlF 3

B. SiCl 4

C. XeF 2

D. ICl3

Answer: C::D

Watch Video Solution

7. Which of the following statements is incorrect ?

A. Aσ - bond is weaker than aπ-bond

B. There are four co-ordinate bonds in the N H +

4
ions

C. The covalent bond is directional in nature

D. HF is less polar than HCl

Answer: A::B::D

Watch Video Solution

8. Which of the following species is /are capable of forming a coordinate

bond with BF ? 3

A. P H 3

B. N H +

C. OH −

D. M g 2+

Answer: A::C

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9. Ionic compounds in geneal do not possess :

A. high melting points and non-directional bonds

B. high melting points and low-boiling points

C. directional bonds and low-boiling points

D. high solubilities in polar and non-polar solvents

Answer: B::C::D

Watch Video Solution

10. Correct statbility order of metal cation is /are :

A. P b2+
< Sn
2+

B. P b4+ 2+
< Pb

C. Sn 4+
< Sn
2+

D. P b4+
< Sn
4+
Answer: B::D

Watch Video Solution

11. Consider the following molecule :

H2 C = C = C = C = CF2
(1) (2) (3) (4) (5)

Ih hybridization of C(1) carbon atom is 2

sp (s + py + pz and

hybridization of C(4) carbon atom is sp(s + pz ) . Then according to

given information the correct statement(s) is / are :

A. Nodal plane of π -bond between C(2) and C ( 3 ) lies in xz-plane,

formed by sideways overlapping of p -orbitals

y

B. Nodal plane of π -bond between C(3) and C ( 4 ) lies in yz-plane,

formed by side ways overlapping of p -orbitals

x

C. The orbitals involve in hybridization of C(5) carbon atom are

s + px + pz
D. Nodal plane of π -bond between C(1) and C ( 2 ) lies in yz-plane,

formed by side ways overlapping of p -orbitals

y

Answer: A::B::C

View Text Solution

12. Consider the following two molecules and according to the given

information select correct statement(s) about AX 2

and AY2 :

where A: 16th group of 3rd period element

X: more electronegative than (A) and same group number of (A) ltbgt Y:

Less atomic size than (A) and same period number of (A)

A. The hybridization of central atoms are different in both compounds

B. The shape of both molecules are same

C. Both compounds are planar

D. The X-A-X bond angle is less than Y-A-Y bond angle

Answer: A::B::C
Watch Video Solution

13. Which of the following statements are correct about sulphur

hexafluoride ?

A. all S-F bonds are equivalent

B. SF is a planar molecule
6

C. oxidation number of sulphur is the same as number of electrons of

sulphu involved in bonding

D. sulphur has acquired the elctronic structure of the gas argon

Answer: A::C

Watch Video Solution

14. If AB
n

4
types species are tetrahedral, then which of the following is

/are correctly match ?

A B n
A.
Xe O 0

A B n
B.
Se F 0

A B n
C.
P O −3

A B n
D.
N H +1

Answer: A::C::D

Watch Video Solution

15. Which of the following statements is correct ?

A. ClF molecule is bent T-shape

3

B. In SF4 molecule, F-S-F equatorial bond angle is 103

∘
due to lp-lp

repulsion

C. In [ICl molecular ion, Cl-I-Cl bond angle is 90

− ∘
4
]

D. In OBr , the bond angle is less than OCl

2 2

Answer: A::C
Watch Video Solution

16. Which of the following combination of bond pair (b.p.) and lone pair

(l.p.) give same shape ?

(i) 3 b.p.+1 l.p. (ii) 2 b.p.+2 l.p. (iii) 2 b.p.1 l.p. (iv) 2 b.p. + 0 l. p.

(v) 3 b.p. +2 l.p. (vi) 2 b.p.+3 l.p.

A. ii and iii

B. iv and v

C. iv and vi

D. iii and vi

Answer: A::C

Watch Video Solution

17. Select the true statement(s) among the following :

A. Pure overlapping of two d xy orbitals along x-axis results in the

formation of π-bond

B. N O +

2
> NO
−

3
> NO
−

2
is the correct order of bond angle as well

as N-O bond order

C. N F 3
< N Cl3 < N Br 3 < N I3 is the correct order of Lewis basic

character as well as bond angle

D. H F > H Cl > H Br > H I is the correct order of dipole moment

as well as boiling point

Answer: A::C

Watch Video Solution

18. p -orbital can not form π -bond by lateral overlap with :

y

A. d - orbital
xz

B. d x
2
−y
2 -orbitals
C. d -orbital
xy

D. p -orbital
z

Answer: A::B::D

Watch Video Solution

19. Which of the following orbital (s) cannot form δ-bond ?

A. d x
2
−y
2 -orbital

B. d -orbital
xy

C. d -orbital
z
2

D. p -orbital
x

Answer: C::D

Watch Video Solution

20. Select correct statement(s) regarding σ and π bonds :

A. σ - bond lies on the line joining the nuclei of bonded atoms

B. π - electron cloud lies on either side to the line joining the nuclei of

bonded atoms

C. (2p π
− 3d π )π - bond is stronger than (2p
π
− 3pπ )π - bond.

D. σ-bond has primary effect to decide direction of covalent bond,

while π- bond has no primary effect in direction of bond

Answer: A::B::C::D

Watch Video Solution

21. Which of the following statements is / are correct ?

A. All carbon to carbon bonds contain a sigma bond and one or more

π - bonds
B. All carbon to carbon bonds are sigma bonds

C. All oxygen to hydrogen bonds are hydrogen bonds

D. All carbon to hydrogen bonds are sigma bonds

Answer: D

Watch Video Solution

22. Consider the following three orbitals :

Correct statement(s) regarding given information is /are :

A. Orbitals (i) and (ii) can never form any type of covalent bond

B. If internuclear axis is x, then combination of (ii) and (iii) orbitals can

form π- bond
C. Orbital (iii) can form δ- bond with other orbital having same

orientation of lobes

D. If internuclear axis is 'x', then combination of (i) and (iii) orbitals can

form π - bond

Answer: A::C::D

Watch Video Solution

23. Which of the following combination of orbitals can not form bond. (If

x axis in internuclear axis)

A. s + p z

B. s + s

C. pz
+ px

D. d xy
+ py

Answer: A::C
Watch Video Solution

24. Consider the following atomic orbitals :

Which of the following statement(s) is /are correct regarding given

orbital ?

A. It is a gerade atomic orbital

B. It has zero nodal plane

C. Circular electron density is present in XY plane

D. Opposite lobes of orbital have same sign of wave function (ψ)

Answer: A::B::C::D

Watch Video Solution

25. In which of the following there is intermolecular hydrogen bonding ?

A. Water

B. Ethanol

C. Acetic acid

D. H-F

Answer: A::B::C::D

Watch Video Solution

26. Correct order of decreasing boiling points is :

A. H F > H I > H Br > H Cl

B. H 2
O > H2 T e > H2 Se > H2 S

C. Br 2
> Cl2 > F2

D. CH 4
> GeH4 > SiH4

Answer: A::B::C

Watch Video Solution

27. In which species the hybrid state of central atom is / are sp

3
d ?

A. I3
−

B. SF 4

C. P F 5

D. IF 5

Answer: A::B::C

Watch Video Solution

28. Select correct statement(s) is /are :

A. In AsH3 molecule lone pair at central atom is present in almost

pure s-orbital

B. Number of pπ − dπ bond in SO 3
and SO2 are same

C. N F is better Lewis base than N Cl

3 3

D. Stable oxidation state of Lead is + 2

Answer: A::D

Watch Video Solution

29. Which of the following species does / do not exist ?

A. OF 4

B. N H 2
−

C. N Cl 5
D. ICl2−

Answer: A::C::D

Watch Video Solution

30. Which of the following species is /are superoctet molecule ?

A. AlF 3

B. SiCl 4

C. XeF 2

D. ICl3

Answer: C::D

Watch Video Solution

31. Which of the following statements is incorrect ?

A. Aσ - bond is weaker than aπ-bond

B. There are four co-ordinate bonds in the N H +

4
ions

C. The covalent bond is directional in nature

D. HF is less polar than HCl

Answer: A::B::D

View Text Solution

32. Which of the following species is /are capable of forming a coordinate

bond with BF ? 3

A. P H 3

B. N H +

C. OH −

D. M g 2+

Answer: A::C
Watch Video Solution

33. Ionic compounds in geneal do not possess :

A. high melting points and non-directional bonds

B. high melting points and low-boiling points

C. directional bonds and low-boiling points

D. high solubilities in polar and non-polar solvents

Answer: B::C::D

Watch Video Solution

34. Correct statbility order of metal cation is /are :

A. P b2+
< Sn
2+

B. P b4+ 2+
< Pb

C. Sn 4+
< Sn
2+
D. P b4+
< Sn
4+

Answer: B::D

Watch Video Solution

35. Consider the following molecule :

H2 C = C = C = C = CF2
(1) (2) (3) (4) (5)

Ih hybridization of C(1) carbon atom is 2

sp (s + py + pz and

hybridization of C(4) carbon atom is sp(s + pz ) . Then according to

given information the correct statement(s) is / are :

A. Nodal plane of π -bond between C(2) and C ( 3 ) lies in xz-plane,

formed by sideways overlapping of p -orbitalsy

B. Nodal plane of π -bond between C(3) and C ( 4 ) lies in yz-plane,

formed by side ways overlapping of p -orbitalsx

C. The orbitals involve in hybridization of C(5) carbon atom are

s + px + pz
D. Nodal plane of π -bond between C(1) and C ( 2 ) lies in yz-plane,

formed by side ways overlapping of p -orbitals

y

Answer: A::B::C

View Text Solution

36. Consider the following two molecules and according to the given

information select correct statement(s) about AX 2

and AY2 :

where A: 16th group of 3rd period element

X: more electronegative than (A) and same group number of (A) ltbgt Y:

Less atomic size than (A) and same period number of (A)

A. The hybridization of central atoms are different in both compounds

B. The shape of both molecules are same

C. Both compounds are planar

D. The X-A-X bond angle is less than Y-A-Y bond angle

Answer: A::B::C
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37. Which of the following statements are correct about sulphur

hexafluoride ?

A. all S − F bonds are equivalent

B. SF is a planar molecule
6

C. oxidation number of sulphur is the same as number of electrons of

sulphu involved in bonding

D. sulphur has acquired the elctronic structure of the gas argon

Answer: A::C

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38. If AB
n

4
types species are tetrahedral, then which of the following is

/are correctly match ?

A B n
A.
Xe O 0

A B n
B.
Se F 0

A B n
C.
P O −3

A B n
D.
N H +1

Answer: A::C::D

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39. Which of the following statements is correct ?

A. ClF molecule is bent T-shape

3

B. In SF4 molecule, F-S-F equatorial bond angle is 103

∘
due to lp-lp

repulsion

C. In [ICl 4
]
−
molecular ion, Cl-I-Cl bond angle is 90 ∘

D. In OBr , the bond angle is less than OCl

2 2

Answer: A::C
View Text Solution

40. Which of the following combination of bond pair (b.p.) and lone pair

(l.p.) give same shape ?

(i) 3 b.p.+1 l.p. (ii) 2 b.p.+2 l.p. (iii) 2 b.p.1 l.p. (iv) 2 b.p. + 0 l. p.

(v) 3 b.p. +2 l.p. (vi) 2 b.p.+3 l.p.

A. ii and iii

B. iv and v

C. iv and vi

D. iii and vi

Answer: A::C

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41. Select the true statement(s) among the following :

A. Pure overlapping of two d xy orbitals along x-axis results in the

formation of π-bond

B. N O +

2
> NO
−

3
> NO
−

2
is the correct order of bond angle as well

as N-O bond order

C. N F 3
< N Cl3 < N Br 3 < N I3 is the correct order of Lewis basic

character as well as bond angle

D. H F > H Cl > H Br > H I is the correct order of dipole moment

as well as boiling point

Answer: A::C

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42. p -orbital can not form π -bond by lateral overlap with :

y

A. d - orbital
xz

B. d x
2
−y
2 -orbitals
C. d -orbital
xy

D. p -orbital
z

Answer: A::B::D

View Text Solution

43. Which of the following orbital (s) cannot form δ-bond ?

A. d x
2
−y
2 -orbitals

B. d -orbital
xy

C. d -orbital
z
2

D. p -orbital
x

Answer: C::D

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44. Select correct statement(s) regarding σ and π bonds :

A. σ - bond lies on the line joining the nuclei of bonded atoms

B. π - electron cloud lies on either side to the line joining the nuclei of

bonded atoms

C. (2p π
− 3d π )π - bond is stronger than (2p
π
− 3pπ )π - bond.

D. σ-bond has primary effect to decide direction of covalent bond,

while π- bond has no primary effect in direction of bond

Answer: A::B::C::D

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45. Which of the following statements is / are correct ?

A. All carbon to carbon bonds contain a sigma bond and one or more

π - bonds
B. All carbon to carbon bonds are sigma bonds

C. All oxygen to hydrogen bonds are hydrogen bonds

D. All carbon to hydrogen bonds are sigma bonds

Answer: D

View Text Solution

46. Consider the following three orbitals :

Correct statement(s) regarding given information is /are :

A. Orbitals (i) and (ii) can never form any type of covalent bond

B. If internuclear axis is x, then combination of (ii) and (iii) orbitals can

form π- bond
C. Orbital (iii) can form δ - bond with other orbital having same

orientation of lobes

D. If internuclear axis is 'x', then combination of (i) and (iii) orbitals can

form π - bond

Answer: A::C::D

View Text Solution

47. Which of the following combination of orbitals do / does not form

bond (if x-axis is internuclear axis) ?

A. s + p z

B. s + s

C. pz
+ px

D. d xy
+ py

Answer: A::C
View Text Solution

48. Consider the following atomic orbitals :

Which of the following statement(s) is /are correct regarding given

orbital ?

A. It is a gerade atomic orbital

B. It has zero nodal plane

C. Circular electron density is present in XY plane

D. Opposite lobes of orbital have same sign of wave function (ψ)

Answer: A::B::C::D

View Text Solution

MATCH THE COLUMN

1. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.

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2. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one
entries of Column-I may have the matching with the same entries of

Column-II.

Watch Video Solution

3. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.

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4. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one
entries of Column-I may have the matching with the same entries of

Column-II.

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5. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.

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6. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.

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7. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.

View Text Solution

8. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.

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9. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of
Column-II.

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10. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.

View Text Solution

11. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.

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12. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.
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13. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.

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14. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.
View Text Solution

15. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.

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16. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.
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17. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.

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18. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of
Column-II.

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19. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.

View Text Solution

20. Column-I and Column -II contains four entries each. Entries of Column-

I are to be matched with some entries of Column-II. One or more than one
entries of Column-I may have the matching with the same entries of

Column-II.

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21. Column-I and Column -II contains four entries each. Entries of Column-I

are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.

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22. Column-I and Column -II contains four entries each. Entries of Column-

I are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.

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23. Column-I and Column -II contains four entries each. Entries of Column-

I are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of
Column-II.

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24. Column-I and Column -II contains four entries each. Entries of Column-

I are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.

View Text Solution

25. Column-I and Column -II contains four entries each. Entries of Column-

I are to be matched with some entries of Column-II. One or more than one

entries of Column-I may have the matching with the same entries of

Column-II.

View Text Solution

ASSERTION-REASON TYPE QUESTIONS

1. Assertion : Multiple bond between two bonded atoms can have more

than three bonds.

Reason : Multiple bond between two bonded atoms can not have more

than two π-bonds.

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: D

View Text Solution

2. Assertion : 2 nd
period elements do not involve in excitation of electron.

Reason : 2 nd
period elements do not have vacant 2d-orbitals.

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion
D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: B

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3. Assertion : In SO3 molecule bond dissociation energy of all S=O bonds

are not equivalent.

Reason : SO molecule is having two types of 2pπ

3
− 3pπ and 2pπ − 3dπ

pi-bonds.

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion
Answer: B

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4. Assertion : P H +

4
ion is having tetrahedron geometry.

Reason : P-atom is unhybridised in P H +

4
ion.

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: A

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5. Assertion : All diatomic molecules with polar bond have dipole moment.

Reason : Dipole moment is a vector quantity.

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: D

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6. Assertion : Water is a good solvent for ionic compounds but poor one

for covalent compounds.

Reason :Hydrogen energy of ions realeases sufficient energy to overcome

lattice energy and break hydrogen bonds in water, white covalent bonded
compound interact so weakly that even van der walls force between

molecule of convalent compounds cannot be broken .

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: C

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7. Assertion : Xe-atom in XeF assumes sp-hybrid state.

2

Reason : XeF molecule does not follow octet rule.

2

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: B

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8. Assertion : The atoms in a covalent molecule are said to share

electrons, yet some covalent molecule are polar.

Reason :In a polar covalent molecule , the shared electron spend more

time on the average near one of the atoms .

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: C

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9. Assertion : CCl is a non-polar molecule.

4

Reason : CCl has polar bonds.

4

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion
D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: D

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10. Assertion : Geometry of ICl is tetrahedral.

3

Reason : Its shape is T-shape, due to the presence of two lone pairs.

A. assertion is true but the reason is false

B. assertion is false but reason is true

C. both assertion and reason are true and the reason is the correct

explanation of assertion

D. both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: B
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11. Assertion : The covalency of carbon is four in excited state.

Reason : The four half-filled pure orbitals of carbon form same kind of

bonds with an atom as those are with hybridised orbitals.

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: A

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12. Assertion : The shape of XeF is square- planar.
4

Reason : In an octahedral geometry, a single lone pair can occupy any

position but a second lone pair will occupy the opposite position to the

first lone pair.

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: C

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13. Assertion : Multiple bond between two bonded atoms can have more

than three bonds.

Reason : Multiple bond between two bonded atoms can not have more

than two π-bonds.

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: D

View Text Solution

14. Assertion : 2
nd
period elements do not involve in excitation of

electron.

Reason : 2 nd
period elements do not have vacant 2d-orbitals.

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: B

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15. Assertion : In SO molecule bond dissociation energy of all S=O bonds

3

are not equivalent.

Reason : SO molecule is having two types of 2pπ
3
− 3pπ and 2pπ − 3dπ

pi-bonds.

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: B

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16. Assertion : P H +

4
ion is having tetrahedron geometry.

Reason : P-atom is unhybridised in P H +

4
ion.

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: A

View Text Solution

17. Assertion : All diatomic molecules with polar bond have dipole

moment.

Reason : Dipole moment is a vector quantity.

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion
D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: D

Watch Video Solution

18. Assertion : Water is a good solvent for ionic compounds but poor one

for covalent compounds.

Reason :Hydrogen energy of ions realeases sufficient energy to overcome

lattice energy and break hydrogen bonds in water, white covalent bonded

compound interact so weakly that even van der walls force between

molecule of convalent compounds cannot be broken .

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion
D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: C

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19. Assertion : Xe-atom in XeF assumes sp-hybrid state.

2

Reason : XeF molecule does not follow octet rule.

2

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: B
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20. Assertion : The atoms in a covalent molecule are said to share

electrons, yet some covalent molecule are polar.

Reason :In a polar covalent molecule , the shared electron spend more

time on the average near one of the atoms .

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: C

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21. Assertion : CCl is a non-polar molecule.
4

Reason : CCl has polar bonds.

4

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: D

View Text Solution

22. Assertion : Geometry of ICl is tetrahedral.

3

Reason : Its shape is T-shape, due to the presence of two lone pairs.

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: B

View Text Solution

23. Assertion : The covalency of carbon is four in excited state.

Reason : The four half-filled pure orbitals of carbon form same kind of

bonds with an atom as those are with hybridised orbitals.

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion
D. If both assertion and reason are true but reason is not the correct

explanation of assertion

Answer: A

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24. Assertion : The shape of XeF is square- planar.

4

Reason : In an octahedral geometry, a single lone pair can occupy any

position but a second lone pair will occupy the opposite position to the

first lone pair.

A. If assertion is true but the reason is false

B. If assertion is false but reason is true

C. IF both assertion and reason are true and the reason is the correct

explanation of assertion

D. If both assertion and reason are true but reason is not the correct

explanation of assertion
Answer: C

Watch Video Solution

SUBJECTIVE PROBLEMS

1. Consider following compounds A to E :

(A) XeF n
(B)XeF
+

( n+1)
(C)XeF
−

( n+1)
(D)XeF ( n + 2 )

(E ) XeF 2−

( n+4)
,

If value of n is 4, then calculate value of p ÷ q here, 'p' is total number of

bond pair and 'q' is total number of lone pair on central atoms of

compounds (A) to (E ).

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2. Consider the following five group (According to modern periodic table)

of elements with their increasing order to atomic numbers :

Group 1 → A, B, C, D, E Group2 → F , G, H , I, J
Group

13 → K, L, M , N , O Group15 → P , Q, R, S, T Group 17 → U

IF first and last element of each group belongs to 2nd and 6th period

respectively and Z represents to carbonate ion (CO

2−

3
) then consider

the following orders.

(i)O
+
> H
2+
, Polarising power

(ii) T 3+
> S
3+
> R
3+
, Stability of cation

(iii)U
−
(aq) > V
−
(aq) > W
−
(aq) > X
−
(aq) , Size

(iv) J V 2
< IV2 < GV2 < LV3 , Covalent character

(v) GZ > IZ > J Z , Thermal stability

(vi) AV > BV > CV > DV > EV , Thermal stability

(vii) C 3
P > B3 P > A 3 P , Lattice energy

(viii) KU 3
< KV3 < KW3 < KX3 , Melting point

Then calculate value of |p − q|

2
, here p and q are correct and incorrect

orders in the given eight orders respectively.

View Text Solution

3. Consider the following species and find out total number of species

which are polar and can act as Lewis acid

CCl4 , CO2 , SO2 , AlCl3 , H CH O, SO3 , SiCl4 , BCl3 , CF4

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4. Consider the following table regarding interhalogen compounds, XY n

(where Y is more electronegative than X)

Thn according to given information calculate value of expression

P3 − P1
P2 × (
(Q1 + Q2 )

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5. What is covalency of chlorine atom in second excited state ?

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6. Sum of σ and π bonds in N H 4
+
cation is ..

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7. Calculate the value X − Y for XeOF4 . (X = Number of σ bond pair

and Y = Number of Ione pair on central atom).

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8. The molecule AB is planar with six pairs of electrons around A in the

n

valence shell. The value of n is

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X + Y + Z
9. Calculate value of , here X is O-N-O bond angle in NO
−

3
Y
10

is O-N-O bond angle in NO

+

2
and Z is F-Xe-F adjacent bond angle in
XeF4 .

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10. Calculate x+y+z for H 3

P O3 acid, where x is no. of lone pairs, y is no. of

σ bonds and z is no. of π bonds.

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11. How many right angle, bond angles are present in T eF

−

5
molecular

ion ?

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12. How may possible ∠F SeF bond angles are present in SeF4 molecule

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13. In IF
−

6
and T eF
−

5
, sum of axial d-orbitals which are used in

hybridisation in both species.

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14. Among the following, total no. of planar species is :

(i) SF 4
(ii)BrF3 (iii)XeF2 (iv)IF5

(v)SbF −

4
(vi)SF
−

5
(vii)SeF
+

3
(viii)CH
+

(ix) P Cl +

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15. Calculate the value of " x+y-z" here x,y and z are total number of non-

bonded electron pair (s),pie (π) bond(s) and sigma (σ) bonds in

hydrogen phosphite ion respectively.

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16. Consider the following table

Then calculate value of "p+q+r-s-t".

View Text Solution

17. In phosphorus acid, if X is number of non bonding electron pairs. Y is

number of σ-bonds and Z is number of π- bonds. Then, calculate value of

Y × Z − X .

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18. Calculate the number of p π

− dπ bond(s) present in SO 2−

4
:

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19. Sum of σ and π bonds in N H +

4
cation is ..

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20. Consider the following orbitals (i)3p (ii)4d

x x
2 (iii)3d x
2
−y
2 (iv)3d yz

Then, calculate value of "x + y − z " here x is total number of gerade

orbital and y is total number of ungerade orbitals and z is total number

of axial orbitals in given above orbitals.

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21. Calculate value of |x-y|, here x and y are the total number of bonds in

benzene and benzyne respectively which are formed by overlapping of

hybridized orbitals.

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22. Consider the following compounds :

− −
(i)IF5 (ii)ClI (iii)XeO2 F2 (iv)N H
4 2

+
(v)BCl3 (vi)BeCl2 (vii)AsCl (viii)B(OH )
4 3

(ix) N O −

2
(x)ClO
+

Then calculate value of "x+y-z", here, x,y and z are total number of

compounds in given compounds in which central atom used their all

three p-orbitals, only two p-orbitals and only one p-orbital in

hybridisation respectively .

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23. Total number of species which used all three p-orbitals in

hybridisation of central atom and should be non-polar also.

+ +
XeO2 F2 , SnCl2 , IF5 , I , XeO4 , SO2 , XeF , SeF4
3 7

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24. Consider the following species

− 2− − 3− 2− 2−
NO , SO , ClO , SO3 , P O , XeO3 , CO , SO
3 4 3 4 3 3

Then calculate value of |x-y|, where

x : Total number of species which have bond order 1.5 or greater than 1.5

y : Total number of species which have bond order less than 1.5

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25. Consider the following orbitals

3s, 2px , 4d xy , 4d z 2 , 3d x2 − y 2 , 3py , 4s, 4pz and find total number of orbital

(s) having even number of nodal plane.

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26. For the following molecules :

− − − + +
P Cl5 , BrF3 , ICl , XeF , NO , XeO2 F2 , P Cl , CH
2 5 3 4 3

a + b
Calculate the value of
c

a = Number of species having sp d-hybridisation 3

b= Number of species which are planar

c= Number of species which are non-planar

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27. Find out number of transformation among following which involves

the change of hybridisation of underlined atom.

(a)

+ +
H2 O + H → H3 O (b)N H3 + B F3 → N H3 . U nderl ∈ e(B)F3
–
– –
– –
–

(c ) –X
–
eF 6
→ X eF
–– 5
+
+ F
−
(d)2 P Cl5 → P Cl
–– –
–
+

4
) + P Cl
6
−

(e ) –C
–
H 3
− CH3 → C H
–
– 3
−
+ CH
+

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28. Consider following compounds A to E :

(A) XeF n
(B)XeF
+

( n+1)
(C)XeF
−

( n+1)
(D)XeF ( n + 2 )

(E ) XeF 2−

( n+4)
,

If value of n is 4, then calculate value of p ÷ q here, 'p' is total number of

bond pair and 'q' is total number of lone pair on central atoms of

compounds (A) to (E ).

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29. Consider the following five group (According to modern periodic

table) of elements with their increasing order to atomic numbers :

Group 1 → A, B, C, D, E Group2 → F , G, H , I, J

Group

13 → K, L, M , N , O Group15 → P , Q, R, S, T Group 17 → U

IF first and last element of each group belongs to 2nd and 6th period

respectively and Z represents to carbonate ion (CO

2−

3
) then consider

the following orders.

(i)O
+
> H
2+
, Polarising power

(ii) T 3+
> S
3+
> R
3+
, Stability of cation

(iii)U
−
(aq) > V
−
(aq) > W
−
(aq) > X
−
(aq) , Size

(iv) J V 2
< IV2 < GV2 < LV3 , Covalent character

(v) GZ > IZ > J Z , Thermal stability

(vi) AV > BV > CV > DV > EV , Thermal stability

(vii) C
3
P > B3 P > A 3 P , Lattice energy

(viii) KU 3
< KV3 < KW3 < KX3 , Melting point

Then calculate value of , here p and q are correct and incorrect

2
|p − q|

orders in the given eight orders respectively.

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30. Consider the following species and find out total number of species

which are polar and can act as Lewis acid

CCl4 , CO2 , SO2 , AlCl3 , H CH O, SO3 , SiCl4 , BCl3 , CF4

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31. Consider the following table regarding interhalogen compounds, XY n

(where Y is more electronegative than X)

Thn according to given information calculate value of expression
P3 − P1
P2 × (
(Q1 + Q2 )

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32. What is covalency of chlorine atom in second excited state ?

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33. Sum of σ and π bonds in N H +

4
cation is ..

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34. Calculate the value X − Y for XeOF . (X

4 = Number of σ bond pair

and Y = Number of Ione pair on central atom).

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35. The molecule M Lx is planar with 6 electron pairs around M in the

valence shell. The value of x is :

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X + Y + Z
36. Calculate value of , here X is O-N-O bond angle in N O 3
−
Y
10

is O-N-O bond angle in NO

+

2
and Z is F-Xe-F adjacent bond angle in

XeF4 .

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37. Calculate x+y+z for H 3

P O3 acid, where x is no. of lone pairs, y is no. of

σ bonds and z is no. of π bonds.

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38. How many right angle, bond angles are present in T eF
−

5
molecular

ion ?

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39. How may possible ∠F SeF bond angles are present in SeF4 molecule

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40. In IF
−

6
and T eF
−

5
, sum of axial d-orbitals which are used in

hybridisation in both species.

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41. Among the following, total no. of planar species is :

(i) SF 4
(ii)BrF3 (iii)XeF2 (iv)IF5
(v)SbF
− − + +
(vi)SF (vii)SeF (viii)CH
4 5 3 3

(ix) P Cl
+

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42. Calculate the value of " x+y-z" here x,y and z are total number of non-

bonded electron pair (s),pie (π) bond(s) and sigma (σ) bonds in

hydrogen phosphite ion respectively.

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43. Consider the following table

Then calculate value of "p+q+r-s-t".

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44. In phosphorus acid, if X is number of non bonding electron pairs. Y is

number of σ-bonds and Z is number of π- bonds. Then, calculate value of

Y × Z − X .

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45. Calculate the number of p bond(s) present in SO :

2−
π
− dπ
4

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46. Sum of σ and π bonds in N H +

4
cation is ..

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47. Consider the following orbitals (i)3p (ii)4d

x x
2 (iii)3d x
2
−y
2 (iv)3d yz

Then, calculate value of "x + y − z " here x is total number of gerade

orbital and y is total number of ungerade orbitals and z is total number

of axial orbitals in given above orbitals.

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48. Calculate value of |x-y|, here x and y are the total number of bonds in

benzene and benzyne respectively which are formed by overlapping of

hybridized orbitals.

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49. Consider the following compounds :

− −
(i)IF5 (ii)ClI (iii)XeO2 F2 (iv)N H
4 2

+
(v)BCl3 (vi)BeCl2 (vii)AsCl (viii)B(OH )
4 3

(ix) N O −

2
(x)ClO
+

Then calculate value of "x+y-z", here, x,y and z are total number of

compounds in given compounds in which central atom used their all

three p-orbitals, only two p-orbitals and only one p-orbital in

hybridisation respectively .
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50. Total number of species which used all three p-orbitals in

hybridisation of central atom and should be non-polar also.

+ +
XeO2 F2 , SnCl2 , IF5 , I , XeO4 , SO2 , XeF , SeF4
3 7

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51. Consider the following species

− 2− − 3− 2− 2−
NO , SO , ClO , SO3 , P O , XeO3 , CO , SO
3 4 3 4 3 3

Then calculate value of |x-y|, where

x : Total number of species which have bond order 1.5 or greater than 1.5

y : Total number of species which have bond order less than 1.5

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52. Consider the following orbitals

3s, 2px , 4d xy , 4d z 2 , 3d x2 − y 2 , 3py , 4s, 4pz and find total number of orbital
(s) having even number of nodal plane.

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53. For the following molecules :

− − − + +
P Cl5 , BrF3 , ICl , XeF , NO , XeO2 F2 , P Cl , CH
2 5 3 4 3

a + b
Calculate the value of
c

a = Number of species having sp d-hybridisation

3

b= Number of species which are planar

c= Number of species which are non-planar

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54. Find out number of transformation among following which involves

the change of hybridisation of underlined atom.

(a)

+ +
H2 O + H → H3 O (b)N H3 + B F3 → N H3 . U nderl ∈ e(B)F3
–
– –
– –
–
(c ) –X
–
eF 6
→ X eF
––
+

5
+ F
−
(d)2 P Cl5 → P Cl
–– –
–
+

4
) + P Cl
−

(e ) –C
–
H 3
− CH3 → C H
–
– 3
−
+ CH
+

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