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CH 4 Class 11 PQP

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12 views

CH 4 Class 11 PQP

Uploaded by

au7801856
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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GG INTERNATIONAL SCHOOL – PIMPRI.

ACADEMIC SESSION:2024-25

NAME : CODE: XI-CHE-04


ROLL NO/ DATE : Lesson: Chemical Bonding and Molecular
Structure
Marks : 30 M PREPARED BY: Ms Vandana Pimparkar

Section A: Multiple Choice Questions (1 Mark each)

1. Which of the following molecules has a non-zero dipole moment?


a) BeCl₂ b) BF₃ c) H₂O d) CO₂

2. Which of the following has the highest bond order?


a) O₂ b) NO c) O₂⁻² d) N₂

Section B: Assertion-Reason Questions (1 Mark each)


a) Both A and R are true, and R is the correct explanation of A.
b) Both A and R are true, but R is not the correct explanation of A.
c) A is true, but R is false.
d) A is false, but R is true.

3. Assertion (A): HF has a higher dipole moment than HCl.


Reason (R): Fluorine is more electronegative than chlorine.

4. Assertion (A): The bond angle in H₂O is smaller than in NH₃.


Reason (R): Lone pair-bond pair repulsion is greater than bond pair-bond pair repulsion.

Section C: Very Short Answer Questions (1 Mark each)

5. What is the shape of XeF₄ according to VSEPR theory?

6. Why is a hydrogen bond stronger than van der Waals forces but weaker than covalent
bonds?

Section D: Short Answer Questions - I (2 Marks each)

7. Explain why the bond angle in ammonia is greater than that in water, even though both
molecules have lone pairs of electrons.

8. Using the concept of hybridization, explain the shape of ethane (CH3-CH3).

Section E: Short Answer Questions - II (3 Marks each)

9. a) Calculate the bond order of NO molecule.


b) Explain why O₂ is paramagnetic while N₂ is diamagnetic, based on molecular orbital
theory.
10. Compare the ionic and covalent character of NaCl and LiCl, based on Fajan's rule.

Section F: Long Answer Questions (5 Marks each)

11. a) Describe the formation of sigma (σ) and pi (π) bonds.


b) Explain the concept of hybridization in the context of sp³ hybridization in carbon, with an
example.

12. a) Explain the difference between the shapes of SF₆ and XeF₄, considering VSEPR
theory.
b) Discuss the molecular orbital diagram of O2, highlighting its bond order and magnetic
properties.

Section G: Case Study-based Question (5 Marks)

13. Case Study: The discovery of resonance in certain molecules helped to explain their
exceptional stability and bond lengths.

a) Explain why the bond length in the carbonate ion (CO₃²⁻) is intermediate between single
and double bonds.

b) Benzene is more stable than expected based on the Kekulé structure. Explain this stability
in terms of resonance.

c) What is the significance of resonance energy in stabilizing molecules like benzene?

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