Physics: Crash Course For JEE Main 2020
Physics: Crash Course For JEE Main 2020
HEAT TRANSFER,
KINETIC THEORY OF GASES
&
THERMODYNAMICS
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1 3 3
Total translational K.E. of gas = M < V2 > = PV = nRT
T
2 2 2
3P 3P 3RT 3KT
< V2 > = Vrms = = =
Mmol m
Important Points :
8KT KT KT
– Vrms V
T m = 1.59 m
Vrms = 1.73
m
2KT KT
Most probable speed Vp = = 1.41 Vrms > V > Vmp
m m
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Degree of freedom :
Mono atomic f = 3
Diatomic f = 5
polyatomic f = 6
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Maxwell’s law of equipartition of energy :
Total K.E. of the molecule = 1/2 f KT
For an ideal gas :
Internal energy U =
f
nRT
N
SI
2
Vf
Workdone in isothermal process : W = [2.303 nRT log10 ]
Vi
Internal energy in isothermal process :
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U = 0
Work done in isochoric process : dW = 0
Change in int. energy in isochoric process :
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f
U = n
R T = heat given
2
Isobaric process :
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f f
Specific heat : Cv =
R Cp = 1 R
2 2
Molar heat capacity of ideal gas in terms of R :
Cp
(i) for monoatomic gas : = 1.67
Cv
Cp
(ii) for diatomic gas : = 1.4
Cv
Cp
(iii) for triatomic gas : = 1.33
Cv
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Cp
2
In general : = = 1
Cv f
Mayer’s eq. Cp – Cv = R for ideal gas only
Adiabatic process :
nR (Ti Tf )
Work done W =
1
In cyclic process :
Q = W
In a mixture of non-reacting gases :
n1M1 n2M2
Mol. wt. = n1 n 2
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n1C v 1 n 2C v 2
Cv =
n1 n 2
n1Cp n2 Cp .....
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Cp (mix) 1 2
= C = n C n C ....
v (mix) 1 v1 2 v2
Heat Engines
N
SI
O
O
ET
W QH – Q L Q
= Q Q 1– L
H H Q H
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Entropy
f
Q Q
change in entropy of the system is S =
T
S f – Si
i
T
In an adiabatic reversible process, entropy of the system remains con-
stant.
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(1) Operation I (Isothermal Expansion)
(2) Operation II (Adiabatic Expansion)
(3) Operation III (Isothermal Compression)
(4) Operation IV (Adiabatic Compression)
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Thermal Efficiency of a Carnot engine
V2 V3 Q 2 T2 T
1– 2
V1 V4 Q1 T1 T1 N
SI
O
O
ET
Refrigerator
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Q2 1 1
Coefficient of performance, = = T
W T1 1
–1 –1
T2 T2
V
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Constant Pressure : T= T
V V 0
(c) Electrical Resistance Thermometer :
R t R0
T = R R × 100
D
100 0
Thermal Expansion :
(a) Linear :
L
= L T
0
or
N
L = L0 (1 + T)
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(b) Area/superficial :
A
= A T or A = A0 (1 + T)
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0
(c) volume/ cubical :
V
O
r = V T or V = V0 (1 + T)
0
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2 3
Thermal stress of a material :
F
Y
A
Energy stored per unit volume :
1 1 AY
E= K(L)2 or E ( L)2
2 2 L
Variation of time period of pendulum clocks :
1
T = T
2
T’ < T - clock-fast : time-gain
T’ > T - clock slow : time-loss
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CALORIMETRY :
Q
Specific heat S =
m.T
Q
Molar specific heat C =
n.T
Water equivalent = mWSW
HEAT TRANSFER
dQ dT
Thermal Conduction : = – KA
dt dx
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Thermal Resistance : R=
KA
D
(i) Series :
K eq = K 1 K 2
....... (when A = A = A = .........)
1 2 3
d
E of a body at T temp.
Emissivity : e=
E of a black body at T temp.
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E (body )
Kirchoff’s law : a(body ) = E (black body)
Wein’s Displacement law : m . T = b.
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b = 0.282 cm-k
Stefan Boltzmann law :
u = T4 s = 5.67 × 10–8 W/m2 k4
u = u – u0 = e A (T4 – T04)
d
Newton’s law of cooling : = k ( – 0) ; = 0 + (i – 0) e–k t
dt
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(A) (B) (C) (D)
Q.3 A ring consisting of two parts ADB and ACB of same conductivity k carries an
amount of heat H. The ADB part is now replaced with another metal keeping
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the temperatures T1 and T2 constant. The heat carried increases to 2H. What
ACB
7
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should be the conductivity of the new ADB part? Given
5
ADB
= 3:
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(A) k (B) 2 k (C) k (D) 3 k
3 2
Q.4 Three identical rods AB, CD and PQ are joined as shown. P and Q are mid
points of AB and CD respectively. Ends A, B, C and D are maintained at
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0°C, 100°C, 30°C and 60°C respectively. The direction of heat flow in PQ is
(A) from P to Q (B) from Q to P
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K/2 5K K
(A) 15K/16 (B) 6K/13 (C) 5K/16 (D) 2K/13
Q.9 The rate of emission of radiation of a black body at 273°C is E, then the rate of emission of radiation of
this body at 0°C will be
E E E
(A) (B) (C) (D) 0
16 4 8
Q.10 A system S receives heat continuously from an electrical heater of power 10W. The temperature of S
becomes constant at 50°C when the surrounding temperature is 20°C. After the heater is switched off,
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S cools from 35.1°C to 34.9°C in 1 minute. The heat capacity of S is
(A) 100J/°C (B) 300J/°C (C) 750J/°C (D) 1500J/°C
Q.11 Find the approx. number of molecules contained in a vessel of volume 7 litres at 0°C at 1.3 × 105 pascal
(A) 2.4 × 1023 (B) 3 × 1023 (C) 6 × 1023 (D) 4.8 × 1023
D
Q.12 A cylindrical tube of cross-sectional area A has two air tight frictionless pistons at its two ends. The
pistons are tied with a straight two ends. The pistons are tied with a straight piece of metallic wire. The
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tube contains a gas at atmospheric pressure P0 and temperature T0. If temperature of the gas is doubled
then the tension in the wire is
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(A) 4 P0 A (B) P0A/2
(C) P0 A (D) 2 P0 A
Q.13 At a temperature T K, the pressure of 4.0g argon in a bulb is p. The bulb is put in a bath having
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temperature higher by 50K than the first one. 0.8g of argon gas had to be removed to maintained original
pressure. The temperature T is equal to
(A) 510 K (B) 200 K (C) 100 K (D) 73 K
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Q.14 When 2 gms of a gas are introduced into an evacuated flask kept at 250C the pressure is found to be one
atmosphere. If 3 gms of another gas added to the same flask the pressure becomes 1.5 atmospheres.
ET
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Q.18 28 gm of N2 gas is contained in a flask at a pressure of 10 atm and at a temperature of 57°. It is found
that due to leakage in the flask, the pressure is reduced to half and the temperature reduced to 27°C.
The quantity of N2 gas that leaked out is
(A) 11/20 gm (B) 20/11 gm (C) 5/63 gm (D) 63/5 gm
Q.20 A vessel contains 1 mole of O2 gas (molar mass 32) at a temperature T. The pressure of the gas is P. An
identical vessel containing one mole of He gas (molar mass 4) at a temperature 2T has a pressure of
(A) P/8 (B) P (C) 2P (D) 8P
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Q.21 A container X has volume double that of contianer Y and both are connected by a thin tube. Both
contains same ideal gas. The temperature of X is 200K and that of Y is 400K. If mass of gas in X is m
then in Y it will be:
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(A) m/8 (B) m/6 (C) m/4 (D) m/2
Q.22 One mole of an ideal gas at STP is heated in an insulated closed container until the average speed of its
(B) 2
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molecules is doubled. Its pressure would therefore increase by factor.
(A) 1.5 (C) 2 (D) 4
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Q.23 Three particles have speeds of 2u , 10u and 11u. Which of the following statements is correct ?
(A) The r.m.s. speed exceeds the mean speed by about u.
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Q.24 Two monoatomic ideal gas at temperature T1 and T2 are mixed. There is no loss of energy. If the masses
of molecules of the two gases are m1 and m2 and number of their molecules are n1 and n2 respectively.
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Q.25 At temperature T, N molecules of gas A each having mass m and at the same temperature 2N molecules
of gas B each having mass 2m are filled in a container. The mean sqaure velocity of molecules of gas B
is v2 and mean square of x component of velocity of molecules of gas A is w2. The ratio of w2/v2 is :
(A) 1 (B) 2 (C) 1/3 (D) 2/3
Q.26 A given mass of a gas expands from a state A to the state B by three paths 1, 2 T 1 B
and 3 as shown in T-V indicator diagram. If W1, W2 and W3 respectively be
2
the work done by the gas along the three paths, then A 3
(A) W1 > W2 > W3 (B) W1 < W2 < W3 O V
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Q.27 An ideal gas undergoes the process 1 2 as shown in the figure, the heat supplied and work done in the
process is Q and W respectively. The ratio Q : W is
(A) : – 1 (B)
(C) – 1 (D) – 1/
Q.28 A reversible adiabatic path on a P-V diagram for an ideal gas passes through state A where
P = 0.7×105 N/m–2 and v = 0.0049 m3. The ratio of specific heat of the gas is 1.4. The slope of path at
A is :
(A) 2.0 × 107 Nm–5 (B) 1.0 × 107 Nm–5 (C) – 2.0 × 107 Nm–5 (D) –1.0 × 107 Nm–5
Q.29 One mole of an ideal gas is contained with in a cylinder by a frictionless piston and is initially at
temperature T. The pressure of the gas is kept constant while it is heated and its volume doubles. If R is
molar gas constant, the work done by the gas in increasing its volume is
(A) RT ln2 (B) 1/2 RT (C) RT (D) 3/2 RT
Q.30 Three processes form a thermodynamic cycle as shown on P-V diagram for an
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ideal gas. Process 1 2 takes place at constant temperature (300K). Process
2 3 takes place at constant volume. During this process 40J of heat leaves
the system. Process 3 1 is adiabatic and temperature T3 is 275K. Work
done by the gas during the process 3 1 is
D
(A) –40J (B) –20J
(C) +40J (D) +20J
Q.31 N
When unit mass of water boils to become steam at 1000C, it absorbs Q amount of heat. The densities of
water and steam at 1000C are 1 and 2 respectively and the atmospheric pressure is p0. The increase in
internal energy of the water is
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1 1 1 1 1
1
(A) Q (B) Q + p0 (C) Q + p0 (D) Q - p0
2 1 1 2
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1 2
Q.32 A ideal monoatomic gas is carried around the cycle ABCDA as shown
in the fig. The efficiency of the gas cycle is
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4 2
(A) (B)
21 21
ET
4 2
(C) (D)
31 31
Q.33 In thermodynamic process pressure of a fixed mass of gas is changed in such a manner that the gas
releases 30 joule of heat and 18 joule of work was done on the gas. If the initial internal energy of the
gas was 60 joule, then, the final internal energy will be :
(A) 32 joule (B) 48 joule (C) 72 joule (D) 96 joule
Q.34 A cylinder made of perfectly non conducting material closed at both ends is divided into two equal parts
by a heat proof piston. Both parts of the cylinder contain the same masses of a gas at a temperature
t0 = 27° and pressure P0 = 1 atm. Now if the gas in one of the parts is slowly heated to t = 57°C while
the temperature of first part is maintained at t0 the distance moved by the piston from the middle of the
cylinder will be (length of the cylinder = 84 cm)
(A) 3 cm (B) 5 cm (C) 2 cm (D) 1 cm
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Q.35 Two identical vessels A & B contain equal amount of ideal monoatomic
gas. The piston of A is fixed but that of B is free. Same amount of heat is
absorbed by A & B. If B's internal energy increases by 100 J the change
in internal energy of A is
500
(A) 100 J (B) J
3
(C) 250 J (D) none of these
Q.36 An ideal gas undergoes an adiabatic process obeying the relation PV4/3 = constant. If its initial temperature
is 300 K and then its pressure is increased upto four times its initial value, then the final temperature is
(in Kelvin):
(A) 300 2 (B) 300 3 2 (C) 600 (D) 1200
Q.37 A closed container is fully insulated from outside. One half of it is filled with an
ideal gas X separated by a plate P from the other half Y which contains a vacuum
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as shown in figure. When P is removed, X moves into Y. Which of the following
statements is correct?
(A) No work is done by X (B) X decreases in temperature
(C) X increases in internal energy (D) X doubles in pressure
D
Q.38 1 kg of a gas does 20 kJ of work and receives 16 kJ of heat when it is expanded between two states. A
second kind of expansion can be found between the initial and final state which requires a heat input of
(B) 5 kJ
N
9 kJ. The work done by the gas in the second expansion is :
(A) 32 kJ (C) – 4 kJ (D) 13 kJ
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Q.39 One mole of an ideal gas at temperature T1 expends according to the law P = a (constant). The work
done by the gas till temperature of gas becomes T2 is : V2
1 1 1 1
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(A) R(T2 – T1) (B) R(T2 – T1) (C) R(T2 – T1) (D) R(T2 – T1)
2 3 4 5
Q.40 The adiabatic Bulk modulus of a diatomic gas at atmospheric pressure is
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(A) 0 Nm–2 (B) 1 Nm–2 (C) 1.4 ×104 Nm–2 (D) 1.4 105 Nm–2
ONE OR MORE THAN ONE OPTION MAY BE CORRECT
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Q.4 50 gm ice at – 10°C is mixed with 20 gm steam at 100°C. When the mixture finally reaches its steady
state inside a calorimeter of water equivalent 1.5 gm then : [Assume calorimeter was initially at 0°C,
Take latent heat of vaporization of water = 540 cal/gm, Latent heat of fusion of water = 80 cal/gm,
specific heat capacity of water = 1 cal/gm-°C, specific heat capacity of ice = 0.5 cal/gm °C]
(A) Mass of water remaining is : 67.4 gm
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(B) Mass of water remaining is : 67.87 gm
(C) Mass of steam remaining is : 2.6 gm
(D) Mass of steam remaining is : 2.13 gm
D
Q.5 Figure shows the pressure P versus volume V graphs for two different gas sample
at a given temperature. MA and MB are masses of two samples, nA and nB are
numbers of moles. Which of the following must be incorect.
(A) MA > MB
(C) nA > nB
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(B) MA < MB
(D) nA < nB
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Q.6 The total kinetic energy of translatory motion of all the molecules of 5 litres of nitrogen exerting a pressure
P is 3000 J.
(A) the total k.e. of 10 litres of N2 at a pressure of 2P is 3000 J
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temperature, T0. The piston is moved up slowly to increase the volume of the gas to times. Which of
the following is incorrect?
(A) Work done by the gas is RT0 ln .
(B) Work done against the atmosphere is RT0( 1).
(C) There is no change in the internal energy of the gas.
(D) The final pressure of the gas is 1 times its initial pressure.
( 1)
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Q.9 A container holds 1026 molecules/m3, each of mass 3 × 10–27 kg. Assume that 1/6 of the molecules
move with velocity 2000 m/s directly towards one wall of the container while the remaining 5/6 of the
molecules move either away from the wall or in perpendicular direction, and all collisions of the molecules
with the wall are elastic
(A) number of molecules hitting 1 m2 of the wall every second is 3.33 × 1028.
(B) number of molecules hitting 1 m2 of the wall every second is 2 × 1029.
(C) pressure exerted on the wall by molecules is 24 × 105Pa.
(D) pressure exerted on the wall by molecules is 4 × 105Pa.
Q.10 Two gases have the same initial pressure, volume and temperatue. They expand to the same final volume,
one adiabatically and the other isothermally
(A) The final temperature is greater for the isothermal process
(B) The final pressure is greater for the isothermal process
(C) The work done by the gas is greater for the isothermal process
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(D) All the above options are incorrect
Q.11 The first law of thermodynamics can be written as U = Q + W for an ideal gas. Which of the
following statements is correct?
D
(A) U is always zero when no heat enters or leaves the gas
(B) W is the work done by the gas in this written law.
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(C) U is zero when heat is supplied and the temperature stays constant
(D) Q = –W when the temperature increases very slowly.
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Q.12 A cyclic process ABCD is shown in the p-V diagram. Which of the
following curves represents the same process if BC & DA are isothermal
processes
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A B D C B A B
A
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p V
(A) p C (B) V B (C) C (D)
D A D C
D
T T T T
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Q.13 2 moles of a monoatomic gas are expanded to double its initial volume, through a process P/V = constant.
If its initial temperature is 300 K, then which of the following is not true.
(A) T = 900 K (B) Q = 3200 R (C) Q = 3600 R (D) W = 900 R
INTEGER TYPE
Q.1 A wall has two layer A and B each made of different material, both the layers have the same thickness.
The thermal conductivity of the material A is twice that of B. Under thermal equilibrium the temperature
difference across the wall B is 36°C. The temperature difference across the wall A is (° C)
Q.2 The spectral emissive power E for a body at temperature T1 is plotted against
the wavelength and area under the curve is found to be A. At a different
temperature T2 the area is found to be 9A. Then 1/2 =
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Q.3 A black body calorimeter filled with hot water cools from 60°C to 50°C in 4 min and 40°C to 30°C in
8 min. The approximate temperature of surrounding is (° C)
Q.4 A rigid tank contains 35 kg of nitrogen at 6 atm. Sufficient quantity of oxygen is supplied to increase the
pressure to 9 atm, while the temperature remains constant. Amount of oxygen supplied to the tank is :
Q.5 A polyatomic gas with six degrees of freedom does 25J of work when it is expanded at constant pressure.
The heat given to the gas is (in J)
Q.6 A vessel contains an ideal monoatomic gas which expands at constant pressure, when heat Q is given to
it. Then the work done in expansion is xQ, find X ?
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D
N
SI
O
O
ET
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ANSWER KEY
OBJECTIVE QUESTION BANK
ONLY ONE OPTION IS CORRECT.
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ONE OR MORE THAN ONE OPTION MAY BE CORRECT
Q.1 A, C Q.2 A, B Q.3 D Q.4 A, C Q.5 C
Q.6 C, D Q.7 D Q.8 A, D Q.9 A, D
D
Q.10 A, B, C Q.11 C Q.12 A, B Q.13 B
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