Chemistry Complete Notes (Khan Sir)_9658126916
Chemistry Complete Notes (Khan Sir)_9658126916
(Chemistry)
Ex. :–
–
(Composition) (Structure) (Properties)
1.
(Chemical Reaction)
2.
Lavoisier 1. (Crystalline solid)
R. Hoffmann
Ex. :–
2. (Amorphous Solid)
P.C. Roy Ex. :– Glass
Nitrate Man of India (Liquid)–
Ex. :–
(Matter)
(30º 35ºC)
Br.
(Gas)–
(Attraction force)
Ex. :–
(Small particles)
(particles of matter)
(Atom) - Atom S.T.P (Standard Temperature and Pressure)
1 gram 22.4 Litre
Remark:–
(Molecules) -
(Solid)
(Diffusion) -
(Intermolecular force)
Ex. :–
(Metalloids)
Note :–
Ex. :–
Note :– (Po)
(Compound)
(Physical Change)
Ex. :– (H2O)
(Organic Compound)
Ex. :–
Ex. :– CH4, CO2
(Chemical Change) (Inorganic Compound)
Ex. :– H2O, Fe2O3
Ex. :–
(Mixture)
Note:–
+
(Sublimation) -
+
(ii) (Homogeneous Mixture)
Ex. :– +
+
(Vaporisation) -
(Boliling) -
(Atomic Theory)
ATOM
(Nucleous)
(Fundamental Particles of
Atom )
Ex. :–
(Å)
10 10 m(1Å )
(Stable Particles)
(f)
(Unstable Particles)
(Stable Particles) 10 15 m (1 )
1 (105)
1.6749 1027 kg
1.6749 × 10–24 gram
1.0086 amu
–13.6
E= ev
n2 0
n=
Remark :–
ev =
1 ev = 1.6 × 10–19
(Absolute Mass) [Neutrino n ]
0
0
(Positron) (e+)
(Anti-Particle)
19
9.1 1031 kg
–1.6 10
H 1.6 1019
amu (Atomic Mass Unit) Remark:– Anti Particle
Chemistry By. Khan Sir KGS 5
(Isobar)
(Meson)
Ex. :– 14 14
6C 7N
18 Ar40 20Ca
40
(Isotopes)
(a)
(b)
(c)
(Boson) Ex. :– 1 2 3
1H 1 H 1 H
Polonium (Po) 27
Note :– Higgs Boson = God Particle
Atomic Number
(i) –14 (C – 14)
'Z'
(ii) U – 235
(iii) I – 131
(Z) (P) –
(e )
(iv) Fe – 59
(Ions)
(v) As – 74
(vi) Co – 60
(vii) Na – 23
(Isoelectronic)
Na – 24
Note :–
Quantum Number
1. Principal Quantum Number)
2. (Azimuthal Quantum Number)
(Offbau's Law) 3. (Magnetic Quantum Number)
4. (Spin Quantum Number)
1. Principal Quantum Number)
(Electronic Configura-
tion)
Na 1s 2 2s 2 2p 6 3s1
11
(Valency)
10th Electron 9th Electron
n=2 n=2
l 1 l 1 Valence Electron
m 1, 0, 1 m 1, 0, 1
–1 –1 Case I– 1, 2, 3, 4
s s
2 2 =
(Huygen's Ex. :– 13Al 2, 8, 3 = 3)
Uncertainty Principle) Mg 2, 8, 2 = 2)
12
Na 2, 8, 1 = 1)
11
Case II– 5, 6, 7, 8
(De-Broglie's Principle)
=8–
Ex. :– 8O 2, 6 = 8 – 6 = 2)
10
Ne 2, 8 = 8 – 8 = 0)
h h 17
Cl 2, 8, 7 = 8 – 7 = 1)
p mv
h
Chemistry By. Khan Sir KGS 8
(Radioactivity) -
8
O 2, 6
8
O–2 2, 8
11
Na 2, 8, 1
11
Na+ 2, 8
(Ions)
(i) (Cation)
(Octane Rule) (ii) (Anion)
17
Cl 2, 8, 7
17
Cl– 2, 8, 8
11
Na 2, 8, 1
11
Na+ 2, 8
Bond
(i) (Ionic or Electrova-
Bond
lent Bond)
(ii) (Co-Valent Bond)
Co-Valent bond
(iii) (Co-ordinate Bond)
(i) Single Bond
(Electrovalent/ (ii) Double bond
Ionic Bond) (iii) Triple Bond
Bond electrons
(i) (Single Covalent
Bond)
e– Eg. H2, Cl2, H2O, CH4
Na Cl Na+ + Cl– NaCl
Cl Cl ×× ××
2, 8, 1 2, 8, 7 × Cl × × Cl ×
2, 8, 7 2, 8, 7 × × Cl – Cl Cl 2
Ca O Ca+2 + O–2 CaO ×× ××
2, 8, 8, 2 2, 6 (ii) (Double Covalent Bond)
Mg O Mg+2 + O–2 MgO e–
2, 8, 2 2, 6
(Ionization Potential)
Electron
×N × × × ×N N×
× × × N
× × × × × N2
(F)
1 2
Ionic (Atomic Orbital) S P (Atomic Orbital)
Na O H
Covalent SP
2
Bond
Hybrid Orbital (H.O)
Triple bond
Single bond sp, sp2, sp3
Bond Energy
Bond Bond Energy 2 (S, P) º
3 (S, P, P) º
Single Bond Bond Energy Triple Bond 4 (S, P, P, P)
Bond Energy
(Co-ordinate Covalent Bond)
Electron Vailence Electron
Hybridisation = SP3
N2 O Hybridisation = SP2
Electronegativity Trick :
F O N Cl – Br – I – C H
(Element)
6.
Zn + H2SO4 ZnSO4 + H2
(Ca)
(Li)
(Periodic (OS)
Table) (Ti)
(Pt)
(Non-Metal)
(Metal)
1.
Note :–
(Metalloid)
2.
3.
(Quick Silver) Ex. :–
4.
5. Ex. :– ,
Tellurium (Te), Antimony (Sb)
Chemistry By. Khan Sir KGS 13
Note:– Ex. :–
2. (Saturated Solution)
(Inorganic Compound)
(Mixture)
Ex. :– etc.
(Heterogeneous Mixture)
Ex. :–
(Suspension)
Note :–
10–5 cm
(Filter Paper)
Ex. :–
(Solution)
(Colloid) 10–7 m
10–9 m 10–7 m
Microscope Microscope
Ex. :–
(Molality) :-
Ex. :– Blood,
Note:–
Mole
kg
(Dialysis)
(Normality)
Remark:–
1000
(Emulsion)
Ex. :–
(Acid)
H+
pH (Power of Hydrogen) 7
Ex :– Hcl, H2SO4, HNO3
Zn + H2SO4 ZnSO4 + H2
(Lichen)
(i)
H+
Ex :– Hcl, H2SO4, HNO3, H2O3, HCN, HF.
(ii)
(iii) Lewis
Note :–
Note :– H+
H+ H3O+
–
(i) HClO4 > HClO3 > HClO2 > HClO
(ii) HI > HBr > HCl > HF
(ii) HCOOH > CH 3 COOH > C 2 H 5 COOH >
C 3H 7COOH
OH–
(Properties of Acids)
+ + (Use of Bases)
(NaOH)
+
+ +
[Ca(OH)2]
+ +
(Base) (Bleaching
Powder)
pH 7
(Antacid)
(CaO)
=
=
(MgO)
(KOH)
(Electrolyte)
(Properties of bases)
(Salt)
2NaOH + Al NaAlO2 + H2
Note :-
Ex :– NaCl
(OH-)
(General Salt)
H+ OH–
NaOH ( s ) Na ( aq ) OH ( aq )
Note :–
Ex. :- NaCl, NO2CO3, CuSO4, K2SO4, Al2(SO4)3,
Na2SO4, MgCl2
(Double Salt)
Hydrogen Peroxide (H2O2) CuSO4
FeSO4.(NH4)2.SO4.6H2O
120ºC
(Acidic Salt)
Chemistry By. Khan Sir KGS 18
H+
1
pH 5
Ex. :– NaHCO3, NaHSO4, KHSO4, NH4Cl, 2
(Alkaline Salt)
SO2 NO2
OH–
Ex. :– Ca(OH)Cl, Na2CO3, CuCO3, Cu(OH)2 pH–
(Complex Salt)
[]
Ex. :– Ag[Na(CN)2]
+
+
+
pH
pH
pH
pH
7 pH
7 pH
Ex. :–
pH 7
7 pH
Note :–
(Hypo)
(Average Life)
(Disintegration Constant )
“Irene curie” F. Joliet
- (-Rays)
1
T 1.44 t 1
2
(Artificial Radioactivity)
Radio Activity
Frederic Joliot
- (-Rays)
Radio Activity
Radio Active
(G. M. Counter)
Radio Active
- (-Rays)
Radio Active
Radio Active
(82Pb206)
Note :–
(i) =>> Note :–
(ii) = > > (i)
(iii) =>>
(ii)
(Half-life period)
(iii) (Penetrating Power)
(iv)
t1
2
(Nuclear Chemistry)
0.693
t1 ,
2
(Nuclear Reaction)
(Controller Rods)
(Nuclear Fis-
sion Reaction) (Moderator)
(Atom Bomb) (Coolant)
18 May 1974
Remark :– (Zr),
(Neutron Bomb)
(Catalyst)
(Atomic Reactor)
(Catalyst Promoters)
Ex. :– Molybdenum (MO)
(BARC-Bhabha Atomic
(Activation Energy)
Research Centre) 1956
(Nuclear Power Station)
(USA)
(Chemical Reactions) c.
(Displacement Reaction)
(Physical Change)
Zn H 2SO 4
ZnSO 4 H 2
K > Na > Ca > Mg > Al > Zn
Ex. :– > Fe > Pb > H > Cu > Hg > Ag > Au
etc. (Double Displacement
(Chemical Change)
Reaction)
(Ab + Cd Ad + Cb)
Ex. :–
(Reversible Reaction)
1. (Exothermic Reaction)
Ex. :–
(System)
Ex. :–
a. CH 4 2O2 CO2 2H 2O Heat
b. (Irreversible Reaction)
c. CO2
d.
e.
(Gaseous Law)
2. (Endothermic Reaction)
(System) (Gaseous)
Ex. :–
a. N2 O2
2NO (Intermolecular Force)
b.
Chemistry By. Khan Sir KGS 23
(Ideal Gas)
P1V1 P2 V2
T1 T2
(Avogadro's Law)
Remark :– CO2,
H2 N2
(Real Gas) Vn
V = n × Constant
V
Constant
n
a (Pressure) ‘P’
b (Temperature) ‘T’ V1 V2
c (Volume) ‘V’ n1 n2
(Charle's Law) (Equation of Ideal Gas)
PV nRT
P= (Pressure)
V= (Volume)
TV R= (Gas constant)
R = 8.314 Joule/Mole-kelvin
(Absolute Zero)
n= (No. of Moles)
Note :–
Note :–
1 2 3 4 5 6 7
H Li Be B C N O
F Na Mg Al Si P S
(Dobereiner) Cl K Ca Sc Ti V Cr
(Triads)
(Defects of
Newlands Rule of Octves)–
1.
Ex. :–
(i) Li7, 11Na23, K39
3 19 2.
7 39 46
= 23 Na
2 2
table
PT (Vertical)
(Horizontal)
(Periods)
(Limtations of
Mendeleef's Periodic Table)
p block
s block
d - block
Note :– f- block
s- block
A B "O– group"
s
block
Li
IA VIIA Na
Ba
(Sr)
(Mosley's Periodic Table) Ca
K, Rb & Cs
1913 p- block
d- block
IA (Alkali Metal) Li, Na, K, Rb,
(i) Cs, Fr
(ii) IIA (Alkaline Earth Metal)
Be, Mg, Ca, Sr, Ba, Ra
IB (Coinage Metal) Cu, Ag, Au
IIB Volatile Metal (Zn, Ca, Hg)
VA Pnicogens (Pnicos = Poison, Gen = to
Produce) N, P, As, Sb, Bi
VIA Chalcogene (Chalcos = ore, Gen = to
(Characteristics of Periods) Produce) O, S, Se, Te, Po
VIIA Halogen (F, Cl, Br, I)
VIIIA Zero Group
Cl = (17 – 10) + 10 = 17
(Valence
Electron & Valency)
Electronegalivity
Electronegalivity
Note :– Electronegalivity
Electronegalivity
Electronegalivity
(Ionisalion Petenlial) I.P.
He
Ionisalion Enthalphy
Electron Volt
Mole (kg-J/Mol)
He
I.P.
(Size of Atom)
I.P.
Note :– I.P.
65% 95% (i) (P bermanent Hardness)
97%
(ii) (Temporary Hardness)
(i) (Permanent Hardness)
Angle 104.5º
(Ca) (Mg)
4ºC (277 K)
100ºC (373 K) 0ºC (273 (Na2Al2Si2O8)
K)
Na(Na4P6O18
(ii) (Temporary Hardness)
1. (Distilled Water) (Ca)
(Soft Water) (Mg)
(Hard Water)
(Heavy Water) Ca(OH)2
(D2O)
250 PPM
101.4ºC
(Soft Water)
[H2O + (Na +
(i) (Sedimentation Method)
Ca + Mg)]
(0-60 mg/l)
(Hard Water) (ii) (Filteration Method)
Remark :– UV
(Mineral) (Calcination)
Melting Point
Carbonate
(Ores)
(Ore's Concentration)
(MATRIX / GANGUE)
Gangue
(Flux)
Flux
Note :–
(Slag)
(Magnetic Method)
(A)
(Froth/Foam Floatation Method) (1) (Al2O3.2H2O)
(2) (Al2O3.H2O)
(3) (Al2O3)
(4) (Na3AlF6)
(5) ( Al2O3)
(Roasting) (B)
(1) (Cu FeS2)
ZnS, PbS, HgS Melting (2) (Cu2S)
Point (3) (Cu2O)
(4) CuCO3 . Cu(OH)2
(2) (AgBr)–
(3) (AgI)–
(4) (AgNo3)–
(I)
(1) (ZnS)
0.5 – 1.5%
High
Carbon Steel
(Isomerism) (Alkene)
Double Bond Alkane
(Hydrocarbon) Olefins
= CnH2n
n = 2, 3, 4.......
C2H4
(Alkane) C3H6
C4H8
Single Bond
(Alkyne)
(General Formula) CnH2n+2
Tripal Bond
CH2
= CnH2n–2
n = 2, 3, 4.......
n=2 C2H2
(Methane) CH4
Note :– (CaC2)
(Tetrahedral)
Bond Angle 109º.28'
Note :– (CH3COONa) CaC2 2H 2 O
Ca(OH) 2 C 2 H 2
(NaOH)
(Functional Group)
CH 3COONa NaOH
CH 4 Na 2 CO3
(a) –OH
(Natural Gas), CNG = CnH2n+1OH or R – OH
(Compressed Natural Gas) n = 1, 2, 3, 4.......
CH3OH
(Marsh)
C2H5OH
Marsh
Chemistry By. Khan Sir KGS 35
(b) (F, Cl, Br, I) Carboxylic Acid HCOOH
C2H5I Carboxylic Acid CH3COOH
CH3 Br Carboxylic Acid C2H5COOH
(c) – CHO Note :– Carboxylic Acid
= CnH2n+1CHO
n = 1, 2, 3, 4.......
C2H5CHO (Ether) —O—
HCHO CH2 — O — CH3
C3H7CHO C2H5 — O — C2H5
Carboxylic Acid COOH (Keton) — CO —
= CnH2n+1COOH or R – COOH
CH3 — CO — CH3
n = 1, 1, 2, 3, 4.......
C2H5 — CO — CH3
(Fuel)
(Coaltar)
C.N.G.,
Note :– H2
(Coke)
150 kilojoule/g) 95%
(CO)
Heamoglobin
(Coal)
NO2 Brown
SO2 , CO
(Gasoline/Petrol)
(Calorific Value)
KJ/g
(Diesel)
C7H16 (Heptane) C17H36 (Heptadecane)
Sulphur
(CNG)
CNG 200-250 HTPB (hydroxyl-Terminated Polybutadiene)
C-10
C-10
CNG (Octane Number)
CNG (CH4)
CNG (Knocking)
(Green Diesel/Bio-Diesel)
(Renewable)
(Knocking)
Knocking
Chemistry By. Khan Sir KGS 38
(TET)
(Dynamite)
(Mycel)
Sodium
nitrate
RDX (Research Department Explosive)
USA T-4
(Ca+2 & Mg+2)
(Detergents)
IED (Improvised Explosive Device)
(Gun Powder)
(–SO3H)
(C12H25OH),
H2SO4 NaOH
Ca+2 Mg+2
(CaOCl2) –
(Cement) Note :–
+ + = (Mortar)
+ + + + =
(Concrete)
(Medicines)
(Components of Cement)
(Classifications of Medicines)
(Antibiotics)–
(Insecticide)
Amoxicillin, Azithromycin,
Clindamycin, Sulfonamides.
(Analgesics)–
C6H5 + OH = Phenol
(SiO2), (NaSiO3)
(CaSiO3)
1400ºC
(Polymer Or Polymerisation)
(ii)
(Synthetic Fibre)
Ex. :– Bakellite, Glyptal, Veetal,
(Polyster)
Note :–
(Condensation) (Food Preservatives)
(Polyamide)
(Chlorofluoro Carbon or Freon)
(Nylon) (C)
(F) (Cl)
(Bristle)
(Solvent) (Propellants)
Chemistry By. Khan Sir KGS 43
(CCI4)
CFC (Green House Gas)
(O3)
(Protocol) CFC
(Non-
(Mustard Gas) Inflammable)
(Fire Extinguisher)
(Mustard)
(CH3NCO)
(Carcinogenic)
(Tear Gas)
(Non-toxic)
(CH3OH)
OH
(CHCl3)
(Unconsciouness)
(Wood Spirit) (Wood Naphtha)
(C2H5OH) (CaOCl2)
(CCl4)
(Fe) (H2O)
(C2H5OH)
(Surgery)
(Alcohol)’
(Solvent)
(Fermentation)
(Wine)
(Wood Spirit or Wood
Naptha)
(CH3OH)
(Lactobacillus)
(C2H5 – O – C2H5)
(Tartaric Acid)
(Surgery)
(Citric Acid)
(HCOOH)
(Oxalic Acid)
(Bleaching Agent)
(CH3COOH)
(Vinegar)
(Kidney)
9–10%
(NH2CONH2)
(Glacial)
(KCNO)
(Milk Acid) (NH4)2SO4
Chemistry By. Khan Sir KGS 45