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241-Assignment-Group CC01-04

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0% found this document useful (0 votes)
37 views

241-Assignment-Group CC01-04

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GROUP ASSIGNMENT PROJECT

Course: Physical Chemistry 1 (CH2003) – 241


Group No: 241- CC01 -04

Submision: 02 files (File name: Group No.)


1. Calculation file (01 excel file)
2. Report file (pdf file)
Report requirements:
- File type: pdf
- No. of pages of report (all) <= 10
- Font: Arial , 12 ; Alignment: Justify; Line spacing: 1.5 line
- Must be consisted of:
o Cover (including member info.)
o Content of Questions
o Solutions
o Comments about the assignment and the course
o Evidences of team-work activity (Plan, meeting pictures)
- Deadline of Submission: Sunday (08/12/2024) via BKel. Report
submitted after 23:59 of 08/12/2024 will not be accepted.

IMPORTANT Note:

1. In case two reports are detected with "signs" of copying


(similar content >50%), both groups will receive a score of 0
(zero).
Question 1:
In the manufacture of sulfuric acid, one step is the oxidation of sulfur dioxide to
sulfur trioxide. Consider performing this oxidation at a pressure of P atm with
molar ratio SO2:O2 = x:y, using air as the oxygen source (assuming air contains
21%O2 and 79% N2 only). The reactor temperature is maintained at a constant
temperature of
T°C.

P (atm) molar ratio SO2:O2 = x:y T (°C)

1.5 2:1 690

(a) What is the equilibrium constant (KP) at the operating conditions?


(b) If equilibrium is attained within the reactor, what is the exit stream
composition?
(c) To produce 10 tons of sulfur trioxide, calculate the heat must be supplied to or
removed from the reactor to maintain isothermal operation at T0C.
(d) Plot the KP ; KC ; Kx as a function of operation pressure
(P= 1 – 20 atm) (at ToC) and comment about the chart.
(e) Plot the equilibrium conversion of SO 2 (the extent of reaction) as a function of
operation temperature (300 – 750 oC) (at pressure P) and comment about the
chart.
Question 2:

A rigid tank of volume V is connected to a piston-cylinder assembly by a valve,


as shown below. Both vessels contain pure water. They are immersed in a
constant-temperature bath at TB= 220ºC and P= 600 kPa. Consider the tank and
the piston–cylinder assembly as the system and the constant temperature bath
as the surroundings. Initially, the valve is closed and both units are in equilibrium
with the surroundings (the bath). The rigid tank contains saturated water with a
quality of 90% (i.e., 90% of the mass of water is vapor). The piston-cylinder
assembly initially has a volume of Vinitial.
The valve is then opened. The water flows into the piston–cylinder until equilibrium is
obtained. For this process, determine the work done, W, by the piston; the change in
internal energy, U, of the system; and the heat transferred, Q.

V (m3) Vinitial (m3)


1.50 0.20
Question 3: A vapor–liquid phase diagram for a binary mixture of
species 1 and 2 at 293 K is shown in the following figure.

a b

a 0.50 0.70

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