Q= m cp ΔT

Steam Heater
184,021 18,188 0.50590 20
Cp agua = 1 Kal/ kg
Cp Vapor 2 barg =
Cp óleo (100 °C) = 0.5059 kcal/kg°C
Vazão = 18,188 kg/h
^H entalpi vapor saturado 3barg 654.134 kcal/kg
^H entalpi vapor saturado 3barg 664.288 kcal/kg
DeSmet
Direct steam 3 barg = 6 kg/ton
Steam Vaccum 9 barg = 25 kg/ton
Destillate Cooling water (Δ 8°C) = 0,2 m³/ton
Final Oil Cooling water (Δ 8°C) = 4 m³/ton
Air pressured 5 Nm³/h
Power 145 kw
Gaz 2.7 kg/ton
0,1kg % FFA removido
Nitrogen 0.1 Nm³/ton
Deodorizer Comparative

Parameter - Temperature Unit Alfa Laval DeSmet

Steam Heater kg/h

Temp. in - bleached oil °C 85 85 281.32
Temp. out - bleached oil °C 105 105

Final Heater
Temp. in - bleached oil °C 210 213
Temp. out - bleached oil °C 245 245

First Economizer
Temp. in - bleached oil °C 105 105
Temp. out - bleached oil °C 210 213
Temp. in - deodorized oil °C 242 243
Temp. out - deodorized oil °C 130 146

Second Economizer
Temp. in - neutralized oil °C 85 85
Temp. out - neutralized oil °C 105 115
Temp. in - deodorized oil °C 130 146
Temp. out - deodorized oil °C 105 115

Third Economizer
Temp. in - crude oil °C 70 70
Temp. out - crude oil °C 85 85
Temp. in - deodorized oil °C 105 115
Temp. out - deodorized oil °C 95 100

Cooling Water
Temp. in - deodorized oil °C 95 100
Temp. out - deodorized oil °C 38 41
Temp. in - water °C 28 28
Temp. out - water °C 35 35

Destillate Cooling Water

Temp. in - destillate °C
Temp. out - destillate °C 50 50
Temp. out - water °C 35 35
### °C

E726

Steam 2
BARG
### °C

High Pressure
55 BARG

GT708 Agua
Acido
Cirico

T725

Alfa Laval 210 °C

PROCESS

VHE706

Steam 2 105 °C
BARG
Neutral Oil
RB Oil Tank

Bleacher

85 °C
P701 E702
D702 P705

Condensates
Vaccum

SCR716
VHE707

FFA
T720B Surge
245 °C Tank

SP709
P771B E718C

242 °C

70 °C
Crude
Oil

105 °C Neutralizatio
n
85 °C
VHE706

130 °C
85 °C 38 °C
Neutral Oil
95 °C
Bleacher

105 °C

105 °C 28

E713 F714/5
P712A
35
Steam 2
BARG

Condensate
50 °C
FFA

Torre
28 °C
Torre

H2

Reprocess

Neutral Tank

Deodorized Tank
°C
Torre

Torre
°C
857E

821A

245 °C

High Pressure
55 BARG

890H Agua
Acido
Cirico
213 °C
834CA

DeSmet
PROCESS
P834CA

146 °C
682B 85 °C
Bleacher

Neutral
Steam 2 105 °C Oil
BARG 880C
115 °C
RB Oil Tank

802
115 °C

85 °C
P802

Condensates
822QE 841A

849

857G

823A

822P Steam 2
BARG
FFA
Surge
Tank
50 °C
243 °C 823L FFA
28 °C
Torre
880A1
P814G 881AG
Torre

70 °C
822B
Crude
Oil

880A2 Neutralizatio
n
881A 85 °C

100 °C
41 °C

115 °C

804NI

881B 816B1/B2

P822
zatio

H2

Reprocess

Neutral Tank

Deodorized Tank
804NI 28 °C
Torre

Torre
35 °C
CURRENT PROCESS FLOW DIAGRAM - Deodorizing

Vacuum
SCRUBBER System

DEODORIZER KRUPP
(1994)

1st TRAY High Pressure

Steam

2nd TRAY

3rd TRAY

4th TRAY
Stripping
Steam
5th TRAY
FFA
Surge
6th TRAY Tank
FFA
Storage
7th TRAY Tank
Flowmeter
8th TRAY

LT

DEAERATOR Water

c
HEATER

cooling
water tower

Condensate
Flowmeter
COOLER

RBD Tanks- Magnetic pump

Tks 1,2 3
Tank Capacity
65 Tons To cooling
water tower
PROPOSED PROCESS FLOW DIAGRAM - Deodorizing (DeSmet) Vaccum System
Clay Eficiency
168.54 ppb/kg
High
Delta Specification Pressure
50 ppb Steam
Saving Analyzer CRUDE Oil Tank
TKs-1/2/3
0.30 kg/ton

SCRUBBER

1st TRAY

2nd TRAY
SOFT COLUMN

3rd TRAY

4th TRAY
Stripping Steam

STRIPPER

To bleacher
ECONOMIZER FFA
Surge
30 oC Tank
FFA
ECONOMIZER Storage
Tank
from OR Oil Tank Water Flow:
70 m3/h
Water Temp:

Flowmeter
35 oC

Steam DEAERATOR Deodorization Loss LT

c
OR Oil Tank
TQ -301
80 ton HEATER

Water from
cooling
tower
Condensate
FLowmeter

RBD Tanks-
Tks 1,2 3 Magnetic pump
Tank Capacity COOLER 0 kg/h
65 Tons Water to
Nitrogen cooling
tower
CITRIC ACID PUMP

Vacuum System
NEW

P
I
PHOSPHORIC ACID TANK
TQ-130
1,2
ton CAUSTIC REACTORS
EXISTENT 8 min Retention
Time
Volume: 2 m3 DRYER
PT
TQ-112
PHOSPHORIC PI 5,2 ton
ACID TANK FT
OR Oil Tank
TQ - 102 SILICA TQ -201
23 ton CITRIC ACID
Steam CENTRIFUGE
WESTFALIA SEPARATOR PI

HEATER FT
Flowmeter
EXISTENT NEW
Dynamic NEW TQ-110
Mixer SILICA TANK
TQ-110 21 m3
NEW PI
CRUDE OIL EXISTENT
TQ - 02
950 ton
FT
Condensate EXISTENT

Desodorized Oil Flow EXISTENT

Flowmeter

13,750 kg/h
EXISTENT

PI EXISTENT
CRUDE OIL
TQ - 03
750 ton
DILUTED FT NEW
CAUSTIC
TQ - 105 PI
22 ton
EXISTENT

Soapstock
CRUDE OIL Production (dry base)
TQ - 04 DILUTED
750 ton CAUSTIC
TQ - 106 EXISTENT
22 ton
CITRIC ACID PUMP

New equipment
PROPOSED PROCESS FLOW DIAGRAM - Neutralizing
ACID REACTOR Vacuum System
@ 8min Retention Time CAUSTIC REACTOR

P
I
PHOSPHORIC ACID TANK Volume: 2,5 m3 @ 20 min Retention Time
TQ-130 Volume: 7 m3

1,2 CITRIC
ACID
ton
Pre-Bleaching
FT
Static Mixer DRYER

Flowmeter
PT (Theoretical) TQ-112
SILICA
5,2 ton

Flowmeter
Deodorized Oil 0.00 kg/ton 0.06 kg/ton Flowmeter
PHOSPHO PI
RIC ACID Excess Citric Acid Excess
OR Oil Tank
TANK #DIV/0! -100 % TQ -201
TQ - 102
23 ton
CENTRIFUGE PI
Dynamic
Mixer
PI

HEATER 180oC TQ-110

Flowmeter
SILICA TANK 21 m3
90°C
TQ-110
CAVITATION PUMP PI
CRUDE OIL CM1000
TQ - 02 100 HP
950 ton NEW PUMP
FT
TO FINAL COOLER
Condensate
Desodorized Oil Flow
18,750 kg/h
Flowmeter

CRUDE OIL
PI
Pre-Bleaching
TQ - 03
750 ton
DILUTED
FT
CAUSTIC
TQ - 105
22 ton PI

Soapstock
Production (dry base)
CRUDE OIL
TQ - 04 DILUTED
750 ton CAUSTIC
TQ - 106
22 ton
CURRENT PROCESS FLOW DIAGRAM - Bleaching

Vacuum System NEW

Filtration / Pre-
Filtration

Vertical
Filters
50 m2

OR Oil Tank Bleaching Loss

TQ -201
90 ton Pre-Filtration Line #REF!

BLEACHER
Vertical
Filters
50 m2

Volume:
20 m3
Vacuum: Filtration / Pre-
200 mbar Filtration

LT
Vertical
Neutral Oil Flow Filters
Steam 50 m2

Steam Heater
Flowmeter
Filtration Line HEATER Condensate

OR Oil Tank
TQ -301
80 ton
PROPOSED PROCESS FLOW DIAGRAM - Bleaching

Clay Eficiency
168.54 ppb/kg
Vaccum System Delta Specification
50 ppb
Saving Analyzer Filtration / Pre-
0.30 kg/ton Filtration
Pre-Bleaching
Neutra
Silica Tank Vertical
Chlorophyll Online Analyzer Filters
50 m2

Filtration / Pre-
Filtration
BLEACHER

Vertical
Filters
50 m2

OR Oil Tank
TQ -201
90 ton

Vertical
Steam Filters Filtration / Pre-
50 m2 Filtration
Deodorizer

c
HEATER

Filtration Line Flowmeter Condensate Water Flow:

Vertical
Filtration ###

c
Filters ECONOMIZER
50 m2 / Pre- Water Temp:
Filtration
Crude Oil heat exchanger

Deodorization Loss

OR Oil Tank
TQ -301
80 ton
PROPOSED PROCESS FLOW DIAGRAM - Deodorizing (Alfa Laval) Vaccum System

VHE FINAL OIL HEATER

Clay Eficiency 200 oC
168.54 ppb/kg SCRUBBER
Delta Specification High Pressure
50 ppb Steam
26
Saving Analyzer FFA
CRUDE Oil Tank
TKs-1/2/3
0.30 kg/ton Surge
Tank
SOFT FFA
COLUMN Storage
Tank

50 oC
TO NEUTRALIZATION
DEODORIZER
ALFA
85 oC
1st TRAY

2nd TRAY
200 oC

3rd TRAY 28
Vacuum Deo 115 oC
4th TRAY 80 oC TT
Stripping Steam Vacuum Deo
5th TRAY

6th TRAY 0 oC
VHE - BLEACHED x DEO VHE - NEUTRAL X DEO

7th TRAY

8th TRAY 30 oC
25 23
Water Flow: 145 oC
70 m3/h
Water Temp:

Flowmeter
35 oC 24
Magnetic pump Magnetic pump
115 oC
Steam DEAERATOR Deodorization Loss LT
0.2819 % 27 85 oC

c
OR Oil Tank
TQ -301
80 ton HEATER
115 oC
Deodorized Oil Flow
#REF!
Water from
33 oC cooling
tower
Condensate
FLowmeter

RBD Tanks-
Tks 1,2 3
35 oC Magnetic pump
Tank Capacity COOLER #REF!
65 Tons
Water to #REF!
cooling
tower
FINAL OIL HEATER

PROPOSED PROCESS FLOW DIAGRAM - Deodorizing (Crown) Vaccum System

High Pressure
Steam

Clay Eficiency Steam

168.54 ppb/kg SCRUBBER
Delta Specification
50 ppb 26
Saving Analyzer FFA
0.30 kg/ton Surge
Tank
SOFT FFA
COLUMN Storage
Tank

DEODORIZER
CROWN

Stripping Steam 1st TRAY

2nd TRAY

Vacuum Deo
TT

LT

Steam

Steam
30 oC 25 BLEACHED x DEO

Water Flow: 145 oC

70 m3/h
Water Temp:
35 oC
Magnetic pump
115 oC
DEAERATOR Deodorization Loss
27

Flowmeter
0.2819 %
OR Oil Tank
TQ -301
80 ton
115 oC

Deaerating Water from

Economizer
33 oC cooling FLowmeter 35 oC
tower

RBD Tanks-
Tks 1,2 3
Tank Capacity
COOLER 65 Tons 0 kg/h
Water to #DIV/0!
cooling
tower
Vacuum Deo

VHE FINAL OIL HEATER

High Pressure Vacuum Deo Vacuum Deo
Steam

Vacuum Bleaching

245°C
Vacuum Bleaching

Hermetic NEW SOFT COLLUM DEODORIZER

Filters

OIL DRYER Stripping 245°C

C Steam

Crude Oil
200°C TAQ31/32

c
Neutral oil Vacuum Deo
240°C

c
Max.
Min.
110°C

C
100°C VHE ECONOMIZER

Vacuum Deo

115°C 45°C 30°C

145°C
C

85°C RBD Tanks

TAQ51/52
115°C 75°C COOLING WATER
90°C

NEUTRALIZATION