JR - Inter - Very Very Important Questions PDF
JR - Inter - Very Very Important Questions PDF
5 23 5 21
2. If cosh x , show that cosh(2x) and sinh(2x) .
2 2 2
3
3. If cosh x find sinh 2x,cosh 2x .
2
SECTION - B
II. Short Answer Questions
01. Show that the four points 4 i 5j k, j k,3 i 9j 4k, 4 i 4j 4k are coplanar..
04. (i) Show that the line joining the pair of points 6a 4b 4c, 4c and the line joining the pair of
points a 2b 3c, a 2b 5c intersect at the point 4c when a, b, c are non-coplanar vectors.
Let a and b be vectors , satisfying a = b = 5 and a, b 45 .Find the area of the triangle
0
07.
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Jr.Inter_I.P.E_Very Very Important Questions
cos sin
12. If A then show that A.AT = AT A = I .
sin cos
1 2 2
13. If
3A 2 1 2 then show that A-1 = AT .
2 2 1
1 2 2
14. If A 2 1 2 then show that A2 – 4A – 5I = 0.
2 2 1
3 3 4
15. If
A 2 3 4 then show that A–1 = A3.
0 1 1
7 2 2 1
1 2 and B 4 2 then find
16. If A= AB ' and BA' .
5 3 1 0
17. If 450 , then prove that (i) (1 tan )(1 tan ) 2 and hence deduce that
0
1
ta n 2 2 2 1.
2
sin16
18. Prove that cos .cos 2 .cos 4 .cos 8 and hence deduce that
16 sin
4 8 16 1
co s . co s . co s . co s .
15 15 15 15 16
19. Solve 2 cos 2 3 sin 1 0
20. (i) Solve 7 sin 2 3 cos 2 4.
(ii) Solve the equation 2cos 2 11sin 7 and write general solution.
21. Solve 1 sin 2 3 sin cos .
22. Solve (i) 3 cos sin 2 (ii) 3 sin cos 2.
23. If 1 , 2 are solutions of the equation cos 2 sin 2 , tan 1 tan 2 and 0,
then find the value ofi) tan 1 tan 2 ii) tan 1 .tan 2 (iii) tan 1 2 .
A B C S2
24. In a ABC , prove that cot cot cot
2 2 2
Using the principle of Mathematical induction, prove that the following. for all n N . (01-10 Q's)
n
01. Show that a a d a 2d ..............n terms 2a n 1 d
2
( 1)2 ( 2)
02. Show that 1 (1 2 ) (1 2 3 ) .... upto n terms
2 2 2 2 2 2
,
12
( 2
6 11)
03. Show that 2.3 3.4 4.5 .... upto n terms ,
3
( 1)( 2)( 3)
04. Show that 1.2.3 + 2.3.4 + 3.4.5 + .....upto n terms , .
4
2
a rn 1
05. Show that a ar ar ....n terms , if r 1 , .
r 1
1 1 1 1
.......
(2 1)(2 1) 2 1
06. Show that ,
1.3 3.5 5.7
1 1 1
07. Show that , .... upto n terms
3 1
,
1.4 4.7 7.10
13 13 23 13 23 33 2
..... upto n terms 2
9 13 ,
24
08. Show that
1 1 3 1 3 5
09. Show that 49 16 1 is divisible by 64 for all positive integers n.
10. Show that 3.52 1
23 1
is divisible by 17, .
abcd .
19. If a 2i 3 j 4k , b i j k and c i j k , then compute a (b c) and verify that it
is perpendicular to a .
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Jr.Inter_I.P.E_Very Very Important Questions
1 Adj A
20. A is a non- singular matrix then prove that A .
det A
a b c
21. Show that
a2 b2 c2 abc(a b)(b c)(c a) .
a3 b3 c3
b c c a a b a b c
22. Show that
c a a b b c 2b c a .
a b b c c a c a b
a b c 2a 2a
23. Show that
2b b c a 2b (a b c)3 .
2c 2c c a b
a b 2c a b
24. Show that
c b c 2a b 2(a b c)3 .
c a c a 2b
1 a2 a3 a a2 bc
1 b2 b3 b b2 ca (a b)(b c)(c a)(ab bc ca)
25. Show that .
2 3 2
1 c c c c ab
2
a b c 2bc a 2 c2 b2
26. Show that b c a c2 2ac b2 a2 (a 3 b3 c3 3abc)2
c a b b2 a2 2ab c2
27. (i) Solve the following simulataneous linear equations by using Cramer’s rule & Matrix
inverse method 3x + 4y + 5z = 18 ; 2x – y + 8z = 13 ; 5x – 2y + 7z = 20.
(ii) Solve the following simulataneous linear equations by using Cramer’s rule & Matrix
inverse method x - y + 3z = 5 ; 4x + 2y - z = 0 ; -x + 3y + z = 5.
28. In , prove that 1 2 3 4
29. In , prove that r + r3 + r1 - r2 = 4RcosB.
65 21
30. If a = 13, b = 14, c = 15 show that R ,r 4, r1 , r3 14 .
8 2
31. If r = 1, r1 = 2, r2 = 3, r3 = 6 show that a= 3,b = 4, c = 5.
32. If r1 8, r2 12, r3 24 find a,b,c.
33. Find the shortest distance between the skew lines r 6iˆ 2ˆj 2kˆ t ˆi 2ˆj 2kˆ and
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Jr.Inter_I.P.E_Very Very Important Questions
MATHEMATICS-IB
SECTION - B
II. Short Answer Questions
01. (i) Find the equation of the locus of P if the ratio of the distances from P to A(5, -4) and
B(7,6) is 2 : 3.
(ii).If the distance from the point P to the points (2,3) and (2, -3) are in the ratio 2:3, then
find the equation of the required locus of P.
02. A (1,2), B (2,-3) and C(-2,3) are three points. A point P moves such that 2
2 2 2
Show that the equation to the locus of P is 7x - 7y + 4 = 0.
*03. (i) The ends of the hypotenuse of a right angled triangle are (6,0) and (0,6). Find the
equation of locus of its third vertex.
(ii) Find the locus of a point P if the join of the points (2,3) and (–1,5) subtends a right
angle at P.
*04. (i) A(5,3) and B(3,-2) are two fixed points, find the equation of locus of P, so the area of
triangle PAB is 9 units.
(ii) A(2,3) and B(–3,4) be two given points. Find the equation of locus of P so that the
area of the triangle PAB is 8.5.
*05. (i) Find the equation of locus of a point , the sum of whose distances from (0, 2) and
(0, -2) is 6
ii) Find the equation of locus of P, if A = (2,3), B=(2,-3) and PA + PB = 8.
*06. (i). Find the equation of locus of P, if A = (4,0), B = (-4,0) and 4.
(ii).Find the equation of locus of a point, the difference of whose distances from (-5,0) and (5,0) is 8.
x y x y
07. A variable line drawn through the point of intersection of the lines 1, 1 meets
a b b a
the coordinate axes in A and B. Show that the locus of the mid point of AB is 2(a + b)xy =
ab(x + y).
*08. Transform the equation 1 into the normal form when a > 0 and b > 0. If the perpen--
1 1 1
dicular distance of the straight line from the origin is p, deduce that 2
2
2 .
09. Find the equation of the straight line passing through the points (3,-4) and making X and Y-
intercepts which are in the ratio 2 : 3.
10. Find the equation of the line passing through the point of intersection of the lines
(i) x + y + 1 = 0, 2x – y + 5 = 0 and the point (5,–2)
(ii) 2x – 5y + 1 = 0, x – 3y – 4 = 0 and making equal intercepts on the axes.
iii) Find the equation of the line perpendicular to the line 3 x 4 y 6 0 and making an intercept
- 4 on the x-axis.
*11. Find the equations of the straight lines passing through the point (1,2) and making an angle of 600
with the line 3 2 0 .
12. Find the length of the perpendicular drawn from the point of intersection of the lines
3 2 4 0 and 2 5 1 0 to the straight line 7 24 15 0 .
13. A triangle of area 24sq.units is formed by a straight line and the coordinate axes in the first quad-
rant. Find the equation of the straight line, if it passes through (3,4).
*14. Find the points on the line 4x – 3y – 10 = 0 which are at a distance of 5 units from the point (1,–2).
*15. Find the condition that the lines ax by c 0 bx cy a 0 cx ay b 0 to be concurrent.
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Jr.Inter_I.P.E_Very Very Important Questions
*16. Transform the equation 3 10 0 into (a) slope intercept form (b) intercept form and (c)
normal form.
*17. x - 3y - 5 = 0 is the perpendicular bisector of the line segment joining points A, B. If A = (-1, -3),
find the co-ordinates of ‘B’.
*18. Show that the lines 2 x y 3 0 , 3 x 2 y 2 0 , 2 x 3 y 23 0 are concurrent and find the
point of concurrency.
1 2
( 4) 0 2
2
*19. Check the continuity of the following function at 2. ( )
0 2 .
2 8 3 2
*20. Check the continuity of f given by
( 2
9) /( 2
2 3) 0 5 3
( ) at the point 3.
1.5 3
co s cos
0
2
( )
*21. Show that 1 2 where a and b are real constants,
( 2) 0
2
is continuous at 0.
k 2 x k if x 1
*22. If f, given by f x , is a continuous function on R, then find the values of k.
2 if x 1
*23. Find the real constant a, b, so that the function f given by f x Sin x, if x 0
x2 a, if 0 x 1
= bx 3 if 1 x 3
3 if x 3 is continuous on R.
*24. Find the derivatives of the following functions using the first principles.
(i) 1 (ii) sin2x (iii) tan2x (iv) sec3x
log
*25. If , then show that .
(1 log )2
sin 2 ( )
*26. If sin sin( ) , then show that .
sin
2 1 2
*27. Differentiate f(x) with respect to g(x) for the ( ) tan , ( ) sin
1
.
1 2
1 2
28. Find for the functions (cos sin ), (sin cos ) .
1 1
2
30. Find the derivative of the function y defined implicity by each of the equations .
31. If ( ) sin ( ) tan 1
1
and then '( ) '( )( ) .
32. If y ax n 1
bx n
then show that x 2 y 2 n n 1 y.
33. If y a cos x b 2x sin x then show that y11 y 4 cos x .
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Jr.Inter_I.P.E_Very Very Important Questions
34. If y = acos(sinx) +bsin(sinx) then prove that: y11 tan x y1 y cos 2 x 0 ..
35. Find the derivative of cot x from the first principle.
36. If ay 4 x b then 5yy " y ' .
5 2
2
1 3 3 4 4 3 1
*37. If tan 1 tan 1 3
2
tan 1 then show that .
1 2
1 6
2 4
1 2
38. The volume of a cube is increasing at a rate of 9 cubic centimeters per second. How fast is the
surface area increasing when the length of the edge is 10 centimeters ?
*39. A particle is moving in a straight line so that after t seconds its distance is s (in cms) from a fixed
point on the line is given by s f t 8t t 3 . Find (i) the velocity as time t=2 sec (ii) the initial
velocity (iii) acceleration at t=2 sec.
40. A container in the shape of an inverted cone has height 12 cm and radius 6 cm at the top. If it is
filled with water at the rate of 12cm 3 / sec , what is the rate of change in the height of water level
when the tank is filled 8 cm ?
*41. A particle is moving along a line according to s f t 4t 3 3t 2 5t 1 where s is measured in
meters and t is measured in seconds. Find the velocity and accelration at time t. At what time the
acceleration is zero.
42. The distance-time formula for the motion of a particle along a straight line is
s t 3 9t 2 24t 18 . Find when and where the velocity is zero..
*43. A stone is dropped into a quiet lake and ripples move in circles at the speed of 5 cm/sec. At the
instant when the radius of circular ripple is 8 cm., how fast is the enclosed area increases ?
44. A container is in the shape of an inverted cone has height 8 ma nd radius 6 m at the top. If it is filled with
water at the rate of 2 m3 / minute, how fast is the height of water changing when the level is 4 m ?
*45. A point P is moving on the curve y = 2x2. The x coordinate of P is increasing at the rate 4 unit
per second. Find the rate at which y coodinate is increasing when the point is at (2,8).
46. The radius of a circle is increasing at the rate of 0.7 cm/sec. What is the rate of increase of its
circumference?
*47. Find the value of K, so that the length of the sub normal at any point on the curve y = a1 – K xk is constant.
n n
x y x y
*48. Show that the equation of the tangent to the curve 2 at (a,b) is 2.
a b a b
49. Show that the tangent at any point on the curve x c sec , y c tan is y sin x c cos .
50. Find the equations of tangent and normal to the curve y x3 4x 2 at (–1,3).
*51. (i) Find the equation of tangent and the normal to the curve y 5x 4 at the point (1,5).
(ii) Find the slope of the nomral to the curve x a cos3 ; y a sin 3 at .
4
x
52. Find the lengths of subtangent and subnormal at a point on the curve y b sin a .
a x /a x /a
*53. Find the lengths of normal and subnormal at a point on the curve y e e .
2
x
54. Find the equation of tangent and normal to the curve y 2.e 3 at the point where the
curve meets the Y-axis.
*55. Find the equations of tangent and normal to the curve xy = 10 at (2, 5).
Sri Chaitanya IIT Academy, India. Sri Bhaskar Bhavan, VJA Page No : 7
Jr.Inter_I.P.E_Very Very Important Questions
SECTION - C
III. Long Answer Questions
*01. If Q(h, k) is the foot of the perpendicular from ( 1 , 1 ) on the straight line 0 , then
( 1 ) : ( 1 ) : ( 1 1 ):( 2
2
) . Also find foot of perpendicular form (4, 1)
upon the line 3x – 4y + 12 = 0
*02. If Q(h, k) is the image of the point ( 1 , 1 ) w.r.t. the straight line 0 ,then
( 1 ) : ( 1 ) : 2( 1 1 ) : ( 2 2 )
*03. Find the circumcentre of the triangle whose vertices are given below
i) (-2,3), (2, -1) and (4,0) ii) (1,3), (0, -2) and (-3, 1)
04. (i) Find the circumcentre of the triangle whose sides are 3 5 0, 2 4 0 and
5 3 1 0 .
(ii) x + y + 2 = 0, 5x – y – 2 = 0, x – 2y + 5 = 0.
*05. If p and q are the lengths of the perpendiculars from the origin to the straight lines
sec cosec and cos sin cos 2 , prove that 4 2 2 2 .
*06. The base of an equilateral triangle is x + y – 2 = 0 and the opposite vertex is (2, –1). Find the
equations of the remaining sides.
07. Find the orthocentre of the triangle whose vertices are (-5,-7), (13,2) and (-5,6).
08. Let the equation 2
2
0 represent a pair of straight lines. Then the angle be-
2
tween the lines is given by cos .
( )2 4 2
*09. If the equation ax 2 2 hxy by 2 0 represents a pair of distinct (i.e, intersecting) lines, then the
combined equation of the pair of bisectors of the angles between these lines is
h( x 2 y 2 ) (a b) xy .
*10. Show that the product of the perpendicular distances from a point (, ) to the pair of straight lines
2 2 2
2
2 2
0 is ( )2 4 2 .
*11. Show that the area of the triangle formed by the lines ax 2 2 hxy by 2 0 and lx my n 0
n 2 h 2 ab
is am 2 2 hlm bl 2 .
*14. Find the values of k, if the lines joining the origin to the points of intersection of the curve
2 x 2 2 xy 3 y 2 2 x y 1 0 and the line x 2 y k are mutually perpendicular..
15. Find the condition for the chord 1 of the circle 2
2
2
(whose centre is the
origin) to subtend a right angle at the origin.
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Jr.Inter_I.P.E_Very Very Important Questions
16. Find the angle between the lines joining the origin to the points of intersection of the curve
2 2 2 2 5 0 and the line 3 1 0 .
2
*17. Let us find the lines joining the origin to the points of intersection of the curve
7 2 4 8 2 2 4 8 0 . with the straight line 3 2 and the angle between
them.
*18. Show that the pair of straight lines 6 2 5 6 2 0 and 6 2 5 6 2 5 1 0
form a square.
19. If the equation mx2 – 10xy + 12y2 + 5x – 16y – 3 = 0 represents a pair of straight lines. Find m
and also find angle and point of intersection for this value of m
20. Write down the equaiton of the pair of straight lines joining the origin to the points of intersection
of the line 6x y 8 0 with the pair of straight lines : 3x 2 4xy 4y 2 11x 2y 6 0 . Show
that the lines so obtained make equal angles with the co ordiante axes.
21. Find the angle between two diagonals of a cube.
22. If a ray makes angles , , , with the four diagonals of a cube show that
4
cos 2 cos 2 cos 2 cos 2 .
3
*23. Find the angle between the lines whose direction cosines satisfy the equations
0, 2 2 2 0 .
*24. Find the direction cosines of two lines which are connected by the relations – 5m + 3n = 0,
7 2 + 5m2 – 3n2 = 0.
*25. Find the angle between the lines whose direction cosines are given by the equations
3 5 0 and 6 2 5 0 .
*26. Find the direction cosines of two lines which are connected by the relations + m + n = 0 and
mn – 2n – 2 m = 0. Also find the acute angle between the lines.
27. Show that the lines whose d.c’s are given by + m + n = 0, 2mn + 3n – 5 m = 0 are perpendicu-
lar to each other.
28. The vertices of a triangle A(1,4,2), B(–2,1,2),C(2,3,–4) find the angles A,B,C.
1 2
1 2
*29. If tan1
for 0 1 , find .
1 1
2 2
1 2
*30. If 1 2
1 2
( ) then .
1 2
1 log log dy
31. (i) If log
log then . (ii) y x tan x sin x
cos x
, find
log 2 dx
*32. Find the derivative of the function (sin )log sin
.
1
log
*33. If then 1 .
log
1/ 2 a cos x b
34. If f x a2 b2 .cos 1
then prove that f 1 x a b cos x
1
.
a b cos x
dy
*35. If y x a2 x2 a 2 log x a2 x 2 then prove that 2 a2 x2 .
dx
2 2 2
*36. If the tangent at any point on the curve 3
3
3 intersects the coordinate axes in A and B,
then show that the length AB is a constant.
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Jr.Inter_I.P.E_Very Very Important Questions
*37. If the tangent at any point P on the curve
( 0) meets the coordinate axes in A, B,
then show that AP : BP is a constant.
*38. Show that the curves 2
4( 1) and 2
36(9 ) intersect orthogonally..
39. (i) Find the angle between the curves 2
4 ; 2
2
5.
(ii) Find the angle between the curves y 2 8x, 4x 2 y 2 32 .
40. At any point t on the curve ( sin ), (1 cos ) , find the lengths of tangent, normal,
subtanent and subnormal.
1 1
41. Show that the curves 6x2 – 5x + 2y = 0 and 4x2 + 8y2 = 3 touch each other at , .
2 2
*42. Show that the condition for the orthogonality of the curves ax2 + by2 = 1 and a1x 2 b1 y 2 1 is
1 1 1 1
a b a1 b1 .
43. At a point x1, y1 on the curve x 3 y 3 3axy , Show that the tangent is
x2
1 ay1 x y12 ax1 y ax1y1
*44. Show that when the curved surface of a right circular cylinder inscribed in a sphere of radius R is
maximum, then the height of the cylinder is 2 .
*45. A window is in the shape of a rectangle surmounted by a semicircle. If the perimeter of the window
be 20 ft. Find the maximum area of the window.
*46. From a rectangular sheet of dimensions 30 cm × 80 cm, four equal squares of side x cm are
removed at the corners, and the sides are then turned up so as to form an open rectangular box.
What is the value of x, so that the volume of the box is the greatest.
47. A wire of length is the cut into two parts which are bent respectively in the form of a square and a
circle. What are the lengths of the pieces of the wire so that the sum of the areas is the least.
48. Find the maximum area of the rectanle that can be formed with fixed perimeter 20.
49. Prove that the radius of the right circular cylinder of greatest curved surface area which
can be inscribed in a given cone is half of that of the cone.
*50. Find two positive integers x and y such that x + y = 60 and xy3 is maximum.
51. The proft function p(x) of a company, selling x items per day is given by
p(x) = (150 - x)x - 1600. Find the number of items that the company should shell to get maximum
profit. Also find the maximum profit.
*52. Find two positive integers whose sum is 16. and the sum of whose squares is minimum.
Sri Chaitanya IIT Academy, India. Sri Bhaskar Bhavan, VJA Page No : 10
Jr.Inter_I.P.E_Very Very Important Questions
PHYSICS
SECTION - A
I. Very Short Answer Questions
01. Define average pressure.Mention it’s unit and dimensional formula.Is it a scalar or a vec-
tor?
02. Define co-efficient Viscosity. What are it’s units and dimensions?
03. What is the principle behind the carburetor of an automobile?
04. What is magnus effect?
05. Why are drops and bubbles spherical?
06. Give the expression for the excess pressure in a liquid drop.
07. Give the expression for the excess pressure in an air bubble inside the liquid.
08. Give the expression for the soap bubble in air.
09. Can a substance contract on heating? Give an example.
10. Why gaps are left between rails on a railway track?
11. What is latent heat of fusion?Write its units.
12. What is latent heat of vapourisation?
13. State Weins displacement law?
14. Ventilators are provided in rooms just below the roof. Why?
15. What is greenhouse effect? Explain global warming.
16. State Newton’s law of cooling.
17. State the conditions under which Newton’s law of cooling is applicable.
18. The roof of buildings are often painted white during summer. Why?
19. Define mean free path.
20. When does a real gas behave like an ideal gas?
21. State Boyle's Law and Charles Law.
22. State Dalton’s law of partial pressures.
23. What is the expression between pressure and kinetic energy of a gas molecules ?
24. What is the discovery of C.V. Raman ?
25. What is the contribution of S.Chandra sekhar to Physics?
26. Distinguish between accuracy and precision.
27. How can systematic errors be minimised or eliminated ?
28. Distinguish between fundamental units and derived units.
29. What are the different types of errors that can occur in a measurement ?
30. Why do we have different units for the same physical quantity ?
31. The percentage error in the mass and speed are 2% and 3% respectively. What is the
maximum error in kinetic energy calculated using these quantities ?
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Jr.Inter_I.P.E_Very Very Important Questions
32. In a system of units, the unit of force is 100 N, unit of length is 10 m and the unit of time is
100 s. What is the unit of mass in the system ?
33. The vertical component of a vector is equal to its horizontal component. What is the*
angle made by the vector with X-axis‘?
34. Two forces of magnitudes 3 units and 5 units act at 60° with each other. what is the
magnitude of their resultant?
35. A i j .What is the angle between the vector and x—axis?
36. When two right angled vectors of magnitude 7 units and 24 units combine, what is
the magnitude of their resultant?
37. If P =2i + 4j + 14k and Q= 4i + 4j + 10k find the magnitude of P + Q.
SECTION - B
II. Short Answer Questions
01. a) Develop the notations of work and kinetic energy and show that it leads to work-energy
theorem.
b) State the conditions under which a force does no work.
02. State and prove law of conservation of energy in case of a freely falling body.
03. A machine gun fires 360 bullets per minute and each bullet travels with a velocity of
600 ms 1 . If the mass of each bullet is 5 gm, find the power of the machine gun?
04. Define simple harmonic motion. Show that the motion of (point) projection’ of a particle
performing uniform circular motion, on any diameter, is simple harmonic. What is the
length of the pendulum. Which ticks seconds.
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Jr.Inter_I.P.E_Very Very Important Questions
05. Show that the motion of a simple pendulum is simple harmonic and hence derive an
equation for its time period. What is seconds pendulum?
06. Explain reversible and irreversible processes. Describe the Working of Carnot engine.
Obtain an expression for the effieciency.
07. State second law of thermodynamics. How is heat engine different from a refrigerator.
CHEMISTRY
SECTION - B
II. Short Answer Questions
01. State Fajan's rules, and give suitable examples.
02. Explain the hybridisation involved in PCl5 molecule.
03. Explain the hybridisation involved in SF6 molecules.
04. Explain the fomration of coordinate convalent bond with one example.
05. What is hydrogen bond? Explain the different types of hydrogen bonds with examples.
06. Derive Idel gas equation.
07. State and Grahan's law of diffusion.
08. State and explain Dalton's law of partial pressures.
09. Deduce (a) Boyle's law and (b) Charle's law from Kinetic gas equation.
10. Deduce (a) Grahams and (b) Dalton's law from kinetic gas eqaution.
11. Define (a) rms (b) average (c) most probable speeds of gas molecules. Give their inter-
relationship.
12. Write the postulates of Kinetic molecular theory of gases.
13. Chemical analysis of a carbon compound gave the following percenatge composition by
weight of the elemenets presents. Carbon = 10.06%, hydrogen = 0.84% ; chlorine =
89.10%. Calculate the Emprical formula.
14. A carbon compound on analysis gave the following percentage composition carbon
14.5% ; Hydrogen 1.8%; Chlorine 64.46%; Oxygen 19.24%; Calculathe the emprical
formula of the compound.
15. Calculate the emprical formula of a compound having percentage composition
K = 26.57% ; Cr = 35.36% ; 0 = 38.07%.
16. A carbon compound contains 12.8% carbon, 2.1% hydrogen, 85.1% bromine. The
molecular weight of the compound is 187.9 calculate molecular formula.
17. Balance the following redox reactions by ion electron method.
2
(c) Cr2O 7 aq SO 2 g Cr 3aq SO 42 aq (in acidic medium)
Sri Chaitanya IIT Academy, India. Sri Bhaskar Bhavan, VJA Page No : 13
Jr.Inter_I.P.E_Very Very Important Questions
18. Explain extensive and intensive properties.
19. Define heat capacity. What are CP and Cv ? Show that CP – Cv = R.
20. State and explain the Hess's law of constant Heat summation.
21. State the second law of thermodynamics and explain it.
22. State the first law of thermodynamics. Explain its mathematical notation.
23. Derive the relation between KP and KC for equilibrium reaction.
24. Write the conjugate acid and conjugate base of each of the following.
Sri Chaitanya IIT Academy, India. Sri Bhaskar Bhavan, VJA Page No : 14
Jr.Inter_I.P.E_Very Very Important Questions
41. Describe two methods of preparations of ethylene. Give equation for the reactions of
ethylene with the following
(a) O3 (Ozone) (b) HOCl (Hypohalos acid)
(c) Baeyer's reagent (Cold and dil.alk.KMnO4)
(d) Heated with O2 at high pressure
(Write any two methods of ethylene)
42. Complete the following reactions and name the products A, B and C
H 2O hot metal AlCl3 CH 3Cl
CaC 2 A tube
B C.
SECTION - C
III. Long Answer Questions
01. What are the postulates of Bohr's model of hydrogen atom? Discuss the importance of
this model to explain various series of line spectra in hydrogen atom.
02. How are the quantum numbers n, and m arrived at? Explain the significance of these
quantum numbers.
03. How do the following properties change in group-1 and in the third period? Explain with
example (a) Atomic radius (b) IE (c) EA (d) Nature of oxides
04. Define IE1 and IE2 . Why is IE2 > IE1 for a given atom? Discuss the factors that effect IE an
element.
05. What is a periodic property? How the following properties vary in a group and in a
period? Exaplain.
(a) Atomic radius (b) Electron gain enthalpy
(c) Electronegativity (d) Ionization Enthalpy
06. Write an esay on s, p, d and f block elements.
07. Give an account of VESPR theory, and its applciations.
08. What do you understand by Hybridisation? Exaplain different types of hybrodisation
involving s and p porbitals.
09. Give the Molecular Orbitals Energy diagram of (a) N2 and (b) O2. Calculate the respective
bond order. Write the magentic nature of N2 and O2 molecules.
10. How do we het benzene from acetylene? Give the corresponding equation. Explain the
halogenation alkylation, acylation, nitration and sulphonation of benzene.
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