Mole Concept and Stoichiometry – Summary Notes

Gases have some properties which differentiate them from other states of the matter, i.e., solids
and liquids. The distance between the molecules of a gas is far larger than solids and liquids
which results in weaker force of attraction between these molecules. The collision between the
gas molecules is random and, hence, gas molecules move in all directions, that too, in a straight
line.
Characteristics of Gases
 Gases have no fixed shape or volume.
 They exert equal pressure in all directions.
 They are highly compressible.
 They can expand on decreasing pressure or increasing temperature.
 They have low density.
 They have large intermolecular spaces and kinetic energy, so they diffuse easily.
 Factors causing variations in the properties of a gas are pressure, temperature and volume
of the gas.
 Gay Lussac’s law of combining volumes states that under similar conditions of
temperature and pressure whenever gases react together, the volumes of the reacting gases
as well as the gaseous products bear a simple whole number ratio.
 Avogadro’s law states that equal volumes of all gases contain the same number of
molecules under similar conditions of temperature and pressure.
 The number of atoms present in 12 g (gram atomic weight) of carbon  C12  is called
Avogadro’s number or Avogadro’s constant. It is represented by N A .
N A  6.023 1023
 Atomicity: It is the number of atoms present in one molecule of an element.
 Elements containing one atom in their molecules are called monoatomic, for example,
helium (He), neon (Ne) and argon (Ar).
 Elements containing two atoms in their molecules are called diatomic, for example,
oxygen  O2  , nitrogen  N2  and chlorine  Cl2  .
 Elements containing more than two atoms in their molecules are called polyatomic,
for example, ozone O3  , phosphorus  P4  and sulphur  S8  .
 Applications of Avogadro’s Law
 To determine the atomicity of elementary gases like H 2 , O2 , Cl2 and N 2 .
 To explain Gay Lussac’s law of combining volumes.
 To relate gram molecular mass and gram molar volume of the gas at STP
GMM
i.e., Molar Volume 
Mass per gas at STP
 To relate molecular mass and vapour density
 To determine the molecular formula of a gas

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 Atomic Weight or Relative Atomic Mass
Hydrogen scale: It is the number of times an atom of an element is heavier than an atom
of hydrogen.
Mass of one atom of an element
Relative atomic mass 
Mass of one atom of hydrogen
Carbon scale: It is the average relative mass of an atom of an element as compared to the
mass of an atom of carbon  C12  taken as 12.
Mass of one atomof an element
Relative atomic mass 
1/12  Mass of one atomof carbon C12 

 Gram Atomic Mass (GAM): It is the atomic mass of an element expressed in grams.
Gram atomic mass = Gram atoms

Molecular Weight or Relative Molecular Mass

Hydrogen scale: It is the number of times a molecule of a substance is heavier than an atom
of hydrogen.
Mass of one molecule of a substance
Molecular weight 
Mass of one atom of hydrogen
Carbon scale: It is the average relative mass of a molecule of a substance as compared to the
mass of an atom of carbon  C12  taken as 12.
Mass of one molecule of a substance
Molecular weight 
1/12   Mass of one atom of carbon (C12 )
 Molar mass or Gram Molecular Mass (GMM):
It is the molecular mass of a substance expressed in grams.
Gram molecular mass = Gram molecules
Gram molecular mass of all gases contains 6.023 1023 number of molecules at STP.
 Molar Volume or Gram Molecular Volume: It is the volume occupied by one mole of
a gas at STP and is equal to 22.4 litres. Gram molecular mass of all gases occupy a volume
of 22.4 litres at STP.
Gram molecular mass
Molar Volume 
Mass per litre of gas at STP
 Mole: It is the amount of a substance which contains the same number of elementary
particles (atoms, molecules or ions) as the number of atoms present in 12 g of carbon
C .
12

1 mole  6.023 1023 particles

Mass of the element
 Moles of an element 
Atomic mass or GAW
Mass of the compound
 Moles of a compound 
Molecular mass or GAW

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 1 mole can be depicted diagrammatically as:

 Applications of Mole Concept

The mole concept helps in the chemical calculations in a number of ways as follows:
 To calculate the actual mass of atoms
Atomic mass or GAW
Mass of one atom 
6.023 10 23
 To calculate the actual mass of molecules
Molecular mass or GAW
Mass of one molecule 
6.023 1023
 To calculate the number of atoms
 Moles  6.0231023
Mass of substance in grams  6.023 1023

Gram molecular mass
 To calculate the number of molecules
 Moles  6.0231023
Molecular mass or GMW

6.023 10 23
 To determine the number of particles present in V litres of a gas at NTP
Number of molecules present in V litres of gas at NTP
Volume of the gas in litres  6.023 1023

22.4 litres
 Vapour Density: It is the ratio of the mass of a certain volume of a gas (or vapour) to the
mass of the same volume of hydrogen under similar conditions of temperature and
pressure.
Mass of a certain volume of a or vapour
Vapour Density [VD] 
Mass of thesame volume of hydrogen
Molecular Mass
Vapour Density 
2
or Molecular Mass  2  VD

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 Percentage Composition of a Compound: It is the percentage by weight of each element
present in a compound. It is the part by weight of its constituent elements present in 100
parts by weight of the compound.
Percentage composition by mass
Weight of the element in one molecule of a compound
 100
GMW of the compound
 Empirical Formula: It is the simplest formula of a compound which gives the simple
whole number ratio of various elements present in one molecule of the compound.
 Determining the Empirical Formula: The following steps are involved in the calculation
of the empirical formula.
 Step 1: Write down the percentage composition by weight and the atomic weight of
each element in the given compound.
 Step 2: Divide the percentage composition of each element by its atomic weight to
get the relative number of atoms in the compound.
 Step 3: Select the smallest relative number and divide the remaining relative numbers
by it to find the simplest ratio of atoms present in the compound.
 Step 4: In case the simplest ratio is not a whole number, multiply each ratio by the
smallest suitable integer so that a whole number ratio is obtained.
 Step 5: Write the empirical formula showing the atoms in the proper simple ratio of
whole number.

 Molecular Formula: It is a chemical formula which gives the actual number of atoms of
various elements in one molecule of a compound.
Molecular Formula  Empirical Formula n
 Relationship between Empirical Formula Weight and Molecular Formula Weight
Molecular formula weight
n
Empirical formula weight
Where n  Simple whole number
 Stoichiometry: It is the study of the quantitative relationship conveyed by a chemical
equation.
 Chemical Equation: It gives the composition and identity of the elements, or compounds,
which take part as the remains and are formed as the products.
 Information Conveyed by the Chemical Equation
 The chemical equation gives information about moles and masses of various reactants
and products.
 It gives information about volumes of gaseous reactants and products measured at
STP.
 Calculations Based on Chemical Equations
 The equation must be balanced.
 The molecular weight of the required substance is calculated and should be written
below the formula of the substance.
 The volume of a gas in litres is indicated by multiplying the number of molecules of
the gas with 22.4.

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