Atomic Structure HL Multiple Choice Questions Answers
Atomic Structure HL Multiple Choice Questions Answers
A 58 B 31 C 29 D 27
A 79 B 34 C 36 D 32
7. In the emission spectrum of deuterium the frequency of the convergence limit in the series
where the electron falls down to n=1 is 3.29x1015 Hz. The value of Planck’s constant is
6.63x10-34 Js. The ionization energy of deuterium in kJ mol-1 is given by.
A 3.29x1015 x 6.63x10-34
6.02x1023 x 1000
B 3.29x1015 x 6.63x10-34 x 6.02x1023
1000
C 6.63x10-34 .
A F B Mg C Na D O
14. Rhenium has two naturally occurring isotopes, 185Re and 187Re. The relative atomic
mass of Rhenium is 186.2. What are the natural abundances of these isotopes?
A 40 % 185Re and 60 % 187Re B 60 % 185Re and 40 % 187Re
C 12 % 185Re and 88 % 187Re D 88 % 185Re and 12 % 187Re
15. Which of the following would produce a line in the visible emission spectrum of hydrogen:
A A photon is emitted as an electron falls from outside the atom to the level with n=1
B A photon is absorbed as an electron is promoted from level n=1 to level n=2
C A photon is emitted as an electron falls from level n=5 to level n=2
D A photon is emitted as an electron falls from level n=7 to level n=3
16. Which of the following transitions in a hydrogen atom would produce a line of the highest
frequency in the emission spectrum?
A n=5 → n=4 B n=4 → n=3 C n=3 → n=2 D n=2 → n=1
17. Which of the following electronic transitions in a hydrogen atom would produce a line of
the shortest wavelength in the emission spectrum?
A n=7 → n=2 B n=9 → n=3 C n=2 → n=1 D n=5 → n=2
19. Which of the following statements about first ionisation energy is not correct?
A First ionisation energy increases across regularly across Period 2
B First ionisation energy decreases down Group 17
C Helium has a higher first ionisation energy than hydrogen
D The first ionisation energy of oxygen is higher than that of sulfur
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HL Atomic Structure Multiple-Choice Questions
20. Which of the following statements is correct
A The maximum number of electrons in the 3d subshell is 6
B The maximum number of electrons in the 5f subshell is 14
C The maximum number of electrons in the 5th shell is 32
D It is not possible for an atom to have more electrons in p orbitals than in d orbitals
21. Which of the following atoms/ions does not have exactly 2 unpaired electrons?
A S B Ni2+ C Cr3+ D Ti2+
22. A line in the emission spectrum of magnesium has wavelength 0.313 µm. The energy of
the photon (in J) emitted is given by:
A E = 6.63x10-34 x 3x108
0.313
B E = 6.63x10-34 x 3x108
3.13x10-6
C E = 6.63x10-34 x 3.13x10-10
D E = 6.63x10-34 x 3x108
3.13x10-7
23. The first ionisation energies of 4 successive elements in the periodic table are:
736 kJ mol-1 577 kJ mol-1 786 kJ mol-1 1060 kJ mol-1
These elements could be:
A Na, Mg, Al, Si B Mg, Al, Si, P C S, Cl, Ar, K D Si, P, S, Cl
24. The first 7 successive ionisation energies for an Ionisation energy / kJ mol-1
element are: 1 966
2 1950
3 2730
4 4850
5 6020
6 12300
7 15400
The element is:
A Ga B Ge C As D Se
25. Which of the following orbital diagrams is correct for an atom with electron configuration
3d3 in its ground state?
A
B
C
D
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