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Morphology and Physical Properties of Gamma Iron Oxide

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Growth and Properties

Part of the book series: Crystals ((CRYSTALS,volume 2))

Abstract

Gamma ferric oxide, γ-Fe2O3, is still the most widely used material for magnetic recording devices. Although there are literature references dating in the 19th century, the material was virtually unknown until systematic studies were commenced about 1925. Methods to prepare small, polycrystalline particles of various shapes, both unsupported and supported on iron metal, as well as epitaxial single-crystal films, are indicated. Data on the crystallographic and magnetic structure and other physical properties are summarized. The transformations from magnetite to gamma ferric oxide to hematite are treated. Finally, γ-Fe2O3 with other cation substitutions is considered. Some directions where further research is needed are suggested.

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References

  1. von Kobell, F.: Grandzuge der Mineralogie 304 (1838)

    Google Scholar 

  2. Robbins, J.: Chem. News 1, 11 (1859)

    Google Scholar 

  3. Malaguti, F.: C. R. (Paris) 55, 350 (1862)

    Google Scholar 

  4. Liversidge, A.: Trans. Aust. Assoc. Hobart 302 (1892)

    Google Scholar 

  5. Hilpert, S.: Ber. dtsch. phsik. Ges. 11, 293 (1909)

    Google Scholar 

  6. Abraham, H., Planiol, R.: C. R. (Paris) 180, 1328 (1925)

    CAS  Google Scholar 

  7. Chevallier, R.: C. R. (Paris) 180, 1473 (1925)

    CAS  Google Scholar 

  8. Welo, L. A., Baudisch, O.: Phil. Mag. 50, 399 (1925)

    CAS  Google Scholar 

  9. Sosman, R. B., Posnjak, E.: J. Wash. Acad. Sci. 15, 329 (1925)

    CAS  Google Scholar 

  10. Wagner, P. A.: Econ. GeoL 22, 845 (1927)

    Article  CAS  Google Scholar 

  11. Scheiderhöhn, H.: Neues Jahrb., Referate 368 (1929)

    Google Scholar 

  12. Herroun, E. F., Wilson, E.: Proc. Phys. Soc. (Lond.) 41, 100 (1928)

    Article  CAS  Google Scholar 

  13. Newhouse, W. H., Glass, J. P.: Econ. Geol. 31, 694 (1936)

    Google Scholar 

  14. Nagata, T.: Rock magnetism, Tokyo: Maruzen 1971

    Google Scholar 

  15. Takei, H., Chiba, S.: J. Phys. Soc. Japan 21, 1255 (1966)

    Article  Google Scholar 

  16. Burlakova, R. B., Edelman, I. S., Koval, K. P., Pavolov, V. F.: Fiz. Tverd. Tela. 17, 320 (1975) [Sov. Phys.-Solid State 17, 195 (1975)]

    Google Scholar 

  17. Camras, M.: U. S. Pat. 2,694, 656 (1954)

    Google Scholar 

  18. Corradi, A. R.: J. M. M. M. 7, 299 (1978)

    Google Scholar 

  19. Bernal, J. D., Das Gupta, D. R., MacKay, A. L.: Nature 180, 645 (1957)

    Article  CAS  Google Scholar 

  20. Sykora, V.: Ind. Chem. Belge. 32, 428 (1967)

    CAS  Google Scholar 

  21. van Oosterhout, G. W.: Acta Cryst. 13, 932 (1960)

    Article  Google Scholar 

  22. Daniel, E. D.: J. Aud. Engr. Soc. 20, 92 (1972)

    Google Scholar 

  23. Gustard, B., Wright, M. R.: IEEE Trans. Mag. MAG-8, 426 (1972)

    Google Scholar 

  24. Bates, G.: IEEE Trans. Mag. MAG-14, 136 (1978)

    Google Scholar 

  25. Ayers, J. W., Stephens, R. A.: U. S. Pat. 3,015,627; 3,015, 628 (1962)

    Google Scholar 

  26. Goto, H., Abashi, G.: U. S. Pat. 3,047, 428 (1962)

    Google Scholar 

  27. Krones, F.: Mitt. Forschungslab. Agfa 1, 289 (1955)

    Google Scholar 

  28. van Oosterhout, G. W., Rooijmans, C. J. M.: Nature 181, 44 (1958)

    Article  Google Scholar 

  29. Mollard, P., Rousset, A., Dupré, G.: Mat. Res. Bull. 12, 797 (1977)

    Article  CAS  Google Scholar 

  30. Krupyanskii, Yu. F., Suzdalev, I. P.: Zh. Eksp. Teor. Fiz. 65, 1741 (1973): [Sov. Phys.-JETP 38, 859 (1974)

    Google Scholar 

  31. Elmore, W. C.: Phys. Rev. 54, 309 (1938)

    Article  CAS  Google Scholar 

  32. Hägg, G.: Z. physik. Chem. 29, 95 (1935)

    Google Scholar 

  33. Verwey, E. J. W.: Z. Krist. 91, 65 (1935)

    CAS  Google Scholar 

  34. Haul, R. Schoon, T.: Z. physik. Chem. 44, 216 (1939)

    Google Scholar 

  35. David, J., Welch, A. J. E.: Trans. Faraday Soc. 52, 1642 (1955)

    Article  Google Scholar 

  36. Simha, K. P., Sinha, A. P. B.: Z. anorg. allg. chem. 293, 288 (1957)

    Google Scholar 

  37. Namikawa, M., Sato, M., Imaoka, Y., Tochihara, S.: Denki Kagaku 31, 37 (1962)

    Google Scholar 

  38. Korobeinikova, A. V., Fadeev, V. I., Reznitskii, L. A.: Zh. Struk. Khim. 17, 860 (1976): [J. Struc. Chem. 17, 737 (1976)]

    Google Scholar 

  39. Verwey, E. J. W., Heilmann, E. L.: J. Chem. Phys. 15, 174 (1948)

    Article  Google Scholar 

  40. Ferguson, G. A., Hass, M.: Phys. Rev. 112, 1130 (1958)

    Article  CAS  Google Scholar 

  41. Braun, P. B.: Nature 170, 1123 (1952)

    Article  CAS  Google Scholar 

  42. Behar, J., Collongues, R.: C. R. (Paris) 244, 617 (1957)

    CAS  Google Scholar 

  43. Schrader, R., Buttner, G.: Z. anorg. allg. chem. 320, 205 (1963)

    Article  CAS  Google Scholar 

  44. Ueda, R., Hasegawa, K.: J. Phys. Soc. Japan B-2, 17, 391 (1962)

    Article  CAS  Google Scholar 

  45. Kachi, S., Momiyama, K., Shimizu, S.: J. Phys. Soc. Japan 18, 106 (1963)

    Article  Google Scholar 

  46. Haneda, K., Morrish, A. H.: Solid State Comm. 22, 779 (1977)

    Article  CAS  Google Scholar 

  47. Gillot, B., Bouton, F.: J. Sol. State Chem. 30, 365 (1979)

    Google Scholar 

  48. Hurt, J., Amendola, A., Smith, R. E.: J. Appl. Phys. 37, 1170 (1966)

    Article  CAS  Google Scholar 

  49. Gustard, B., Vriend, H.: IEEE Trans. Mag. MAG-5, 326 (1969)

    Google Scholar 

  50. Klimaszewki, B., Pietrzak, J.: Bull. Acad. Pol. Sci. 17, 51 (1969)

    Google Scholar 

  51. Imaoka, Y.: J. Electrochem. Soc. Japan 36, 15 (1968)

    CAS  Google Scholar 

  52. Imaoka, Y., Hoshino, Y., Satoh, M.: Proc. Inst. Conf, on Ferrites, p. 467. Tokyo: University of Tokyo Press 1971

    Google Scholar 

  53. Haneda, K., Morrish, A. H.: J. de Physique C-1, 38 , 321 (1977)

    Google Scholar 

  54. Columbo, U., Fagherazzi, G., Gazzarrini, F., Lauzavecchia, G., Sironi, G.: Nature 202, 175 (1964); ibid. 219, 1036 (1968)

    Article  Google Scholar 

  55. Gallagher, K. J., Feitknecht, W., Mannweiler, U.: Nature 217, 1118 (1968)

    Article  CAS  Google Scholar 

  56. Topsøe, H., Dumesic, J. A., Boudart, M.: J. de Physique C-6, 35, 411 (1974)

    Article  Google Scholar 

  57. Basta, E. Z.: Econ. Geol. 54, 698 (1959)

    Article  CAS  Google Scholar 

  58. De Boer, F. E., Selwood, P. W.: J. Amer. Chem. Soc. 76, 3365 (1954)

    Article  Google Scholar 

  59. Healy, F. H., Chessick, J. J., Franioli, A. V.: J. Phys. Chem. 60, 1001 (1956)

    Article  Google Scholar 

  60. Aharoni, A., Frei, E. H., Schieber, M.: Phys. Rev. 127, 439 (1962)

    Article  CAS  Google Scholar 

  61. Elder, T.: J. Appl. Phys. 36, 1012 (1965)

    Article  CAS  Google Scholar 

  62. Strickler, D. W., Roy, R.: J. Am. Ceram. Soc. 44, 225 (1961)

    Article  CAS  Google Scholar 

  63. Sadise, H., Haase, R.: Z. Phys. Chem. A 148, 401 (1930)

    Google Scholar 

  64. Egger, K., Feitknecht, W.: Helv. Chim. Acta 45, 2042 (1962)

    Article  CAS  Google Scholar 

  65. Bondo, Y., Kiyama, M., Takada, T., Kachi, S.: Japan J. Appl. Phys. 4, 240 (1965)

    Article  Google Scholar 

  66. Feitknecht, W., Mannweiler, U.: Helv. Chim. Acta. 50, 570 (1967)

    Article  CAS  Google Scholar 

  67. Mollard, P., Rousset, A., Pâris, J.: C. R. (Paris) 270, 745 (1970)

    CAS  Google Scholar 

  68. Morrish, A. H., Sawatzky, G. A.: Proc. Int. Conf. Ferrites, p. 144. Tokyo: University of Tokyo Press 1971

    Google Scholar 

  69. Senno, H., Tawara, Y.: Jap. J. Appl. Phys. 6, 509 (1967)

    Article  CAS  Google Scholar 

  70. Senno, H., Tawara, Y., Iida, Y.: Jap. J. Appl. Phys. 6, 1347 (1967)

    Article  CAS  Google Scholar 

  71. Cohen, M., Hashimoto, K.: J. Electrochem. Soc. 121, 42 (1974)

    Article  CAS  Google Scholar 

  72. Boggs, W. E., Kachik, R. H., Pellessier, G. E.: J. Electrochem. Soc. 114, 32 (1967)

    Article  CAS  Google Scholar 

  73. Meisel, W.: Z. Chem. 11, 238 (1971)

    Article  CAS  Google Scholar 

  74. Eusling, J., Fleisch, J., Grim, R., Grüber, J., Gülich, P.: Corrosion Sci. 18, 797 (1978)

    Article  Google Scholar 

  75. Iitaka, I., Miyake, S., Iimori, T.: Nature 139, 156 (1937)

    Article  CAS  Google Scholar 

  76. Nagayama, M., Cohen. M.: J. Electrochem. Soc. 109, 781 (1962)

    Article  CAS  Google Scholar 

  77. Ord, J. L., DeSmet, D. J.: J. Electrochem. Soc. 123, 1876 (1976)

    Article  CAS  Google Scholar 

  78. Feitknecht, W., Durtschi, A.: Helv. Chim. Acta 47, 174 (1964)

    Article  CAS  Google Scholar 

  79. van Diepen, A. M., Vledder, H. V., Langereis, C.: Appl. Phys. 15, 163 (1977)

    Article  Google Scholar 

  80. Haneda, K., Morrish, A. H.: Surface Sci. 77, 584 (1978)

    Article  CAS  Google Scholar 

  81. Néel, L.: Ann. Phys. 3, 137 (1948)

    Google Scholar 

  82. Morrish, A. H.: Physical principles of magnetism p. 498. New York: Wiley 1965

    Google Scholar 

  83. Armstrong, R. J., Morrish, A. H., Sawatzky, G. A.: Phys. Lett. 23, 414 (1966)

    Article  CAS  Google Scholar 

  84. Coey, J. M. D.: Phys. Rev. Lett. 27, 1140 (1971)

    Article  CAS  Google Scholar 

  85. Morrish, A. H., Clark, P. E.: Proc. Int. Conf. Mag, p. 180. Moscow: Nauka 1974

    Google Scholar 

  86. Morrish, A. H., Haneda, K., Schurer, P. J.: J. de Physique C-6, 37, 302 (1976)

    Google Scholar 

  87. Coey, J. M. D., Khalafallah, D.: Phys. Stat. Sol. (a) 11, 229 (1972)

    Article  CAS  Google Scholar 

  88. Berkowitz, A. E., Schuele, W. J., Flanders, P. J.: J. Appl. Phys. 39, 1261 (1968)

    Article  CAS  Google Scholar 

  89. Mollard, P., Germi, P., Rousset, A.: Physica86–88 B, 1343 (1977)

    Google Scholar 

  90. Itoh, F., Satou, M.: Jap. J. Appl. Phys. 14, 2091 (1975)

    Article  CAS  Google Scholar 

  91. Haneda, K., Morrish, A. H.: IEEE Trans. Mag. MAG-16, 138

    Google Scholar 

  92. Weiss, P., Forrer, R.: Ann. Phys. 12, 279 (1929)

    CAS  Google Scholar 

  93. Henry, W. E., Boehm, M. J.: Phys. Rev. 101, 1253 (1956)

    Article  CAS  Google Scholar 

  94. Morrish, A. H.: Physical principles of magnetism, p. 491. New York: Wiley 1965

    Google Scholar 

  95. Michel, A., Chaudron, G.: C. R. (Paris) 201, 1191 (1935)

    CAS  Google Scholar 

  96. Michel, A., Chaudron, G., Bernard, J.: J. Phys. Rad 12, 189 (1951)

    Article  CAS  Google Scholar 

  97. Maxwell, L. R., Smart, S., Banner, S.: Phys. Rev. 76, 459 (1949)

    Article  CAS  Google Scholar 

  98. Brown, W. F., Johnson, C. E.: J. Appl. Phys. 33, 2752 (1962)

    Article  CAS  Google Scholar 

  99. Banerjee, S. K.: J. Geomag. Geoelect. 17, 357 (1965)

    Article  Google Scholar 

  100. Banerjee, S. K., Bartholin, H.: IEEE Trans. Mag. MAG-6, 299 (1970)

    Google Scholar 

  101. Readman, P. W., O’Reilly, W.: J. Geomag. Geoelect. 24, 69 (1972)

    Article  CAS  Google Scholar 

  102. Birks. P. B.: Proc. Roy. Soc. B 63, 65 (1950)

    Google Scholar 

  103. Valstyn, E. P., Hanton, J. P., Morrish, A. H.: Phys. Rev. 128, 2078 (1962)

    Article  CAS  Google Scholar 

  104. Eagle, D. F., Mallinson, J. C.: J. Appl. Phys. 38, 995 (1967)

    Article  CAS  Google Scholar 

  105. Morrish, A. H., Watt. L. A. K.: J. Appl. Phys. 29, 1029 (1958)

    Article  CAS  Google Scholar 

  106. Bauminger, R., Cohen, S. G., Marinov, A., Ofer, S., Segal, E.: Phys. Rev. 122, 1447 (1961)

    Article  CAS  Google Scholar 

  107. Kelly, W. H., Folen, V. J., Hass, M., Schreiner, W. N., Beard, G. B.: Phys. Rev. 124, 80 (1961)

    Article  CAS  Google Scholar 

  108. Sawatzky, G. A., van der Woude, F., Morrish, A. H.: Phys. Rev. 187, 747 (1969)

    Article  CAS  Google Scholar 

  109. Osmond, W. P.: Proc. Phys. Soc. (Lond.) B 65, 122 (1952)

    Google Scholar 

  110. Osmond, W. P.: Proc. Phys. Soc. (Lond.) B 67, 875 (1954)

    Article  Google Scholar 

  111. Morrish, A. H., Yu, S. P.: J. Appl. Phys. 26, 1049 (1955)

    Article  CAS  Google Scholar 

  112. Morrish, A. H., Yu, S. P.: Phys. Rev. 102, 670 (1956)

    Article  CAS  Google Scholar 

  113. Jacobs, I. S., Bean, C. P.: Phys. Rev. 100, 1060 (1955)

    Article  Google Scholar 

  114. Brown, W. F.: Phys. Rev. 105, 1479 (1957)

    Article  Google Scholar 

  115. Frei, E. H., Shtrikman, S., Treves, D.: Phys. Rev. 106, 446 (1957)

    Article  CAS  Google Scholar 

  116. Kondorskii, E.: Izvest. Akad. Nauk. SSSR Ser. Fiz. 16, 389 (1952)

    Google Scholar 

  117. Wohlfarth, E. P.: Proc. Roy. Soc. (Lond.) A 232, 208 (1955)

    Article  CAS  Google Scholar 

  118. Morrish, A. H., Watt, L. A. K.: Phys. Rev. 105, 1476 (1957)

    Article  CAS  Google Scholar 

  119. Frumkin, A. L., Gerus’kov, V. P., Maksimov, S. A., Tolmasskii, I. S.: Zh. Tekh. Fiz. 46, 1332 (1976) [Sov. Phys.-Tech. Phys. 21, 757 (1976)]

    Google Scholar 

  120. Sato, T., Shimoiizaka, J.: J. Japan Soc. Powder and Powder Metallurgy 12, 5 (1965)

    Google Scholar 

  121. Bean, C. P.: J. Appl. Phys. 26, 1381 (1955)

    Article  Google Scholar 

  122. Haneda, K., Morrish, A. H.: Phys. Lett. 64A, 259 (1977)

    Google Scholar 

  123. Mørup, S., Topsøe, H.: Appl. Phys. 11, 63 (1976)

    Article  Google Scholar 

  124. Gillot, B., Rousset, A., Dupré, G.: J. Sol. State Chem. 21, 375 (1977)

    Article  CAS  Google Scholar 

  125. Bénard, J.: Ann. Chim. 12, 5 (1939)

    Google Scholar 

  126. Pingaud, B. J.: French Denande 2, 129, 841 (1972)

    Google Scholar 

  127. Adams, G. M., Crowley, J. I., Larson, K. H.: U. S. Pat. 3,894, 970 (1975)

    Google Scholar 

  128. Rousset, A., Chassagneux, F., Mollard, P.: C. R. (Paris) 270, 1129 (1974)

    Google Scholar 

  129. Morrish, A. H., Clark. P. E.: Phys. Rev. B11, 278 (1975)

    Article  CAS  Google Scholar 

  130. Dupré, G., Rousset, A., Mollard, P.: Mat. Res. Bull. 11, 473 (1976)

    Article  Google Scholar 

  131. Khan, Y., Kneller, E.: J. M. M. M. 7, 9 (1978)

    Google Scholar 

  132. Jeschke, J. C.: E. Germ. Patent 8,684 (1954): U. S. Pat. 3, 243, 375 (1966)

    Google Scholar 

  133. Krones, F.: Technik der Magnetspeicher, p. 479. Berlin, Göttingen, Heidelberg: Springer 1963

    Google Scholar 

  134. Nobuoku, S., Ando, T., Hayama, F.: U. S. Pat. 3,081, 264 (1963)

    Google Scholar 

  135. Arshinkov, I., Pesher, P., Tsurnovechki, O.: Izr. Nauchnoizsled. Inst. Kinematogr. Radio (Sophia) 3, 31(1961–6 2)

    Google Scholar 

  136. Rousset, A., Mollard, P., Giraud, A.: C. R. (Paris) 275, 709 (1972)

    CAS  Google Scholar 

  137. Mollard, P., Collomb, A., Devenyi, J., Rousset, A., Pâris, J.: IEEE Trans. Mag. MAG-11, 894 (1975)

    Google Scholar 

  138. Khalafallah, D., Morrish, A. H.: J. Appl. Phys. 43, 624 (1972)

    Article  Google Scholar 

  139. Clark, P. E., Morrish, A. H.: A. I. P. Proc. 18, 1412 (1974)

    Google Scholar 

  140. Slonczewski, J. C.: Phys. Rev. 110, 1341 (1958)

    Article  CAS  Google Scholar 

  141. Tachiki, M.: Progr. Theoret. Phys. (Kyoto) 23, 1055 (1960)

    Article  CAS  Google Scholar 

  142. Haller, W. D., Colline, R. M.: U. S. Pat. 3,573, 980 (1971)

    Google Scholar 

  143. Hwang, P. Y.: U. S. Pat. 3,671, 435 (1972)

    Google Scholar 

  144. Umeki, S., Saitoh, S., Imaoka, Y.: IEEE Trans. Mag. MAG-10, 655 (1974)

    Google Scholar 

  145. Hoshino, Y.: Recent trends in advances of magnetic recording materials, Tokyo: Tokyo Inst. of Tech. 1975

    Google Scholar 

  146. Stavn, M. J.,Morrish, A. H., IEEE Trans. Mag. MAG-15, 1235 (1979)

    Google Scholar 

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Morrish, A.H. (1980). Morphology and Physical Properties of Gamma Iron Oxide. In: Freyhardt, H.C. (eds) Growth and Properties. Crystals, vol 2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-67467-9_4

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